Modeling of U-shaped Ba0.5Sr0.5Co0.8Fe0.2O3-δ hollow-fiber membrane for oxygen permeation

doi:10.1016/j.cjche.2017.02.002

Abstract

Abstract: A mathematic model is developed for the perovskite-type mixed ionic-electronic conducting (MIEC) membrane, which makes it possible to simulate the process of oxygen separation in the U-shaped Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ hollow-fiber membrane. The model correlates the oxygen permeation flux to the measurable variables. The trends of calculated results for purge operation coincide well with the experimental data, therefore the model is considerable for flux prediction under vacuum operation. Higher oxygen separation efficiency can be achieved with vacuum operation than purge operation. Parameter study with vacuum operation reveals that oxygen permeation flux increases with higher vacuum levels, and vacuum pressure of around 1.013×10³ Pa is the optimal. Also, vacuum operation on the lumen side is much more efficient to achieve higher oxygen permeation flux compared with compression mode on the shell side.

Key words: Membranes, Mathematical modeling, Separation, Oxygen permeation, Perovskite

摘要： A mathematic model is developed for the perovskite-type mixed ionic-electronic conducting (MIEC) membrane, which makes it possible to simulate the process of oxygen separation in the U-shaped Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ hollow-fiber membrane. The model correlates the oxygen permeation flux to the measurable variables. The trends of calculated results for purge operation coincide well with the experimental data, therefore the model is considerable for flux prediction under vacuum operation. Higher oxygen separation efficiency can be achieved with vacuum operation than purge operation. Parameter study with vacuum operation reveals that oxygen permeation flux increases with higher vacuum levels, and vacuum pressure of around 1.013×10³ Pa is the optimal. Also, vacuum operation on the lumen side is much more efficient to achieve higher oxygen permeation flux compared with compression mode on the shell side.

关键词: Membranes, Mathematical modeling, Separation, Oxygen permeation, Perovskite

Huiqi Xie, Yanying Wei, Haihui Wang. Modeling of U-shaped Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ hollow-fiber membrane for oxygen permeation[J]. , 2017, 25(7): 892-897.

References

[1] J. Sunarso, S. Baumann, J.M. Serra, W.A. Meulenberg, S. Liu, Y.S. Lin, J.C. Diniz da Costa, Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation, J. Membr. Sci. 320(2008) 13-41.
[2] X. Tan, Y. Liu, K. Li, Mixed conducting ceramic hollow-fiber membranes for air separation, AIChE J. 51(2005) 1991-2000.
[3] P.N. Dyer, R.E. Richards, S.L. Russek, D.M. Taylor, Ion transport membrane technology for oxygen separation and syngas production, Solid State Ionics 134(2000) 21-33.
[4] H.J.M. Bouwmeester, Dense ceramic membranes for methane conversion, Catal. Today 82(2003) 141-150.
[5] Y. Zeng, Y.S. Lin, S.L. Swartz, Perovskite-type ceramic membrane:Synthesis, oxygen permeation and membrane reactor performance for oxidative coupling of methane, J. Membr. Sci. 150(1998) 87-98.
[6] Z. Shao, H. Dong, G. Xiong, Y. Cong, W. Yang, Performance of a mixed-conducting ceramic membrane reactor with high oxygen permeability for methane conversion, J. Membr. Sci. 183(2001) 181-192.
[7] Z. Shao, S.M. Haile, A high-performance cathode for the next generation of solidoxide fuel cells, Nature 431(2004) 170-173.
[8] V.V. Kharton, A.A. Yaremchenko, E.N. Naumovich, Research on the electrochemistry of oxygen ion conductors in the former Soviet Union. Ⅱ. Perovskite-related oxides, J. Solid State Electrochem. 3(1999) 303-326.
[9] L. Qiu, T.H. Lee, L.M. Liu, Y.L. Yang, A.J. Jacobson, Oxygen permeation studies of SrCo_0.8Fe_0.2O_3-δ, Solid State Ionics 76(1995) 321-329.
[10] P. Zeng, R. Ran, Z. Chen, W. Zhou, H. Gu, Z. Shao, S. Liu, Efficient stabilization of cubic perovskite SrCoO_3-δ by B-site low concentration scandium doping combined with sol-gel synthesis, J. Alloys Compd. 455(2008) 465-470.
[11] C.H. Chen, H.J.M. Bouwmeester, R.H.E. van Doorn, H. Kruidhof, A.J. Burggraaf, Oxygen permeation of La_0.3Sr_0.7CoO_3-δ, Solid State Ionics 98(1997) 7-13.
[12] V.V. Kharton, L. Shuangbao, A.V. Kovalevsky, A.P. Viskup, E.N. Naumovich, A.A. Tonoyan, Oxygen permeability and thermal expansion of SrCo (Ti)O_3-δ perovskites, Mater. Chem. Phys. 53(1998) 6-12.
[13] V.V. Kharton, A.A. Yaremchenko, A.V. Kovalevsky, A.P. Viskup, E.N. Naumovich, P.F. Kerko, Perovskite-type oxides for high-temperature oxygen separation membranes, J. Membr. Sci. 163(1999) 307-317.
[14] S. Liu, X. Tan, Z. Shao, J.C. Diniz da Costa, Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ ceramic hollowfiber membranes for oxygen permeation, AIChE J. 52(2006) 3452-3461.
[15] H. Wang, Y. Cong, W. Yang, Oxygen permeation study in a tubular Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ oxygen permeable membrane, J. Membr. Sci. 210(2002) 259-271.
[16] M. Salehi, F. Clemens, E.M. Pfaff, S. Diethelm, C. Leach, T. Graule, B. Grobéty, A case study of the effect of grain size on the oxygen permeation flux of BSCF diskshaped membrane fabricated by thermoplastic processing, J. Membr. Sci. 382(2011) 186-193.
[17] X. Zhu, S. Sun, Y. Cong, W. Yang, Operation of perovskite membrane under vacuum and elevated pressures for high-purity oxygen production, J. Membr. Sci. 345(2009) 47-52.
[18] H. Pan, L. Li, X. Deng, B. Meng, X. Tan, K. Li, Improvement of oxygen permeation in perovskite hollow fibre membranes by the enhanced surface exchange kinetics, J. Membr. Sci. 428(2013) 198-204.
[19] C. Hamel, A. Seidel-Morgenstern, T. Schiestel, S. Werth, H. Wang, C. Tablet, J. Caro, Experimental and modeling study of the O₂-enrichment by perovskite fibers, AIChE J. 52(2006) 3118-3125.
[20] A.Behrouzifar,A.A.Asadi,T.Mohammadi,A.Pak,Experimentalinvestigationandmathematical modeling of oxygen permeation through dense Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ (BSCF) perovskite-type ceramic membranes, Ceram. Int. 38(2012) 4797-4811.
[21] M.A. Habib, R. Ben Mansour, M.A. Nemit-allah, Modeling of oxygen permeation through a LSCF ion transport membrane, Comput. Fluids 76(2013) 1-10.
[22] S.J. Xu, W.J. Thomson, Oxygen permeation rates through ion-conducting perovskite membranes, Chem. Eng. Sci. 54(1999) 3839-3850.
[23] H. Wang, R. Wang, D.T. Liang, W. Yang, Experimental and modeling studies on Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ (BSCF) tubular membranes for air separation, J. Membr. Sci. 243(2004) 405-415.
[24] X. Tan, K. Li, Modeling of air separation in a LSCF hollow-fiber membrane module, AIChE J. 48(2002) 1469-1477.
[25] Z. Shao, W. Yang, Y. Cong, H. Dong, J. Tong, G. Xiong, Investigation of the permeation behavior and stability of a Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ oxygen membrane, J. Membr. Sci. 172(2000) 177-188.
[26] L. Wang, R. Merkle, J. Maier, T. Acartürk, U. Starke, Oxygen tracer diffusion in dense Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ films, Appl. Phys. Lett. 94(2009) 071908.
[27] E. Bucher, A. Egger, P. Ried, W. Sitte, P. Holtappels, Oxygen nonstoichiometry and exchange kinetics of Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ, Solid State Ionics 179(2008) 1032-1035.
[28] S. McIntosh, J.F. Vente, W.G. Haije, D.H.A. Blank, H.J.M. Bouwmeester, Oxygen stoichiometry and chemical expansion of Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ measured by in situ neutron diffraction, Chem. Mater. 18(2006) 2187-2193.
[29] P.Zeng,Z.Chen,W.Zhou,H.Gu,Z.Shao,S.Liu,Re-evaluationofBa_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ perovskite as oxygen semi-permeable membrane, J. Membr. Sci. 291(2007) 148-156.
[30] Y. Wei, H. Liu, J. Xue, Z. Li, H. Wang, Preparation and oxygen permeation of U-shaped perovskite hollow-fiber membranes, AIChE J. 57(2011) 975-984.

Modeling of U-shaped Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ hollow-fiber membrane for oxygen permeation

Modeling of U-shaped Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ hollow-fiber membrane for oxygen permeation

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