Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

›› 2011, Vol. 19 ›› Issue (2): 217-222.

• THERMODYNAMICS AND CHEMICAL ENGINEERING DATA • Previous Articles Next Articles

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

GONG Xingchu, WANG Shanshan, QU Haibin

Department of Chinese Medicine Science and Engineering, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, China

Received:2010-07-14 Revised:2010-11-16 Online:2011-04-28 Published:2011-04-28
Supported by:
Supported by the National Science and Technology Major Project (2009ZX09313-036);the China Postdoctoral Science Foundation (20090461360);the Zhejiang Provincial Education Department Projects (Y200907556)

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

龚行楚, 王珊珊, 瞿海斌

Department of Chinese Medicine Science and Engineering, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, China

通讯作者: QU Haibin,E-mail:quhb@zju.edu.cn
基金资助:
Supported by the National Science and Technology Major Project (2009ZX09313-036);the China Postdoctoral Science Foundation (20090461360);the Zhejiang Provincial Education Department Projects (Y200907556)

Abstract

Abstract: Experimental data on the solubility of D-glucose,D-fructose and sucrose in the mixed solvents composed of water and ethanol from 273.2 to 293.2 K were determined.The solubility of D-glucose,D-fructose and sucrose decreased as the ethanol content increased in the mixed solvent.The solubility of D-glucose,D-fructose and sucrose decreased with decreasing equilibrium temperature.The modified UNIQUAC model,SUNIFAC model and mS-UNIFAC model were applied to predict the solid-liquid equilibria.The prediction results were compared and discussed.Better prediction accuracy was generated using the modified UNIQUAC model.

Key words: glucose, fructose, sucrose, ethanol, solid-liquid equilibria

摘要： Experimental data on the solubility of D-glucose,D-fructose and sucrose in the mixed solvents composed of water and ethanol from 273.2 to 293.2 K were determined.The solubility of D-glucose,D-fructose and sucrose decreased as the ethanol content increased in the mixed solvent.The solubility of D-glucose,D-fructose and sucrose decreased with decreasing equilibrium temperature.The modified UNIQUAC model,SUNIFAC model and mS-UNIFAC model were applied to predict the solid-liquid equilibria.The prediction results were compared and discussed.Better prediction accuracy was generated using the modified UNIQUAC model.

关键词: glucose, fructose, sucrose, ethanol, solid-liquid equilibria

GONG Xingchu, WANG Shanshan, QU Haibin. Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K[J]. , 2011, 19(2): 217-222.

龚行楚, 王珊珊, 瞿海斌. Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K[J]. , 2011, 19(2): 217-222.

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Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

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