Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions

doi:10.1016/j.cjche.2022.05.014

Chinese Journal of Chemical Engineering ›› 2022, Vol. 49 ›› Issue (9): 161-169.DOI: 10.1016/j.cjche.2022.05.014

• Regular • Previous Articles Next Articles

Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions

Fengfeng Gao¹, Jinhua Luo², Xuefeng Zhang¹, Xiaogang Hao¹, Guoqing Guan³, Zhong Liu⁴, Jun Li⁴, Qinglong Luo⁴

1. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
2. Information Management Division, Pingyang County Economic and Information Bureau, Wenzhou 325400, China;
3. Energy Conversion Engineering Group, Institute of Regional Innovation (IRI), Hirosaki University, 2-1-3 Matsubara, Aomori 030-0813, Japan;
4. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China

Received:2022-01-12 Revised:2022-04-24 Online:2022-10-19
Contact: Xiaogang Hao,E-mail:xghao@tyut.edu.cn;Guoqing Guan,E-mail:guan@hirosaki-u.ac.jp
Supported by:
This work is supported by the National Natural Science Foundation of China (U21A20303, 22108188, U20A20141), the National Key Research and Development Program of China (2017YFE0129200), the Natural Science Foundation of Shanxi Province (201901D211054) and JSPS KAKENHI Grant 19K12395, Japan.

Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions

Fengfeng Gao¹, Jinhua Luo², Xuefeng Zhang¹, Xiaogang Hao¹, Guoqing Guan³, Zhong Liu⁴, Jun Li⁴, Qinglong Luo⁴

1. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
2. Information Management Division, Pingyang County Economic and Information Bureau, Wenzhou 325400, China;
3. Energy Conversion Engineering Group, Institute of Regional Innovation (IRI), Hirosaki University, 2-1-3 Matsubara, Aomori 030-0813, Japan;
4. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China

通讯作者: Xiaogang Hao,E-mail:xghao@tyut.edu.cn;Guoqing Guan,E-mail:guan@hirosaki-u.ac.jp
基金资助:
This work is supported by the National Natural Science Foundation of China (U21A20303, 22108188, U20A20141), the National Key Research and Development Program of China (2017YFE0129200), the Natural Science Foundation of Shanxi Province (201901D211054) and JSPS KAKENHI Grant 19K12395, Japan.

Abstract

Abstract: Effective extraction and regeneration of radioactive iodide is one of urgent concerns for the safe utilization of nuclear energy. As a novel environmentally benign ion separation technique, electrochemically switched ion extraction (ESIE) process can be applied for effective capture and recovery of iodide ions (I^-). Herein, a novel kelp seaweed-like core/shell I^- imprinted polypyrrole@bismuth oxyiodide (PPy/I^-@BiOI) composite film is successfully prepared for the selective I^- capture in the ESIE system. It is found that the I^- can be easily trapped in the PPy/I^-@BiOI film after I^- is in situ desorbed from the film by an electrochemical reduction process since it offers particular electroactive binding sites for I^- extraction. The I^- imprinted PPy/I^-@BiOI film displays an extraction capacity as high as 325.2 mg·g^-1 for I^- with favorable stability. In particular, the extraction and desorption of I^- is achieved by adjusting the redox potential and the pristine PPy/I^-@BiOI film can be regenerated and reused for multiple times without decrease in extraction capacity. It is expected that such a PPy/I^-@BiOI film would be useful as an electrochemically switched renewable extractor that could capture and regenerate I^- from radioactive water.

Key words: Electrochemically switched ion extraction, PPy/I^-@BiOI film, Radioactive iodide ion, Separation, Selectivity, Electrochemistry

摘要： Effective extraction and regeneration of radioactive iodide is one of urgent concerns for the safe utilization of nuclear energy. As a novel environmentally benign ion separation technique, electrochemically switched ion extraction (ESIE) process can be applied for effective capture and recovery of iodide ions (I^-). Herein, a novel kelp seaweed-like core/shell I^- imprinted polypyrrole@bismuth oxyiodide (PPy/I^-@BiOI) composite film is successfully prepared for the selective I^- capture in the ESIE system. It is found that the I^- can be easily trapped in the PPy/I^-@BiOI film after I^- is in situ desorbed from the film by an electrochemical reduction process since it offers particular electroactive binding sites for I^- extraction. The I^- imprinted PPy/I^-@BiOI film displays an extraction capacity as high as 325.2 mg·g^-1 for I^- with favorable stability. In particular, the extraction and desorption of I^- is achieved by adjusting the redox potential and the pristine PPy/I^-@BiOI film can be regenerated and reused for multiple times without decrease in extraction capacity. It is expected that such a PPy/I^-@BiOI film would be useful as an electrochemically switched renewable extractor that could capture and regenerate I^- from radioactive water.

关键词: Electrochemically switched ion extraction, PPy/I^-@BiOI film, Radioactive iodide ion, Separation, Selectivity, Electrochemistry

Fengfeng Gao, Jinhua Luo, Xuefeng Zhang, Xiaogang Hao, Guoqing Guan, Zhong Liu, Jun Li, Qinglong Luo. Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions[J]. Chinese Journal of Chemical Engineering, 2022, 49(9): 161-169.

References

[1] X.Y. Zhang, P. Gu, X.Y. Li, G.H. Zhang, Efficient adsorption of radioactive iodide ion from simulated wastewater by nano Cu₂O/Cu modified activated carbon, Chem. Eng. J. 322 (2017) 129-139. 10.1016/j.cej.2017.03.102
[2] D.K.L. Harijan, V. Chandra, T. Yoon, K.S. Kim, Radioactive iodine capture and storage from water using magnetite nanoparticles encapsulated in polypyrrole, J. Hazard. Mater. 344 (2018) 576-584. 10.1016/j.jhazmat.2017.10.065
[3] Y.Z. Tang, H.L. Huang, J. Li, W.J. Xue, C.L. Zhong, IL-induced formation of dynamic complex iodide anions in IL@MOF composites for efficient iodine capture, J. Mater. Chem. A 7 (31) (2019) 18324-18329. 10.1039/c9ta04408f
[4] X.P. Yu, W.J. Cui, F. Zhang, Y.F. Guo, T.L. Deng, Removal of iodine from the salt water used for caustic soda production by ion-exchange resin adsorption, Desalination 458 (2019) 76-83. 10.1016/j.desal.2019.02.006
[5] Y. Feng, P.F. Yang, Y.S. Li, J.L. Gu, AgNPs-containing metal-organic frameworks for the effective adsorption and immobilization of radioactive iodine, J. Chem. Eng. Data 65 (4) (2020) 1986-1992. 10.1021/acs.jced.9b01146
[6] K. Watson, M.J. Farré, N. Knight, Strategies for the removal of halides from drinking water sources, and their applicability in disinfection by-product minimisation:a critical review, J. Environ. Manage. 110 (2012) 276-298.https://pubmed.ncbi.nlm.nih.gov/22810000/
[7] J.H. Luo, X. Du, F.F. Gao, Y.Y. Yang, X.Q. Hao, S.S. Li, X.G. Hao, K.Y. Tang, G.Q. Guan, Iodide ion trapping polypyrrole film:selective capture of iodide ions by electrochemically switched ion extraction (ESIE) process, Chem. Eng. J. 380 (2020) 122529. 10.1016/j.cej.2019.122529
[8] J.H. Luo, X. Du, F.F. Gao, P.F. Ma, X.G. Hao, G.Q. Guan, O. Scialdone, J. Li, Electrochemically triggered iodide-vacancy BiOI film for selective extraction of iodide ion from aqueous solutions, Sep. Purif. Technol. 259 (2021) 118120. 10.1016/j.seppur.2020.118120
[9] M. Karthikeyan, K.K. Satheeshkumar, K.P. Elango, Removal of fluoride ions from aqueous solution by conducting polypyrrole, J. Hazard. Mater. 167 (1-3) (2009) 300-305.https://pubmed.ncbi.nlm.nih.gov/19233561/
[10] S. Zhang, Y.Y. Shao, J. Liu, I.A. Aksay, Y.H. Lin, Graphene-polypyrrole nanocomposite as a highly efficient and low cost electrically switched ion exchanger for removing ClO₄^- from wastewater, ACS Appl. Mater. Interfaces 3 (9) (2011) 3633-3637. 10.1021/am200839m
[11] W.W. Ji, J.J. Niu, W. Zhang, X. Li, W.J. Yan, X.G. Hao, Z.D. Wang, An electroactive ion exchange hybrid film with collaboratively-driven ability for electrochemically-mediated selective extraction of chloride ions, Chem. Eng. J. 427 (2022) 130807. 10.1016/j.cej.2021.130807
[12] J.H. Luo, X. Du, F.F. Gao, H.X. Kong, X.G. Hao, A. Abudula, G.Q. Guan, X.L. Ma, B. Tang, An electrochemically switchable triiodide-ion-imprinted PPy membrane for highly selective recognition and continuous extraction of iodide, Sep. Purif. Technol. 251 (2020) 117312. 10.1016/j.seppur.2020.117312
[13] W.B. Ma, X. Du, M.M. Liu, F.F. Gao, X.L. Ma, Y.G. Li, G.Q. Guan, X.G. Hao, A conductive chlorine ion-imprinted polymer threaded in metal-organic frameworks for electrochemically selective separation of chloride ions, Chem. Eng. J. 412 (2021) 128576. 10.1016/j.cej.2021.128576
[14] Hiratani T, Hamad WY, MacLachlan MJ, Transparent depolarizing organic and inorganic films for optics and sensors, Adv. Mater. 29 (13) (2017) 2017Apr;29(13).https://pubmed.ncbi.nlm.nih.gov/28128872/
[15] L.H. Ai, Y. Zeng, J. Jiang, Hierarchical porous BiOI architectures:Facile microwave nonaqueous synthesis, characterization and application in the removal of Congo red from aqueous solution, Chem. Eng. J. 235 (2014) 331-339. 10.1016/j.cej.2013.09.046
[16] N. Talreja, M. Ashfaq, D. Chauhan, A.C. Mera, C.A. Rodríguez, Strategic doping approach of the Fe-BiOI microstructure:an improved photodegradation efficiency of tetracycline, ACS Omega 6 (2) (2021) 1575-1583. 10.1021/acsomega.0c05398
[17] S.H. Ma, X. Luo, G. Ran, Y.P. Li, Z.Q. Cao, X.Y. Liu, G.Q. Chen, J.H. Yan, L. Wang, Defect engineering of ultrathin 2D nanosheet BiOI/Bi for enhanced photothermal-catalytic synergistic bacteria-killing, Chem. Eng. J. 435 (2022) 134810. 10.1016/j.cej.2022.134810
[18] R.F. Dong, Y. Hu, Y.F. Wu, W. Gao, B.Y. Ren, Q.L. Wang, Y.P. Cai, Visible-light-driven BiOI-based Janus micromotor in pure water, J. Am. Chem. Soc. 139 (5) (2017) 1722-1725. 10.1021/jacs.6b09863
[19] J.W. Bai, Y. Li, P.K. Wei, J.D. Liu, W. Chen, L. Liu, Enhancement of photocatalytic activity of Bi₂ O₃-BiOI composite nanosheets through vacancy engineering, Small 15 (23) (2019) e1900020.https://pubmed.ncbi.nlm.nih.gov/31018044/
[20] S. Vadivel, B. Saravanakumar, M. Kumaravel, D. Maruthamani, N. Balasubramanian, A. Manikandan, G. Ramadoss, B. Paul, S. Hariganesh, Facile solvothermal synthesis of BiOI microsquares as a novel electrode material for supercapacitor applications, Mater. Lett. 210 (2018) 109-112. 10.1016/j.matlet.2017.08.137
[21] D.M. Chen, J.J. Yang, Y. Zhu, Y.M. Zhang, Y.F. Zhu, Fabrication of BiOI/graphene Hydrogel/FTO photoelectrode with 3D porous architecture for the enhanced photoelectrocatalytic performance, Appl. Catal. B Environ. 233 (2018) 202-212. 10.1016/j.apcatb.2018.04.004
[22] Q.Z. Wang, L.H. Zheng, Y.T. Chen, J.F. Fan, H.H. Huang, B.T. Su, Synthesis and characterization of novel PP_y/Bi₂O₂CO₃ composite with improved photocatalytic activity for degradation of Rhodamine-B, J. Alloys Compd. 637 (2015) 127-132. 10.1016/j.jallcom.2015.02.201
[23] L.X. Jiang, C.W. Dong, B. Jin, Z. Wen, Q. Jiang, ZnFe₂O₄@PP_y core-shell structure for high-rate lithium-ion storage, J. Electroanal. Chem. 851 (2019) 113442. 10.1016/j.jelechem.2019.113442
[24] X.S. Xu, Y.Q. Qiu, J.P. Wu, B.C. Ding, Q.H. Liu, G.S. Jiang, Q.Q. Lu, J.G. Wang, F. Xu, H.Q. Wang, Porous nitrogen-enriched hollow carbon nanofibers as freestanding electrode for enhanced lithium storage, Chin. J. Chem. Eng. 32 (2021) 416-422. 10.1016/j.cjche.2020.09.055
[25] J.J. Dong, Y. Lin, H.W. Zong, H.B. Yang, Hierarchical LiFe₅O₈@PP_y core-shell nanocomposites as electrode materials for supercapacitors, Appl. Surf. Sci. 470 (2019) 1043-1052. 10.1016/j.apsusc.2018.11.204
[26] J.X. Gao, T.F. Wang, Q. Shu, Z. Nawaz, Q. Wen, D.Z. Wang, J.F. Wang, An adsorption kinetic model for sulfur dioxide adsorption by ZL50 activated carbon, Chin. J. Chem. Eng. 18 (2) (2010) 223-230. 10.1016/S1004-9541(08)60346-8
[27] L. Kentjono, J.C. Liu, W.C. Chang, C. Irawan, Removal of boron and iodine from optoelectronic wastewater using Mg-Al (NO₃) layered double hydroxide, Desalination 262 (1-3) (2010) 280-283. 10.1016/j.desal.2010.06.015
[28] S.L. Liao, C.F. Xue, Y.H. Wang, J.L. Zheng, X.G. Hao, G.Q. Guan, A. Abuliti, H. Zhang, G.Z. Ma, Simultaneous separation of iodide and cesium ions from dilute wastewater based on PPy/PTCF and NiHCF/PTCF electrodes using electrochemically switched ion exchange method, Separ. Purif. Technol. 139 (2015) 63-69
[29] A. Bo, S. Sarina, Z.F. Zheng, D.J. Yang, H.W. Liu, H.Y. Zhu, Removal of radioactive iodine from water using Ag₂O grafted titanate nanolamina as efficient adsorbent, J. Hazard. Mater. 246-247 (2013) 199-205

Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions

Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Pan Wang, Mengdei Zhou, Zhuangxin Wei, Lu Liu, Tao Cheng, Xiaohua Tian, Jianming Pan. Preparation of bowl-shaped polydopamine surface imprinted polymer composite adsorbent for specific separation of 2′-deoxyadenosine [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 69-79.
[2]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 205-211.
[3]	Hammad Saulat, Jianhua Yang, Tao Yan, Waseem Raza, Wensen Song, Gaohong He. Tungsten incorporated mobil-type eleven zeolite membranes: Facile synthesis and tuneable wettability for highly efficient separation of oil/water mixtures [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 242-252.
[4]	Jindong Dai, Chi Zhai, Jiali Ai, Guangren Yu, Haichao Lv, Wei Sun, Yongzhong Liu. A cellular automata framework for porous electrode reconstruction and reaction-diffusion simulation [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 262-274.
[5]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 9-15.
[6]	Borui Liu, Tao Zhang, Yi Zheng, Kailong Li, Hui Pan, Hao Ling. A dynamic control structure of liquid-only transfer stream distillation column [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 135-145.
[7]	Qunfeng Zhang, Bingcheng Li, Yuan Zhou, Deshuo Zhang, Chunshan Lu, Feng Feng, Jinghui Lv, Qingtao Wang, Xiaonian Li. Regulation of the selective hydrogenation performance of sulfur-doped carbon-supported palladium on chloronitrobenzene [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 69-75.
[8]	Yafei Su, Xuke Zhang, Hui Li, Donglai Peng, Yatao Zhang. In-situ incorporation of halloysite nanotubes with 2D zeolitic imidazolate framework-L based membrane for dye/salt separation [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 103-111.
[9]	Shuangtai Liu, Lei He, Qiuxiang Yao, Xi Li, Linyang Wang, Jing Wang, Ming Sun, Xiaoxun Ma. Separation and analysis of six fractions in low temperature coal tar by column chromatography [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 256-265.
[10]	Wende Tian, Jiawei Zhang, Zhe Cui, Haoran Zhang, Bin Liu. Microscopic mechanism study and process optimization of dimethyl carbonate production coupled biomass chemical looping gasification system [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 291-305.
[11]	Hui Yi Leong, Xiao-Qian Fu, Xiang-Yu Liu, Shan-Jing Yao, Dong-Qiang Lin. Characterisation and separation of infectious bursal disease virus-like particles using aqueous two-phase systems [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 72-78.
[12]	Yueting Shi, Junhai Zhao, Lingli Chen, Hongru Li, Shengtao Zhang, Fang Gao. Double open mouse-like terpyridine parts based amphiphilic ionic molecules displaying strengthened chemical adsorption for anticorrosion of copper in sulfuric acid solution [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 233-246.
[13]	Yujia Cui, Zhiqiang Tan, Yanan Wang, Shuxian Shi, Xiaonong Chen. One-step crosslinking preparation of tannic acid particles for the adsorption and separation of cationic dyes [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 309-318.
[14]	Shanshan Mao, Tao Shen, Qing Zhao, Tong Han, Fan Ding, Xin Jin, Manglai Gao. Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 319-328.
[15]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 273-280.