Potential-aided recovery of iodide using 2-D nanosheet CuxO coating polymer/graphene/carbon fibers composite

doi:10.1016/j.cjche.2019.11.010

Abstract

Abstract: 2-D nanosheet Cu₂O doped CuO coating poly m-phenylenediamine and melamine/graphene/carbon fibers composite (Cu_xO/MPM/GFs) was firstly fabricated by compound electrochemical method. Cu_xO/MPM/GFs was successfully used to the recovery of iodide (I-) from salt water by lower potential-aided sorption and desorption processes. The potential-aided recovery of I^- at Cu_xO/MPM/GFs was characterized by FE-SEM, XRD, IR, Raman, XPS, UV-vis and electrochemical techniques in detail. The maximal adsorption capacity of 86.82 mg·g^-1 could be obtained with a pseudo-second-order model at 0.8 V for 210 min in pH 5.0, 0.1 mol·L^-1 NaCl, and the process accompanied the generation of CuI, CuO and I^5-. The I^- could be quickly desorbed from the electrode with a transfer of CuI to Cu₂O by cycle voltammetry from -1.0 to 0.5 V for 90 cycles in pH 9.0, 0.1 mol·L^-1 KNO₃. Thus, Cu_xO/MPM/GFs was renewable in the continuous electrochemical-adsorption-desorption processes.

Key words: Potential-aided recovery, Iodide, Cu₂O, Carbon fibers composite

摘要： 2-D nanosheet Cu₂O doped CuO coating poly m-phenylenediamine and melamine/graphene/carbon fibers composite (Cu_xO/MPM/GFs) was firstly fabricated by compound electrochemical method. Cu_xO/MPM/GFs was successfully used to the recovery of iodide (I-) from salt water by lower potential-aided sorption and desorption processes. The potential-aided recovery of I^- at Cu_xO/MPM/GFs was characterized by FE-SEM, XRD, IR, Raman, XPS, UV-vis and electrochemical techniques in detail. The maximal adsorption capacity of 86.82 mg·g^-1 could be obtained with a pseudo-second-order model at 0.8 V for 210 min in pH 5.0, 0.1 mol·L^-1 NaCl, and the process accompanied the generation of CuI, CuO and I^5-. The I^- could be quickly desorbed from the electrode with a transfer of CuI to Cu₂O by cycle voltammetry from -1.0 to 0.5 V for 90 cycles in pH 9.0, 0.1 mol·L^-1 KNO₃. Thus, Cu_xO/MPM/GFs was renewable in the continuous electrochemical-adsorption-desorption processes.

关键词: Potential-aided recovery, Iodide, Cu₂O, Carbon fibers composite

Yexiao Yu, Guanping Jin, Yuhong Fang, Zheng Xu, Xiaoyuan Lü, Chunnian Chen. Potential-aided recovery of iodide using 2-D nanosheet Cu_xO coating polymer/graphene/carbon fibers composite[J]. Chinese Journal of Chemical Engineering, 2020, 28(4): 1046-1054.

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Potential-aided recovery of iodide using 2-D nanosheet Cu_xO coating polymer/graphene/carbon fibers composite

Potential-aided recovery of iodide using 2-D nanosheet Cu_xO coating polymer/graphene/carbon fibers composite

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