KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries

doi:10.1016/j.cjche.2022.09.010

Chinese Journal of Chemical Engineering ›› 2023, Vol. 57 ›› Issue (5): 214-223.DOI: 10.1016/j.cjche.2022.09.010

KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries

Kai Xue¹, Yanchun Xue¹, Jing Wang¹, Shuya Zhang¹, Xingmei Guo^1,2, Xiangjun Zheng¹, Fu Cao¹, Qinghong Kong³, Junhao Zhang¹, Zhong Jin²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. MOE Key Laboratory of Mesoscopic Chemistry, MOE Key Laboratory of High Performance Polymer Materials and Technology, Jiangsu Key Laboratory of Advanced Organic Materials, Suzhou Tierui New Energy Technology Co. Ltd, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China;
3. School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

Received:2022-05-23 Revised:2022-08-27 Online:2023-07-08 Published:2023-05-28
Contact: Xingmei Guo,E-mail:guoxm@just.edu.cn;Fu Cao,E-mail:huanjing2001@163.com;Junhao Zhang,E-mail:jhzhang6@just.edu.cn;Zhong Jin,E-mail:zhongjin@nju.edu.cn
Supported by:
The work was financially supported by the National Key Research and Development Program of China (2017YFA0208200), the National Natural Science Foundation of China (52102100, 22022505 and 21872069), the Natural Science Foundation of Jiangsu Province (BK20181469), Guangdong Basic and Applied Basic Research Foundation (2020A1515110035), the Fundamental Research Funds for the Central Universities (0205-14380266, 0205-14380272), the Scientific and Technological Innovation Special Fund for Carbon Peak and Carbon Neutrality of Jiangsu Province (BK20220008), and the 2021 Suzhou Gusu Leading Talents of Science and Technology Innovation and Entrepreneurship in Wujiang District.

KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries

Kai Xue¹, Yanchun Xue¹, Jing Wang¹, Shuya Zhang¹, Xingmei Guo^1,2, Xiangjun Zheng¹, Fu Cao¹, Qinghong Kong³, Junhao Zhang¹, Zhong Jin²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. MOE Key Laboratory of Mesoscopic Chemistry, MOE Key Laboratory of High Performance Polymer Materials and Technology, Jiangsu Key Laboratory of Advanced Organic Materials, Suzhou Tierui New Energy Technology Co. Ltd, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China;
3. School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

通讯作者: Xingmei Guo,E-mail:guoxm@just.edu.cn;Fu Cao,E-mail:huanjing2001@163.com;Junhao Zhang,E-mail:jhzhang6@just.edu.cn;Zhong Jin,E-mail:zhongjin@nju.edu.cn
基金资助:
The work was financially supported by the National Key Research and Development Program of China (2017YFA0208200), the National Natural Science Foundation of China (52102100, 22022505 and 21872069), the Natural Science Foundation of Jiangsu Province (BK20181469), Guangdong Basic and Applied Basic Research Foundation (2020A1515110035), the Fundamental Research Funds for the Central Universities (0205-14380266, 0205-14380272), the Scientific and Technological Innovation Special Fund for Carbon Peak and Carbon Neutrality of Jiangsu Province (BK20220008), and the 2021 Suzhou Gusu Leading Talents of Science and Technology Innovation and Entrepreneurship in Wujiang District.

Abstract

Abstract: To solve the environmental pollution and low yield during the sythesis of zeolitic imidazolate frameworks (ZIFs) and their derived materials, a KOH-assisted aqueous strategy is proposed to synthesize cobalt zeolitic imidazolate framework (ZIF-67) polyhedrons, which are used as precursors to prepare cobalt selenide/carbon composites with different crystal phases (Co_0.85Se, CoSe₂). When evaluated as anode material for lithium ion batteries, Co_0.85Se/C composites deliver a reversible capacity of 758.7 mA·h·g^-1 with a capacity retention rate of 90.5% at 1.0 A·g^-1 after 500 cycles, and the superior rate capability is 620 mA·h·g^-1 at 2.0 A·g^-1. The addition of KOH accelerates the production of ZIF-67 crystals by boosting deprotonation of dimethylimidazole, resulting in rapid growth and structures transition from two-dimensional to three-dimensional of ZIF-67 in aqueous solution, which greatly promotes the application of MOFs in the field of energy storage and conversion.

Key words: KOH-assisted strategy, Synthesis, Aqueous solution, Nanostructure, Lithium-ion batteries, Long cycle performance

摘要： To solve the environmental pollution and low yield during the sythesis of zeolitic imidazolate frameworks (ZIFs) and their derived materials, a KOH-assisted aqueous strategy is proposed to synthesize cobalt zeolitic imidazolate framework (ZIF-67) polyhedrons, which are used as precursors to prepare cobalt selenide/carbon composites with different crystal phases (Co_0.85Se, CoSe₂). When evaluated as anode material for lithium ion batteries, Co_0.85Se/C composites deliver a reversible capacity of 758.7 mA·h·g^-1 with a capacity retention rate of 90.5% at 1.0 A·g^-1 after 500 cycles, and the superior rate capability is 620 mA·h·g^-1 at 2.0 A·g^-1. The addition of KOH accelerates the production of ZIF-67 crystals by boosting deprotonation of dimethylimidazole, resulting in rapid growth and structures transition from two-dimensional to three-dimensional of ZIF-67 in aqueous solution, which greatly promotes the application of MOFs in the field of energy storage and conversion.

关键词: KOH-assisted strategy, Synthesis, Aqueous solution, Nanostructure, Lithium-ion batteries, Long cycle performance

Kai Xue, Yanchun Xue, Jing Wang, Shuya Zhang, Xingmei Guo, Xiangjun Zheng, Fu Cao, Qinghong Kong, Junhao Zhang, Zhong Jin. KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries[J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 214-223.

References

[1] M. Huang, K. Mi, J.H. Zhang, H.L. Liu, T.T. Yu, A.H. Yuan, Q.H. Kong, S.L. Xiong, MOF-derived bi-metal embedded N-doped carbon polyhedral nanocages with enhanced lithium storage, J. Mater. Chem. A 5 (1) (2017) 266–274.
[2] Y.Z. Liang, N. Song, Z. Zhang, W.H. Chen, J.K. Feng, B.J. Xi, S.L. Xiong, Integrating Bi@C nanospheres in porous hard carbon frameworks for ultrafast sodium storage, Adv. Mater. 34 (28) (2022) 2202673.
[3] J.H. Zhang, M. Huang, B.J. Xi, K. Mi, A.H. Yuan, S.L. Xiong, Systematic study of effect on enhancing specific capacity and electrochemical behaviors of lithium-sulfur batteries, Adv. Energy Mater. 8 (2) (2018) 1701330.
[4] Y.X. Yun, B.J. Xi, F. Tian, W.H. Chen, W.P. Sun, H.G. Pan, J.K. Feng, Y.T. Qian, S.L. Xiong, Zero-strain structure for efficient potassium storage: Nitrogen-enriched carbon dual-confinement CoP composite, Adv. Energy Mater. 12 (3) (2022) 2103341.
[5] N.X. Shi, B.J. Xi, M. Huang, X.J. Ma, H.B. Li, J.K. Feng, S.L. Xiong, Hierarchical octahedra constructed by Cu₂S/MoS₂⊂Carbon framework with enhanced sodium storage, Small 16 (23) (2020) 2000952.
[6] J. Chen, X. Guo, M. Gao, J. Wang, S. Sun, K. Xue, S. Zhang, Y. Liu, J. Zhang, Free-supportingdual-confined porous Si@c-ZIF@carbon nanofibersfor high-performance lithium-ion batteries,Chem. Commun. 57(81) (2021) 10580-10583.
[7] C. Wang, X. Liu, N. Keser Demir, J.P. Chen, K. Li, Applications of water stable metal-organic frameworks, Chem. Soc. Rev. 45 (18) (2016) 5107–5134.
[8] Y.J. Fang, D.Y. Luan, Y. Chen, S.Y. Gao, X.W. Lou, Rationally designed three-layered Cu₂S@Carbon@MoS₂ hierarchical nanoboxes for efficient sodium storage, Angewandte Chemie Int. Ed. 59 (18) (2020) 7178–7183.
[9] M. Huang, B.J. Xi, N.X. Shi, J.K. Feng, Y.T. Qian, D.F. Xue, S.L. Xiong, Quantum-matter Bi/TiO 2 heterostructure embedded in N-doped porous carbon nanosheets for enhanced sodium storage, Small Struct. 2 (4) (2021) 2000085.
[10] M.Y. Gao, Z.H. Tang, M.R. Wu, J.L. Chen, Y.C. Xue, X.M. Guo, Y.J. Liu, Q.H. Kong, J.H. Zhang, Self-supporting N, P doped Si/CNTs/CNFs composites with fiber network for high-performance lithium-ion batteries, J. Alloys Compd. 857 (2021) 157554.
[11] X.C. Cai, J. Lin, M.L. Pang, Facile synthesis of highly uniform Fe-MIL-88B particles, Cryst. Growth Des. 16 (7) (2016) 3565–3568.
[12] Y.X. Wang, M.T. Zhao, J.F. Ping, B. Chen, X.H. Cao, Y. Huang, C.L. Tan, Q.L. Ma, S.X. Wu, Y.F. Yu, Q.P. Lu, J.Z. Chen, W. Zhao, Y.B. Ying, H. Zhang, Bioinspired design of ultrathin 2D bimetallic metal-organic-framework nanosheets used as biomimetic enzymes, Adv. Mater. 28 (21) (2016) 4149–4155.
[13] F.F. Cao, M.T. Zhao, Y.F. Yu, B. Chen, Y. Huang, J. Yang, X.H. Cao, Q.P. Lu, X. Zhang, Z.C. Zhang, C.L. Tan, H. Zhang, Synthesis of two-dimensional CoS1.097/nitrogen-doped carbon nanocomposites using metal–organic framework nanosheets as precursors for supercapacitor application, J. Am. Chem. Soc. 138 (22) (2016) 6924–6927.
[14] H. Hu, B.Y. Guan, X.W. Lou, Construction of complex CoS hollow structures with enhanced electrochemical properties for hybrid supercapacitors, Chem 1 (1) (2016) 102–113.
[15] J. Huang, G.Z. Fang, K. Liu, J. Zhou, X.K. Tang, K.N. Cai, S.Q. Liang, Controllable synthesis of highly uniform cuboid-shape MOFs and their derivatives for lithium-ion battery and photocatalysis applications, Chem. Eng. J. 322 (2017) 281–292.
[16] F. Sun, H. Wang, Z.B. Qu, K.F. Wang, L.J. Wang, J.H. Gao, J.M. Gao, S.Q. Liu, Y.F. Lu, Carboxyl-dominant oxygen rich carbon for improved sodium ion storage: Synergistic enhancement of adsorption and intercalation mechanisms, Adv. Energy Mater. 11 (1) (2021) 2002981.
[17] T. Wang, Y. He, Y.J. Liu, F.J. Guo, X.F. Li, H.B. Chen, H.M. Li, Z.Q. Lin, A ZIF-triggered rapid polymerization of dopamine renders Co/N-codoped cage-in-cage porous carbon for highly efficient oxygen reduction and evolution, Nano Energy 79 (2021) 105487.
[18] J.O. Kim, K.I. Min, H. Noh, D.H. Kim, S.Y. Park, D.P. Kim, Direct fabrication of free-standing MOF superstructures with desired shapes by micro-confined interfacial synthesis, Angew. Chem. Int. Ed. 55 (25) (2016) 7116–7120.
[19] H.M. Liu, M.M. Jin, da Zhan, J.M. Wang, X.Y. Cai, Y.T. Qiu, L.F. Lai, Stacking faults triggered strain engineering of ZIF-67 derived Ni-Co bimetal phosphide for enhanced overall water splitting, Appl. Catal. B Environ. 272 (2020) 118951.
[20] C.N. Gu, J.J. Li, J.P. Liu, H. Wang, Y. Peng, C.S. Liu, Conferring supramolecular guanosine gel nanofiber with ZIF-67 for high-performance oxygen reduction catalysis in rechargeable zinc-air batteries, Appl. Catal. B Environ. 286 (2021) 119888.
[21] J.H. Park, Y.S. Choi, Y.W. Byeon, J.P. Ahn, J.C. Lee, Diffusion kinetics governing the diffusivity and diffusion anisotropy of alloying anodes in Na-ion batteries, Nano Energy 65 (2019) 104041.
[22] J. Du, J. Ren, M. Shu, X. Xu, Z. Niu, W. Shi, R. Si, P. Cheng, Insights into the capacity and rate performance of transition-metal coordination compounds for reversible lithium storage, Angew. Chem. Int. Ed. 60(8) (2021) 4142-4149.
[23] H.H. Li, Y. Ma, H. Zhang, T. Diemant, R.J. Behm, A. Varzi, S. Passerini, Metal-organic framework derived Fe₇S₈ nanoparticles embedded in heteroatom-doped carbon with lithium and sodium storage capability, Small Methods 4 (12) (2020) 2000637.
[24] X.H. Wan, X.M. Guo, M.T. Duan, J. Shi, S.J. Liu, J.H. Zhang, Y.J. Liu, X.J. Zheng, Q.H. Kong, Ultrafine CoO nanoparticles and Co-N-C lamellae supported on mesoporous carbon for efficient electrocatalysis of oxygen reduction in zinc-air batteries, Electrochimica Acta 394 (2021) 139135.
[25] K.K. Guo, B.J. Xi, R.C. Wei, H.B. Li, J.K. Feng, S.L. Xiong, Hierarchical microcables constructed by CoP@C⊂Carbon framework intertwined with carbon nanotubes for efficient lithium storage, Adv. Energy Mater. 10 (12) (2020) 1902913.
[26] R. Guo, C. Lv, W. Xu, J. Sun, Y. Zhu, X. Yang, J. Li, J. Sun, L. Zhang, D. Yang, Effect of intrinsic defects of carbon materials on the sodium storage performance, Adv. Energy Mater. 10(9) (2020) 1903652.
[27] Y. Yin, R.M. Rioux, C.K. Erdonmez, S. Hughes, G.A. Somorjai, A.P. Alivisatos, Formation of hollow nanocrystals through the nanoscale Kirkendall effect, Science 304 (5671) (2004) 711–714.
[28] H. Hu, J. Zhang, B. Guan, X.W. Lou, Unusual formation of CoSe@carbon nanoboxes, which have an inhomogeneous shell, for efficient lithium storage, Angew. Chem. Int. Ed Engl. 55 (33) (2016) 9514–9518.
[29] J. Shi, X.M. Guo, S.J. Liu, Y. Sun, J.H. Zhang, Y.J. Liu, X.J. Zheng, Q.H. Kong, An altered nanoemulsion assembly strategy for in situ synthesis of CO₂P/NP-C nanospheres as advanced oxygen reduction electrocatalyst for zinc-air batteries, Compos. B Eng. 231 (2022) 109589.
[30] J. Kim, J. Lee, J. Yun, S.H. Choi, S.G. Han, J. Moon, J.H. Kim, J.W. Lee, M.S. Park, Functionality of dual-phase lithium storage in a porous carbon host for lithium-metal anode, Adv. Funct. Mater. 30 (15) (2020) 1910538.
[31] X.M. Guo, S.J. Liu, X.H. Wan, J.H. Zhang, Y.J. Liu, X.J. Zheng, Q.H. Kong, Z. Jin, Controllable solid-phase fabrication of an Fe₂O₃/Fe₅C₂/Fe–N–C electrocatalyst toward optimizing the oxygen reduction reaction in zinc–air batteries, Nano Lett. 22 (12) (2022) 4879–4887.
[32] J.J. Yuan, W. Liu, X.K. Zhang, Y.H. Zhang, W.T. Yang, W.D. Lai, X.K. Li, J.J. Zhang, X.F. Li, MOF derived ZnSe-FeSe₂/RGO Nanocomposites with enhanced sodium/potassium storage, J. Power Sources 455 (2020) 227937.
[33] J. Zhu, C.Q. Shang, X. Wang, G.F. Zhou, Enhanced sodium storage performance of Co₇Se₈ enabled through In Situ formation of a nanoporous architecture, ChemElectroChem 7 (21) (2020) 4361–4368.
[34] S. Men, J. Lin, Y. Zhou, X.W. Kang, N-doped porous carbon wrapped FeSe₂ nanoframework prepared by spray drying: A potential large-scale production technique for high-performance anode materials of sodium ion batteries, J. Power Sources 485 (2021) 229310.
[35] W.W. Sun, X.C. Tao, P.P. Du, Y. Wang, Carbon-coated mixed-metal sulfide hierarchical structure: MOF-derived synthesis and lithium-storage performances, Chem. Eng. J. 366 (2019) 622–630.
[36] M. Huang, B. Xi, L. Mi, Z. Zhang, W. Chen, J. Feng, S. Xiong, Rationally designed three-layered TiO₂@amorphous MoS₃@carbon hierarchical microspheres for efficient potassium storage, Small 18(13) (2022) 210781.
[37] M.Y. Gao, Y.C. Xue, Y.T. Zhang, C.X. Zhu, H.W. Yu, X.M. Guo, S.S. Sun, S.L. Xiong, Q.H. Kong, J.H. Zhang, Growing Co–Ni–Se nanosheets on 3D carbon frameworks as advanced dual functional electrodes for supercapacitors and sodium ion batteries, Inorg. Chem. Front. 9 (15) (2022) 3933–3942.
[38] Y.C. Xue, X.M. Guo, M.R. Wu, J.L. Chen, M.T. Duan, J. Shi, J.H. Zhang, F. Cao, Y.J. Liu, Q.H. Kong, Zephyranthes-like CO₂NiSe₄ arrays grown on 3D porous carbon frame-work as electrodes for advanced supercapacitors and sodium-ion batteries, Nano Res. 14 (10) (2021) 3598–3607.
[39] Z. Yang, X.H. Liu, X.X. He, W.H. Lai, L. Li, Y. Qiao, S.L. Chou, M.H. Wu, Rechargeable sodium-based hybrid metal-ion batteries toward advanced energy storage, Adv. Funct. Mater. 31 (8) (2021) 2006457.
[40] M.R. Wu, M.Y. Gao, S.Y. Zhang, R. Yang, Y.M. Chen, S.Q. Sun, J.F. Xie, X.M. Guo, F. Cao, J.H. Zhang, High-performance lithium-sulfur battery based on porous N-rich g-C₃N₄ nanotubes via a self-template method, Int. J. Miner. Metall. Mater. 28 (10) (2021) 1656–1665.
[41] M.T. Duan, M.R. Wu, K. Xue, Z.X. Bian, J. Shi, X.M. Guo, F. Cao, J.H. Zhang, Q.H. Kong, F. Zhang, Preparation of CoO/SnO₂@NC/S composite as high-stability cathode material for lithium-sulfur batteries, Int. J. Miner. Metall. Mater. 28 (10) (2021) 1647–1655.

KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries

KOH-assisted aqueous synthesis of ZIF-67 with high-yield and its derived cobalt selenide/carbon composites for high-performance Li-ion batteries

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