The performance of activated carbon/NiFe2O4 magnetic composite to retain heavy metal ions from aqueous solution

doi:10.1016/j.cjche.2020.07.036

Abstract

Abstract: A novel magnetic activated carbon composite (AC/NiF) was synthesized by a precipitation method and applied in retention of Cu(Ⅱ), and Zn(Ⅱ) ions from aqueous solutions. The impact of different sorption parameters such as: equilibration time, solution pH value, competing cations and ionic strength on the amount sorbed of Cu(Ⅱ), and Zn(Ⅱ) was clarified. Results illustrated that the magnetic composite had retention ability towards both metal ions significantly higher than that of activated carbon (AC). The magnetic composite exhibited an affinity to adsorb Cu(Ⅱ) higher than Zn(Ⅱ) ions. The maximum sorption capacities (Q_max) of the applied magnetic composite (AC/NiF) towards Cu(Ⅱ) and Zn(Ⅱ) were 105.8 and 75.1 mg·g^-1, respectively. Retention of Cu(Ⅱ) and Zn(Ⅱ) was proposed to be achieved though an ion exchange and surface adsorption in neutral conditions, while precipitation was believed to be the relevant mechanism in their removal from basic solutions. The kinetic studies showed that sorption process followed the kinetics of pseudo-second-order reactions with rate constant of 3 × 10^-3 and 2 × 10^-3 min^-1 for sorption of Cu(Ⅱ) and Zn(Ⅱ) onto AC/NiF composite. Removal of Cu(Ⅱ) slightly decreased with increasing the ionic strength of aqueous solution, using NaCl as a background electrolyte. In contrast, presence of Mn(Ⅱ), Mg(Ⅱ) and Co(Ⅱ) in reaction solutions highly depressed the sorption of Cu(Ⅱ) and Zn(Ⅱ) with a competing efficiency followed the order: Mg(Ⅱ) > Mn(Ⅱ) > Co(Ⅱ).The magnetic composite was rapidly recovered from aqueous solution by an external magnetic field, and effectively regenerated using 0.1 mol·L^-1 HCl and 0.1 mol·L^-1 FeCl₃ as eluents. Sorption of Cu(Ⅱ) and Zn(Ⅱ) onto the surface of AC/NiF composite occurred via a spontaneous reaction. And thermodynamically favorable process had ΔH^o values of 30.9 kJ·mol^-1 and 19.7 kJ·mol^-1, respectively. The results confirm that the magnetic composite can be viewed as a promising novel composite opens new opportunities for the attainment of required adsorption and operative magnetic separation.

Key words: Activated carbon, Nickel ferrite, Composite, Mechanism

摘要： A novel magnetic activated carbon composite (AC/NiF) was synthesized by a precipitation method and applied in retention of Cu(Ⅱ), and Zn(Ⅱ) ions from aqueous solutions. The impact of different sorption parameters such as: equilibration time, solution pH value, competing cations and ionic strength on the amount sorbed of Cu(Ⅱ), and Zn(Ⅱ) was clarified. Results illustrated that the magnetic composite had retention ability towards both metal ions significantly higher than that of activated carbon (AC). The magnetic composite exhibited an affinity to adsorb Cu(Ⅱ) higher than Zn(Ⅱ) ions. The maximum sorption capacities (Q_max) of the applied magnetic composite (AC/NiF) towards Cu(Ⅱ) and Zn(Ⅱ) were 105.8 and 75.1 mg·g^-1, respectively. Retention of Cu(Ⅱ) and Zn(Ⅱ) was proposed to be achieved though an ion exchange and surface adsorption in neutral conditions, while precipitation was believed to be the relevant mechanism in their removal from basic solutions. The kinetic studies showed that sorption process followed the kinetics of pseudo-second-order reactions with rate constant of 3 × 10^-3 and 2 × 10^-3 min^-1 for sorption of Cu(Ⅱ) and Zn(Ⅱ) onto AC/NiF composite. Removal of Cu(Ⅱ) slightly decreased with increasing the ionic strength of aqueous solution, using NaCl as a background electrolyte. In contrast, presence of Mn(Ⅱ), Mg(Ⅱ) and Co(Ⅱ) in reaction solutions highly depressed the sorption of Cu(Ⅱ) and Zn(Ⅱ) with a competing efficiency followed the order: Mg(Ⅱ) > Mn(Ⅱ) > Co(Ⅱ).The magnetic composite was rapidly recovered from aqueous solution by an external magnetic field, and effectively regenerated using 0.1 mol·L^-1 HCl and 0.1 mol·L^-1 FeCl₃ as eluents. Sorption of Cu(Ⅱ) and Zn(Ⅱ) onto the surface of AC/NiF composite occurred via a spontaneous reaction. And thermodynamically favorable process had ΔH^o values of 30.9 kJ·mol^-1 and 19.7 kJ·mol^-1, respectively. The results confirm that the magnetic composite can be viewed as a promising novel composite opens new opportunities for the attainment of required adsorption and operative magnetic separation.

关键词: Activated carbon, Nickel ferrite, Composite, Mechanism

S. I. Moussa, M. M. S. Ali, Reda R. Sheha. The performance of activated carbon/NiFe₂O₄ magnetic composite to retain heavy metal ions from aqueous solution[J]. Chinese Journal of Chemical Engineering, 2021, 29(1): 135-145.

S. I. Moussa, M. M. S. Ali, Reda R. Sheha. The performance of activated carbon/NiFe₂O₄ magnetic composite to retain heavy metal ions from aqueous solution[J]. 中国化学工程学报, 2021, 29(1): 135-145.

References

[1] A. Demirbas, Heavy metal adsorption onto agro-based waste materials:a review, J. Hazard. Mater. 157(2008) 220-229.
[2] M. Immamuglu, O. Tekir, Removal of copper (Ⅱ) and lead (Ⅱ) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks, Desalination 228(2008) 108-113.
[3] K. Kadirvelu, J. Goe, L. Rajagopal, Sorption of lead, mercury and cadmium ions in multi-component system using carbon aerogel as adsorbent, J. Hazard. Mater. 153(2008) 502-507.
[4] Y. Feng, J.L. Gong, G.M. Zeng, Q.Y. Niu, H.Y. Zhang, C.G. Niu, J.H. Deng, M. Yan, Adsorption of Cd(Ⅱ) and Zn(Ⅱ) from aqueous solutions using magnetic hydroxyapatite nanoparticles as adsorbents, Chem. Eng. J. 162(2010) 487-494.
[5] P. Trivedi, L. Axe, Modeling Cd and Zn sorption to hydrous metal oxides, Environ. Sci. Technol. 34(2000) 2215-2223.
[6] World Health Organization (Ed.), Guidelines for Drinking-Water Quality:Incorporating First Addendum Recommendations, 3rd ed., vol. 1, World Health Organization, Geneva, Switzerland 2006, pp. 375-376.
[7] X. Wang, Z. Wang, H. Chen, Z. Wu, Removal of Cu(Ⅱ) ions from contaminated waters using a conducting microfiltration membrane, J. Hazard. Mater. 339(2017) 182-190.
[8] B. Dong, A. Fishgold, P. Lee, K. Runge, M. Keswani, Sono-electrochemical recovery of metal ions from their aqueous solutions, J. Hazard. Mater. 318(2016) 379-387.
[9] D. Kołodyńska, J. Krukowska-Bąk, J. Kazmierczak-Razna, R. Pietrzak, Uptake of heavy metal ions from aqueous solutions by sorbents obtained from the spent ion exchange resins, Microporous Mesoporous Mater. 244(2017) 127-136.
[10] M. Ahmaruzzaman, V.K. Gupta, Rice husk and its ash as low-cost adsorbents in water and wastewater treatment, Ind. Eng. Chem. Res. 50(2011) 13589-13613.
[11] Y. Wang, S. Huang, S. Kang, C. Zhang, Xi Li, Low-cost route for synthesis of mesoporous silica materials with high silanol groups and their application for Cu(Ⅱ) removal, Mater. Chem. Phys. 132(2012) 1053-1059.
[12] H.P. Lu, Z.A. Li, G. Gascó, A. Méndez, Y. Shen, J. Paz-Ferreiro, Use of magnetic biochars for the immobilization of heavy metals in a multi-contaminated soil, Sci. Total Environ. 622-623(2018) 892-899.
[13] T.A. Saleh, V.K. Gupta, Processing Methods, Characteristics and adsorption behavior of tires derived carbons:a review, Adv. Colloid Interf. Sci. 211(2014) 92-100.
[14] V.K. Gupta, A. Nayak, S. Agarwal, Bioadsorbents for remediation of heavy metals:current status and their future prospects, Environ. Eng. Res. 20(1) (2015) 1-18.
[15] D.H. Reddy, Y.S. Yun, Spinel ferrite magnetic adsorbents:alternative future materials for waterpurification, Coord. Chem. Rev. 315(2016) 90-111.
[16] M.K. Ridley, M.L. Machesky, J.D. Kubicki, Experimental study of strontium adsorption on anatase nanoparticles as a function of size with a density functional theory and CD model interpretation, Langmuir 31(2015) 703-713.
[17] G. Zhang, H. Liu, R. Liu, J. Qu, Removal of phosphate from water by a Fe-Mn binary oxide adsorbent, J. Colloid Interface Sci. 335(2009) 168-174.
[18] M. Changmai, M.K. Purkait, Kinetics, equilibrium and thermodynamic study of phenol adsorption using NiFe₂O₄ nanoparticles aggregated on PAC, J. Water Proc. Eng. 16(2017) 90-97.
[19] L. Zhou, L. Ji, P.-C. Ma, Y. Shao, H. Zhang, W. Gao, Y. Li, Development of carbon nanotubes/CoFe₂O₄ magnetic hybrid material for removal of tetrabromobisphenol A and Pb(Ⅱ), J. Hazard. Mater. 265(2014) 104-114.
[20] Q. Chang, L. Liu, Y. Muhammad, Sh. Weng, Z. Feng, T. Wei, J. Lei, Z. Tong, Z. Zhao, Synthesis of magnetic Fe-N doped porous carbon possessing hollow-acicular structure with high activity and stability for lumbrukinase adsorptive immobilization, Chem. Eng. J. 334(2018) 1699-1708.
[21] K. Pyrzynska, M. Bystrzejewski, Comparative study of heavy metal ions sorption onto activated carbon, carbon nanotubes, and carbon-encapsulated magnetic nanoparticles, Colloids Surf. A Physicochem. Eng. Aspects 362(2010) 102-109.
[22] H.H. Someda, M.R. Ezz El-Din, R.R. Sheha, H.A. El-Naggar, Application of a carbonized apricot stone for the treatment of some radioactive nuclei, J. Radioanal. Nucl. Chem. 254(2) (2002) 373-378.
[23] H.H. Someda, R.R. Sheha, Solid phase extractive preconcentration of some actinide elements using impregnated carbon, J. Radioanal. Nucl. Chem. 7(2) (2006) 37-43.
[24] A.A. El-Zahhar, S.E. Sharaf El, R.R. Sheha Deen, Sorption of iron from phosphoric acid solution using polyacrylamide grafted activated carbon, J. Environ. Chem. Eng. 1(2013) 290-299.
[25] L. Shao, Z. Ren, G. Zhang, L. Chen, Facile synthesis, characterization of a MnFe₂O₄/activated carbon magnetic composite and its effectiveness in tetracycline removal, Mater. Chem. Phys. 135(2012) 16-24.
[26] H. Sharififard, M. Soleimani, Performance comparison of activated carbon and ferric oxide-hydroxide-activated carbon nanocomposite as vanadium (V) ion adsorbents, RSC Adv. 5(2015) 80650-80660.
[27] E. Pehlivan, S. Cetin, B.H. Yańyk, Equilibrium studies for the sorption of zinc and copper from aqueous solutions using sugar beet pulp and fly ash, J. Hazard. Mater. B 135(2006) 193-199.
[28] J. Zhou, S. Yang, J. Yu, Facile fabrication of mesoporous MgO microspheres and their enhanced adsorption performance for phosphate from aqueous solutions, Colloids Surf. A Physicochem. Eng. Asp. 379(2011) 102-108.
[29] L. Liu, Y. Wei, Q. Chang, H. Sun, K. Chai, Z. Huang, Zhenxia Zhao, Zhongxing Zhao, Ultra-fast screening of a novel moderately hydrophilic angiotensin converting enzyme inhibitory peptide RYL from silkworm pupa using Fe-doped silkworm excrement derived biocarbon:Waste Conversion by Waste, J. Agric. Food Chem. 65(51) (2017) 11202-11211.
[30] P. Hu, X. Liang, M. Yaseen, X. Sun, Z. Tong, Zhongxing Zhao, Zhenxia Zhao, Preparation of highly-hydrophobic novel N-coordinated UiO-66(Zr) with dopamine via fast mechano-chemical method for (CHO^-/Cl^-)-VOCs competitive adsorption in humid environment, Chem. Eng. J. 332(2018) 608-618.
[31] Z.H. Wang, B. Xiang, R.M. Cheng, Y. Li, Behaviors and mechanism of acid dyes sorption onto diethylenetriamine-modified native and enzymatic hydrolysis starch, J. Hazard. Mater. 183(1-3) (2010) 224-232.
[32] L. Zhang, W.L. Jiao, J. He, A. Zhang, Synthesis of PAA/NiFe₂O₄ composite nanoparticles and the effect of microstructure on magnetism, J. Alloys Compd. 577(2013) 538-542.
[33] N.W. Li, M.B. Zheng, X.F. Chang, G. Ji, H. Lu, L. Xue, L. Pan, J. Cao, Preparation of magnetic CoFe₂O₄-functionalized graphene sheets via a facile hydrothermal method and their adsorption properties, J. Solid State Chem. 184(4) (2011) 953-958.
[34] M.H. Do, N.H. Phan, T.D. Nguyen, T.T. Pham, V.K. Nguyen, T.T. Vu, T.K. Nguyen, Activated carbon/Fe₃O₄ nanoparticle composite:fabrication, methyl orange removal and regeneration by hydrogen peroxide, Chemosphere 85(8) (2011) 1269-1276.
[35] W. Deligeer, Y.W. Gao, S. Asuha, Adsorption of methyl orange on mesoporous gFe₂O₃/SiO₂ nanocomposites, Appl. Surf. Sci. 257(8) (2011) 3524-3528.
[36] L. Ai, J. Jiang, Fast removal of organic dyes from aqueous solutions by AC/ferrospinel composite, Desalination 262(2010) 134-140.
[37] A. Üçer, A. Uyanik, Ş.F. Aygün, Adsorption of Cu(Ⅱ), Cd(Ⅱ), Zn(Ⅱ), Mn(Ⅱ) and Fe(Ⅲ) ions by tannic acid immobilized activated carbon, Sep. Purif. Technol. 47(3) (2006) 113-118.
[38] C.G. Lee, J.W. Jeon, M.J. Hwang, K.H. Ahn, C. Park, J.W. Choi, S.H. Lee, Lead and copper removal from aqueous solutions using carbon foam derived from phenol resin, Chemosphere 130(2015) 59-65.
[39] J.H. Park, Y.S. Ok, S.H. Kim, J.S. Cho, J.S. Heo, R.D. Delaune, D.C. Seo, Competitive adsorption of heavy metals onto sesame straw biochar in aqueous solutions, Chemosphere 142(2016) 77-83.
[40] S. Lagergren, Zurtheorie der sogenannten adsorption gelösterstoffe, KungligaSvenskaVetenskapsakademiens, Handl. Band 24(4) (1898) 1-39.
[41] Y.S. Ho, G. Mckay, Sorption of dye from aqueous solution by peat, Chem. Eng. J. 70(1998) 115-124.
[42] Y. Ren, X. Wei, M. Zhang, Adsorption character for removal Cu(Ⅱ) by magnetic Cu(Ⅱ) ion imprinted composite adsorbent, J. Hazard. Mater. 158(2008) 14-22.
[43] R.R. Sheha, Preparation and performance of a novel composite as a reactive resin for copper retention, Chem. Eng. J. 213(2012) 163-174.
[44] J.P. Gustafsson, https://vminteq.lwr.kth.se/.
[45] R.N. Patel, N. Singh, R.P. Shivastava, K.K. Shukla, P.K. Singh, Potentiometric and spectrometric study:copper(Ⅱ), nickel(Ⅱ) and zinc(Ⅱ) complexes with potentially tridentate and monodentate ligands, Proc. Indian Acad. Sci. (Chem. Sci.) 114(2) (2002) 115-124.
[46] H. Irving, R.J. Williams, The stability of transition-metal complexes, J. Chem. Soc. (1953) 3192-3210.
[47] S.P. Santoso, A.E. Angkawijaya, Y.H. Ju, Complex stability in aqueous solution of metal ions (Cu²⁺, Zn²⁺, and Mn²⁺) with pyrocatechuic acid ligand, Int. J. Adv. Sci. Eng. Technol. 3(3) (2015) 23-28.
[48] M.A. Montes-Morán, J.A. Menéndez, E. Fuente, D. Suárez, Contribution of the basal planes to carbon basicity:an ab initio study of the H₃O⁺ π-interaction in cluster models, J. Phys. Chem. B 102(1998) 595-5601.
[49] J. Rivera-Utrilla, M. Sáncher-Polo, Adsorption of Cr (Ⅲ) on ozonised activated carbon. Importance of Cπ-cation interactions, Water Res. 37(2003) 3325-3340.
[50] S. Daneshfozoun, B. Abdullah, M.A. Abdullah, The effects of oil palm empty fruit bunch sorbent sizes on plumbum (Ⅱ) ion sorption, Adv. Mater. Res. Trans. Tech. Publ. 1133(2016) 542-546.
[51] K.A. Krishan, T.S. Anirudhan, Removal of mercury(Ⅱ) from aqueous solutions and chlor-alkali industry effluent by steam activated and sulphurised activated carbons prepared from bagasse pith:kinetics and equilibrium studies, J. Hazard. Mater. 92(2002) 161-183.
[52] J. Zhu, B. Deng, J. Yang, D. Gang, Modifying activated carbon with hybrid ligands for enhancing aqueous mercury removal, Carbon 47(2009) 2014-2025.
[53] C. Chen, J. Hu, D. Shao, J. Li, X. Wang, Adsorption behavior of multiwall carbon nanotube/iron oxide magnetic composites for Ni(Ⅱ) and Sr(Ⅱ), J. Hazard. Mater. 164(2009) 923-928.
[54] R.R. Sheha, E.A. El-Shazly, Kinetics and equilibrium modeling of Se(IV) removal from aqueous solutions using metal oxides, Chem. Eng. J. 160(2010) 63-71.

The performance of activated carbon/NiFe₂O₄ magnetic composite to retain heavy metal ions from aqueous solution

The performance of activated carbon/NiFe₂O₄ magnetic composite to retain heavy metal ions from aqueous solution

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