SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2022, Vol. 51 ›› Issue (11): 10-20.DOI: 10.1016/j.cjche.2022.07.025

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Effect of K2CO3 doping on CO2 sorption performance of silicate lithium-based sorbent prepared from citric acid treated sediment

Junya Wang1, Kai Chen1, Yi Wang1, Jiuming Lei2, Abdullah Alsubaie3, Ping Ning1, Shikun Wen1, Taiping Zhang1,2, Abdulraheem S.A. Almalki4, A. Alhadhrami4, Zhiping Lin5, Hassan Algadi6, Zhanhu Guo7   

  1. 1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China;
    2. Ecological Environment Monitoring Station, Linxiang Branch, Lincang Municipal Bureau of Ecology and Environment, Lincang 677000, China;
    3. Department of Physics, College of Khurma, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia;
    4. Department of Chemistry, Faculty of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia;
    5. Integrated Composites Laboratory (ICL), Department of Chemical and Bimolecular Engineering, University of Tennessee, Knoxville, TN 37996, United States;
    6. Department of Electrical Engineering, Faculty of Engineering, Najran University, P.O. Box 1988, Najran 11001, Saudi Arabia;
    7. College of Materials Science and Engineering, Taizhou University, Taizhou 318000, China
  • Received:2022-04-13 Revised:2022-07-20 Online:2023-01-18 Published:2022-11-18
  • Contact: Shikun Wen,E-mail:shikunwen@kust.edu.cn;Taiping Zhang,E-mail:810849646@qq.com;Zhanhu Guo,E-mail:nanomaterials2000@gmail.com
  • Supported by:
    The authors are very grateful to the financial support from National Natural Science Foundation of China (21868015, 51802135), and the Applied Basic Research Programs of Yunnan Province (140520210057), and Taif University Researchers Supporting Project number (TURSP-2020/163), Taif University, Taif, Saudi Arabia.

Effect of K2CO3 doping on CO2 sorption performance of silicate lithium-based sorbent prepared from citric acid treated sediment

Junya Wang1, Kai Chen1, Yi Wang1, Jiuming Lei2, Abdullah Alsubaie3, Ping Ning1, Shikun Wen1, Taiping Zhang1,2, Abdulraheem S.A. Almalki4, A. Alhadhrami4, Zhiping Lin5, Hassan Algadi6, Zhanhu Guo7   

  1. 1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China;
    2. Ecological Environment Monitoring Station, Linxiang Branch, Lincang Municipal Bureau of Ecology and Environment, Lincang 677000, China;
    3. Department of Physics, College of Khurma, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia;
    4. Department of Chemistry, Faculty of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia;
    5. Integrated Composites Laboratory (ICL), Department of Chemical and Bimolecular Engineering, University of Tennessee, Knoxville, TN 37996, United States;
    6. Department of Electrical Engineering, Faculty of Engineering, Najran University, P.O. Box 1988, Najran 11001, Saudi Arabia;
    7. College of Materials Science and Engineering, Taizhou University, Taizhou 318000, China
  • 通讯作者: Shikun Wen,E-mail:shikunwen@kust.edu.cn;Taiping Zhang,E-mail:810849646@qq.com;Zhanhu Guo,E-mail:nanomaterials2000@gmail.com
  • 基金资助:
    The authors are very grateful to the financial support from National Natural Science Foundation of China (21868015, 51802135), and the Applied Basic Research Programs of Yunnan Province (140520210057), and Taif University Researchers Supporting Project number (TURSP-2020/163), Taif University, Taif, Saudi Arabia.

Abstract: In this paper, a low-cost and environmental-friendly leaching agent citric acid (C6H8O7) was used to treat the sediment of Dianchi Lake (SDL) to synthesize lithium silicate (Li4SiO4) based CO2 sorbent. The results were compared with that treated with strong acid. Moreover, the effects of preparation conditions, sorption conditions and desorption conditions on the CO2 sorption performance of prepared Li4SiO4 were systematically studied. Under optimal conditions, the Li4SiO4 sorbent was successfully synthesized and its CO2 sorption capacity reached 31.37% (mass), which is much higher than that synthesized from SDL treated with strong acid. It is speculated that the presence of some elements after C6H8O7 treatment may promote the sorption of synthetic Li4SiO4 to CO2. In addition, after doping with K2CO3, the CO2 uptake increases from the original 12.02% and 22.12% to 23.96% and 32.41% (mass) under the 20% and 50% CO2 partial pressure, respectively. More importantly, after doping K2CO3, the synthesized Li4SiO4 has a high cyclic stability under the low CO2 partial pressure.

Key words: CO2 sorbents, Li4SiO4, Sediment, Citric acid, Doped with K2CO3

摘要: In this paper, a low-cost and environmental-friendly leaching agent citric acid (C6H8O7) was used to treat the sediment of Dianchi Lake (SDL) to synthesize lithium silicate (Li4SiO4) based CO2 sorbent. The results were compared with that treated with strong acid. Moreover, the effects of preparation conditions, sorption conditions and desorption conditions on the CO2 sorption performance of prepared Li4SiO4 were systematically studied. Under optimal conditions, the Li4SiO4 sorbent was successfully synthesized and its CO2 sorption capacity reached 31.37% (mass), which is much higher than that synthesized from SDL treated with strong acid. It is speculated that the presence of some elements after C6H8O7 treatment may promote the sorption of synthetic Li4SiO4 to CO2. In addition, after doping with K2CO3, the CO2 uptake increases from the original 12.02% and 22.12% to 23.96% and 32.41% (mass) under the 20% and 50% CO2 partial pressure, respectively. More importantly, after doping K2CO3, the synthesized Li4SiO4 has a high cyclic stability under the low CO2 partial pressure.

关键词: CO2 sorbents, Li4SiO4, Sediment, Citric acid, Doped with K2CO3