Ni/bentonite catalysts prepared by solution combustion method for CO2 methanation

doi:10.1016/j.cjche.2018.03.029

Chin.J.Chem.Eng. ›› 2018, Vol. 26 ›› Issue (11): 2361-2367.DOI: 10.1016/j.cjche.2018.03.029

• Special issue of Carbon Capture, Utilisation and Storage • Previous Articles Next Articles

Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation

Yuexiu Jiang¹, Tongxia Huang¹, Lihui Dong¹, Zuzeng Qin¹, Hongbing Ji^1,2

1 School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Electrochemical Energy Materials, Guangxi University, Nanning 530004, China;
2 School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

Received:2017-12-24 Revised:2018-03-20 Online:2018-12-10 Published:2018-11-28
Contact: Zuzeng Qin, Hongbing Ji
Supported by:
Supported by the National Natural Science Foundation of China (21566005), the Natural Science Foundation of Guangxi Province (2016GXNSFFA380015).

Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation

Yuexiu Jiang¹, Tongxia Huang¹, Lihui Dong¹, Zuzeng Qin¹, Hongbing Ji^1,2

1 School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Electrochemical Energy Materials, Guangxi University, Nanning 530004, China;
2 School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

通讯作者: Zuzeng Qin, Hongbing Ji
基金资助:
Supported by the National Natural Science Foundation of China (21566005), the Natural Science Foundation of Guangxi Province (2016GXNSFFA380015).

Abstract

Abstract: A 20 wt% Ni/bentonite catalyst was prepared by a solution combustion synthesis (SCS), which exhibited higher activity for the CO₂ methanation than that of an impregnation method (IPM), and the catalyst prepared by SCS showed a CO₂ conversion of 85% and a CH₄ selectivity of 100% at 300℃, atmospheric pressure, and 3600 ml·(g cat)^-1·h^-1, and the catalyst exhibited stable within a 110-h reaction. The results showed higher metallic Ni dispersion, smaller Ni particle size, larger specific surface area and lower reduction temperature in the Ni/bentonite prepared by SCS than that of IPM. And the Ni/bentonite prepared by the SCS moderated the interaction between NiO and bentonite.

Key words: CO₂ methanation, Ni/bentonite catalyst, Solution combustion synthesis, Impregnation method

摘要： A 20 wt% Ni/bentonite catalyst was prepared by a solution combustion synthesis (SCS), which exhibited higher activity for the CO₂ methanation than that of an impregnation method (IPM), and the catalyst prepared by SCS showed a CO₂ conversion of 85% and a CH₄ selectivity of 100% at 300℃, atmospheric pressure, and 3600 ml·(g cat)^-1·h^-1, and the catalyst exhibited stable within a 110-h reaction. The results showed higher metallic Ni dispersion, smaller Ni particle size, larger specific surface area and lower reduction temperature in the Ni/bentonite prepared by SCS than that of IPM. And the Ni/bentonite prepared by the SCS moderated the interaction between NiO and bentonite.

关键词: CO₂ methanation, Ni/bentonite catalyst, Solution combustion synthesis, Impregnation method

Yuexiu Jiang, Tongxia Huang, Lihui Dong, Zuzeng Qin, Hongbing Ji. Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation[J]. Chin.J.Chem.Eng., 2018, 26(11): 2361-2367.

Yuexiu Jiang, Tongxia Huang, Lihui Dong, Zuzeng Qin, Hongbing Ji. Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation[J]. Chinese Journal of Chemical Engineering, 2018, 26(11): 2361-2367.

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Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation

Ni/bentonite catalysts prepared by solution combustion method for CO₂ methanation

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