CO2 Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers

Chin.J.Chem.Eng. ›› 2012, Vol. 20 ›› Issue (5): 849-855.

• SEPARATION SCIENCE AND ENGINEERING • Previous Articles Next Articles

CO₂ Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers

XU Dong¹, Penny Xiao², LI Gang², ZHANG Jun², Paul Webley², ZHAI Yuchun³

1. Guodian New Energy Technology Research Institute, China Guodian Corporation, Beijing 100034, China;
2. Department of Chemical Engineering, Monash University, Melbourne 3186, Australia;
3. School of Material and Metallurgy, Northeastern University, Shenyang 110004, China

Received:2011-01-18 Revised:2011-10-05 Online:2012-11-06 Published:2012-10-28
Supported by:
Supported by the National Natural Science Foundation of China (51074205);Corporate Research Centre for Greenhouse Gas Technology Foundation in Australia

CO₂ Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers

徐冬¹, Penny Xiao², 李刚², 张军², Paul Webley², 翟玉春³

1. Guodian New Energy Technology Research Institute, China Guodian Corporation, Beijing 100034, China;
2. Department of Chemical Engineering, Monash University, Melbourne 3186, Australia;
3. School of Material and Metallurgy, Northeastern University, Shenyang 110004, China

通讯作者: XU Dong,E-mail:e3e4sun@gmail.com
基金资助:
Supported by the National Natural Science Foundation of China (51074205);Corporate Research Centre for Greenhouse Gas Technology Foundation in Australia

Abstract

Abstract: In order to solve the water issues when 13X zeolite was applied to capture CO₂ from wet flue gas by vacuum swing adsorption process, multi-layered adsorption system was considered regarding activated alumina F200 and silica gel based Sorbead WS as pre-layer materials. LBET (extended Largmuir-BET) model and extended CMMS (cooperative multimolecular sorption) equation were simulated respectively to describe water loading on F200 and Sorbead WS. The two equations can be well added into our in-house simulator to simulate double-layered CO₂-VSA (vacuum swing adsorption) process. Results indicated that water can be successfully stopped in pre-layers with a good CO₂ capture performance.

Key words: CO₂ capture, vacuum swing adsorption, multi-layered adsorption, water vapor

摘要： In order to solve the water issues when 13X zeolite was applied to capture CO₂ from wet flue gas by vacuum swing adsorption process, multi-layered adsorption system was considered regarding activated alumina F200 and silica gel based Sorbead WS as pre-layer materials. LBET (extended Largmuir-BET) model and extended CMMS (cooperative multimolecular sorption) equation were simulated respectively to describe water loading on F200 and Sorbead WS. The two equations can be well added into our in-house simulator to simulate double-layered CO₂-VSA (vacuum swing adsorption) process. Results indicated that water can be successfully stopped in pre-layers with a good CO₂ capture performance.

关键词: CO₂ capture, vacuum swing adsorption, multi-layered adsorption, water vapor

XU Dong, Penny Xiao, LI Gang, ZHANG Jun, Paul Webley, ZHAI Yuchun. CO₂ Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers[J]. Chin.J.Chem.Eng., 2012, 20(5): 849-855.

徐冬, Penny Xiao, 李刚, 张军, Paul Webley, 翟玉春. CO₂ Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers[J]. Chinese Journal of Chemical Engineering, 2012, 20(5): 849-855.

References

1 McKibbin W.J.,Shackleton,R.,Wilcoxen,P.J.,"What to expect from an international system of tradable permits for carbon emissions",Resource and Energy Economics,21 (3),319-346 (1999).
2 Anderson,S.,Newell,R.,"Prospects for carbon capture and storage technologies",Annual Review of Environment and Resources,29,109-142 (2004).
3 Zhang,Z.,Ruan,H.,Zhou,Y.,Su,W.,Sun,Y.,Zhou,L.,"A research note on the adsorption of CO₂ and N₂",Chin.J.Chem.Eng.,19 (5),733-737 (2011).
4 Li,G.,Xiao,P.,Webley,P.,Zhang,J.,"Capture of CO₂ from high humidity flue gas by vacuum swing adsorption with zeolite 13X",Adsorption,14,415-422 (2008).
5 Saha,D.,Deng,S.,"Adsorption equilibria and kinetics of carbon monoxide on zeolite 5A,13X,MOF-5,and MOF-177",J.Chem.Eng.Data,54,2245-2250 (2009).
6 Wang,J.,Zhang,Y.,Ma,Y.,Li,H.,Tang,T.,"adsorption equilibrium of ethylene-carbon dioxide mixture on zeolite ZSMS and its correlation",Chin.J.Chem.Eng.,7 (2),208-215 (1992).
7 Zhang,J.,Xiao,P.,Li,G.,Webley,P.,"Effect of flue gas impurities on CO₂ capture performance from flue gas at coal-fired power stations by vacuum swing adsorption",Energy Procedia,1,1115-1122 (2009).
8 CortØs,F.B.,Chejne,F.,Carrasco-Marín,F.,Moreno-Castilla,C.,PØrez-Cadenas,A.F.,"Water adsorption on zeolite 13X: comparison of the two methods based on mass spectrometry and thermogravimetry",Adsorption,16 (3),141-146 (2010).
9 Serbezov,A.,"Adsorption equilibrium of water vapor on F-200 activated alumina",J.Chem.Eng.Data,48,421-425 (2003).
10 Yang,H.J.,Fan,S.S.,Lang,X.M.,Wang,Y.H.,Nie,J.H.,"Economic comparison of three gas separation technologies for CO₂ capture from power plant flue gas",Chin.J.Chem.Eng.,19 (4),615-620 (2011).
11 Takamura,Y.,Narita,S.,Aoki,J.,Hironaka,S.,Uchid,S.,"Evaluation of dual-bed pressure swing adsorption for CO₂ recovery from boiler exhaust gas",Sep.Purif.Technol.,24,519-528 (2001).
12 Webley,P.A.,He,J.,"Fast solution-adaptive finite volume method for PSA/VSA cycle simulation; 1 single step simulation",Comput.Chem.Eng.,23,1701-1712 (2000).
13 Todd,R.S.,Ferraris,G.B.,Manca,D.,Webley,P.A.,"Improved ODE integrator and mass transfer approach for simulating a cyclic adsorption process",Comput.Chem.Eng.,27,883-892 (2003).
14 Rutherford,S.W.,"Probing the mechanism of water adsorption incarbon micropores with multitemperature isotherms and water pre-adsorption experiments",Langmuir,22 (24),9967-9975 (2006).
15 Li,G.,Xiao,P.,Webley,P.,"Binary adsorption equilibrium of carbon dioxide and water vapor on activated alumina",Langmuir,25,10666-10675 (2009).
16 Siripatrawan,U.,Jantawat,P.,"Determination of moisture sorption isotherms of jasmine rice crackers using BET and GAB models",Food Sci.Technol.Int.,12,459-467 (2006).
17 Timmermann,E.O.,Chirife,J.,Iglesias,H.A.,"Water sorption isotherms of foods and foodstuffs: BET or GAB parameters?",Journal of Food Engineering,48,19-31 (2001).
18 Sircar,S.,Cao,D.V.,"Review: Heat of adsorption",Chem.Eng.Technol.,25,945-948 (2002).
19 Schoenab,M.,Gunthera,G.,"Capillary condensation in deformable mesopores: wetting versus nanomechanics",Molecular Physics,18,1-13 (2010).
20 Desai,R.,Hussain,M.,Ruthven,D.M.,"Adsorption of water vapor on activated alumina,I-equilibrium behaviour",Can.J.Chem.Eng.,70,699-706 (1992).
21 Kotoh,K.,Enoeda,M.,Matsui,T.,Nishikawa,M.,"A multilayer model for adsorption of water on activated alumina in relation to adsorption potential",J.Chem.Eng.Jpn.,26,355-360 (1993).
22 Zheng,Z.Z.,Ruan,H.Z.,Zhou,Y.P.,Su,W.,Sun,Y.,Zhou,L.,"A research note on the adsorption of CO₂ and N₂ ",Chin.J.Chem.Eng,19 (5),733-737 (2011).
23 Li,P.,Tezel,F.H.,"Equilibrium and kinetic analysis of CO₂-N₂ adsorption separation by concentration pulse chromatography",Journal of Colloid and Interface Science,313,12-17 (2007).

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CO₂ Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers

CO₂ Capture by Vacuum Swing Adsorption Using F200 and Sorbead WS as Protective Pre-layers

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