Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO2 catalytic conversion

doi:10.1016/j.cjche.2020.12.019

Abstract

Abstract: The engineering of highly efficient and stable heterogeneous catalysts for catalytic conversion of CO₂ to high value-added products is highly desirable but presents a great challenge. Herein, we reported the synthesis of a series of multifunctional IL@H-Zn/Co-ZIF composite catalysts with a unique porous hollow capsule structure and encapsulated amino-functionalized ionic liquids (ILs). The unique hollow capsule structure of IL@H-Zn/Co-ZIF provides sufficient space for loading active ILs ([C₂NH₂Mim⁺][Br^-]) and fast mass transfer of substrate molecules during catalysis. Furthermore, the microporous Zn-ZIF shell can effectively avoid the leaching of active ILs. Benefiting from the unique hollow structure, the resultant IL@H-Zn/Co-ZIF demonstrated excellent catalytic performance (>95% yield), and good recyclability (still remained about 90% activities after 5 cycles) when applied in the CO₂ cycloaddition reaction under solvent and co-catalyst free conditions.

Key words: MOFs, Catalyst, Hollow capsule, CO₂ capture, Ionic liquids

摘要： The engineering of highly efficient and stable heterogeneous catalysts for catalytic conversion of CO₂ to high value-added products is highly desirable but presents a great challenge. Herein, we reported the synthesis of a series of multifunctional IL@H-Zn/Co-ZIF composite catalysts with a unique porous hollow capsule structure and encapsulated amino-functionalized ionic liquids (ILs). The unique hollow capsule structure of IL@H-Zn/Co-ZIF provides sufficient space for loading active ILs ([C₂NH₂Mim⁺][Br^-]) and fast mass transfer of substrate molecules during catalysis. Furthermore, the microporous Zn-ZIF shell can effectively avoid the leaching of active ILs. Benefiting from the unique hollow structure, the resultant IL@H-Zn/Co-ZIF demonstrated excellent catalytic performance (>95% yield), and good recyclability (still remained about 90% activities after 5 cycles) when applied in the CO₂ cycloaddition reaction under solvent and co-catalyst free conditions.

关键词: MOFs, Catalyst, Hollow capsule, CO₂ capture, Ionic liquids

Bo-Yun Liu, Min-Jie Chen, Liang Yang, Bo Zhao, Tao Xia, Gang-Gang Chang. Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion[J]. Chinese Journal of Chemical Engineering, 2021, 40(12): 124-130.

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Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion

Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion

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