Abstract: Adsorption capacity of activated carbon prepared from spent tea leaves (STL-AC) for the removal of aspirin from aqueous solution was investigated in this study. Preliminary studies have shown that treatment with phosphoric acid (H₃PO₄) increased removal efficiency of STL-AC. Characterizations on STL-AC revealed excellent textural properties (1200 m²·g^-1, 51% mesoporosity), as well as distinctive surface chemistry (1.08 mmol·g^-1 and 0.54 mmol·g^-1 for acidic and basic oxygenated groups, pH_pzc=2.02). Maximum removal efficiency of aspirin observed was 94.28% after 60 min when the initial concentration was 100 mg·L^-1, 0.5 g of adsorbent used, pH 3 and at a temperature of 30℃. The adsorption data were well fitted to the Freundlich isotherm model and obeyed the pseudo-second order kinetics model. The adsorption of aspirin onto STL-AC was exothermic in nature (ΔH^Θ=-13.808 kJ·mol^-1) and had a negative entropy change, ΔS^Θ (-41.444 J·mol^-1). A negative Gibbs free energy, ΔG^Θ was obtained indicating feasibility and spontaneity of the adsorption process. The adsorption capacity of AC-STL (178.57 mg·g^-1) is considerably high compared to most adsorbents synthesized from various sources, due to the well-defined textural properties coupled with surface chemistry of STL-AC which favors aspirin adsorption. The results demonstrate the potential of STL-AC as aspirin adsorbent.

Key words: Activated carbon, Spent tea leaves, Aspirin, Adsorption, Kinetics, Isotherm

摘要： Adsorption capacity of activated carbon prepared from spent tea leaves (STL-AC) for the removal of aspirin from aqueous solution was investigated in this study. Preliminary studies have shown that treatment with phosphoric acid (H₃PO₄) increased removal efficiency of STL-AC. Characterizations on STL-AC revealed excellent textural properties (1200 m²·g^-1, 51% mesoporosity), as well as distinctive surface chemistry (1.08 mmol·g^-1 and 0.54 mmol·g^-1 for acidic and basic oxygenated groups, pH_pzc=2.02). Maximum removal efficiency of aspirin observed was 94.28% after 60 min when the initial concentration was 100 mg·L^-1, 0.5 g of adsorbent used, pH 3 and at a temperature of 30℃. The adsorption data were well fitted to the Freundlich isotherm model and obeyed the pseudo-second order kinetics model. The adsorption of aspirin onto STL-AC was exothermic in nature (ΔH^Θ=-13.808 kJ·mol^-1) and had a negative entropy change, ΔS^Θ (-41.444 J·mol^-1). A negative Gibbs free energy, ΔG^Θ was obtained indicating feasibility and spontaneity of the adsorption process. The adsorption capacity of AC-STL (178.57 mg·g^-1) is considerably high compared to most adsorbents synthesized from various sources, due to the well-defined textural properties coupled with surface chemistry of STL-AC which favors aspirin adsorption. The results demonstrate the potential of STL-AC as aspirin adsorbent.

关键词: Activated carbon, Spent tea leaves, Aspirin, Adsorption, Kinetics, Isotherm