Influence of A-type Zeolite on Methane Hydrate Formation

›› 2009, Vol. 17 ›› Issue (5): 854-859.

• PRODUCT ENGINEERING AND CHEMICAL TECHNOLOGY • Previous Articles Next Articles

Influence of A-type Zeolite on Methane Hydrate Formation

ZANG Xiaoya^1,2,3, DU Jianwei^1,2,3, LIANG Deqing^1,2,3, FAN Shuanshi², TANG Cuiping^1,2,3

1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2. Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China;
3. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China

Received:2009-04-10 Revised:2009-08-09 Online:2009-10-28 Published:2009-10-28
Supported by:
Supported by the National Natural Science Foundation of China (50876107);the National Basic Research Program of China (2009CB219504);NSFC-Guangdong Union Foundation (NSFC-U0733033);CAS Program (KGCX2-YW-805)

Influence of A-type Zeolite on Methane Hydrate Formation

臧小亚^1,2,3, 杜建伟^1,2,3, 梁德青^1,2,3, 樊栓狮², 唐翠萍^1,2,3

1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2. Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences, Guangzhou 510640, China;
3. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China

通讯作者: LIANG Deqing,E-mail:liangdq@ms.giec.ac.cn
基金资助:
Supported by the National Natural Science Foundation of China (50876107);the National Basic Research Program of China (2009CB219504);NSFC-Guangdong Union Foundation (NSFC-U0733033);CAS Program (KGCX2-YW-805)

Abstract

Abstract: The porous medium has an important effect on hydrate formation.In this paper,the formation process and the gas storage capacity of the methane hydrate were investigated with A-type zeolite and Sodium Dodecyl Sulfate (SDS) existing in the system.The results show that A-type zeolite can influence methane hydrate formation.At the temperature of 273.5 K and pressure of 8.3 MPa,the distilled water with A-type zeolite can form methane hydrate with gaseous methane in 12 hours.The formation process of the system with A-type zeolite was quite steady and the amount of A-type zeolite can influence the gas storage capacity significantly.The adding of A-type zeolite with 0.067 g·(g water)^-1 into 2×10^-3 g·g^-1 SDS-water solution can increase the gas storage capacity,and the maximum increase rate was 31%.Simultaneously the promotion effect on hydrate formation of 3A-type zeolite is much more obvious than that of 5A-type zeolite when the water adding amounts are 0.033 g·g^-1 and 0.067 g·g^-1 at the experimental conditions.

Key words: hydrate, formation, gas storage, A-type zeolite

摘要： The porous medium has an important effect on hydrate formation.In this paper,the formation process and the gas storage capacity of the methane hydrate were investigated with A-type zeolite and Sodium Dodecyl Sulfate (SDS) existing in the system.The results show that A-type zeolite can influence methane hydrate formation.At the temperature of 273.5 K and pressure of 8.3 MPa,the distilled water with A-type zeolite can form methane hydrate with gaseous methane in 12 hours.The formation process of the system with A-type zeolite was quite steady and the amount of A-type zeolite can influence the gas storage capacity significantly.The adding of A-type zeolite with 0.067 g·(g water)^-1 into 2×10^-3 g·g^-1 SDS-water solution can increase the gas storage capacity,and the maximum increase rate was 31%.Simultaneously the promotion effect on hydrate formation of 3A-type zeolite is much more obvious than that of 5A-type zeolite when the water adding amounts are 0.033 g·g^-1 and 0.067 g·g^-1 at the experimental conditions.

关键词: hydrate, formation, gas storage, A-type zeolite

ZANG Xiaoya, DU Jianwei, LIANG Deqing, FAN Shuanshi, TANG Cuiping. Influence of A-type Zeolite on Methane Hydrate Formation[J]. , 2009, 17(5): 854-859.

臧小亚, 杜建伟, 梁德青, 樊栓狮, 唐翠萍. Influence of A-type Zeolite on Methane Hydrate Formation[J]. , 2009, 17(5): 854-859.

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Influence of A-type Zeolite on Methane Hydrate Formation

Influence of A-type Zeolite on Methane Hydrate Formation

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