Superb VOCs capture engineering carbon adsorbent derived from shaddock peel owning uncompromising thermal-stability and adsorption property

doi:10.1016/j.cjche.2021.02.013

Chinese Journal of Chemical Engineering ›› 2022, Vol. 47 ›› Issue (7): 120-133.DOI: 10.1016/j.cjche.2021.02.013

Superb VOCs capture engineering carbon adsorbent derived from shaddock peel owning uncompromising thermal-stability and adsorption property

Fu Yang^1,2,3, Wenhao Li¹, Rui Ou¹, Yutong Lu¹, Xuexue Dong¹, Wenlong Tu¹, Wenjian Zhu¹, Xuyu Wang¹, Lulu Li¹, Aihua Yuan¹, Jianming Pan²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China;
3. Jiangsu Agricultural Hormone Engineering Technology Research Center Co. LTD, Changzhou 213022, China

Received:2020-12-23 Revised:2021-02-02 Online:2022-08-19 Published:2022-07-28
Contact: Fu Yang,E-mail:fuyang@just.edu.cn;Aihua Yuan,E-mail:aihua.yuan@just.edu.cn;Jianming Pan,E-mail:pjm@ujs.edu.cn
Supported by:
This work was financially supported by National Natural Science Foundation of China (21908085), Natural Science Foundation of Jiangsu Province, China (BK20190961), Postdoctoral Research Foundation of Jiangsu Province (2020Z291), Foundation from Marine Equipment and Technology Institute for Jiangsu University of Science and Technology, China (HZ20190004), and High-tech Ship Research Project of the Ministry of Industry and Information Technology, China (No.[2017] 614).

Superb VOCs capture engineering carbon adsorbent derived from shaddock peel owning uncompromising thermal-stability and adsorption property

Fu Yang^1,2,3, Wenhao Li¹, Rui Ou¹, Yutong Lu¹, Xuexue Dong¹, Wenlong Tu¹, Wenjian Zhu¹, Xuyu Wang¹, Lulu Li¹, Aihua Yuan¹, Jianming Pan²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China;
3. Jiangsu Agricultural Hormone Engineering Technology Research Center Co. LTD, Changzhou 213022, China

通讯作者: Fu Yang,E-mail:fuyang@just.edu.cn;Aihua Yuan,E-mail:aihua.yuan@just.edu.cn;Jianming Pan,E-mail:pjm@ujs.edu.cn
基金资助:
This work was financially supported by National Natural Science Foundation of China (21908085), Natural Science Foundation of Jiangsu Province, China (BK20190961), Postdoctoral Research Foundation of Jiangsu Province (2020Z291), Foundation from Marine Equipment and Technology Institute for Jiangsu University of Science and Technology, China (HZ20190004), and High-tech Ship Research Project of the Ministry of Industry and Information Technology, China (No.[2017] 614).

Abstract

Abstract: High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising, which also is the determining short slab in volatile organic compounds (VOCs) adsorption applications. Herein, we develop the outstanding engineering carbon adsorbents from waste shaddock peel which affords greatly-enhanced thermal-stability and super structural property (S_Lang?=?4962.6?m²·g^-1, V_micro?=?1.67?cm³·g^-1). Such character endows the obtained adsorbent with ultrahigh adsorption capture performance of VOCs specific to benzene (16.58?mmol·g^-1) and toluene (15.50?mmol·g^-1), far beyond traditional zeolite and activated carbon even MOFs materials. The structural expression characters were accurately correlated with excellent adsorption efficiency of VOCs by studying synthetic factor-controlling comparative samples. Ulteriorly, adsorption selectivity prediction at different relative humidity was demonstrated through DIH (difference of the isosteric heats), exceedingly highlighting great superiority (nearly sixfold) in selective adsorption of toluene compared to volatile benzene. Our findings provide the possibility for practical industrial application and fabrication of waste biomass-derived outstanding biochar adsorbent in the environmental treatment of threatening VOCs pollutants.

Key words: Thermal-stability, Carbon absorbent, VOCs, Shaddock peel, Capture

摘要： High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising, which also is the determining short slab in volatile organic compounds (VOCs) adsorption applications. Herein, we develop the outstanding engineering carbon adsorbents from waste shaddock peel which affords greatly-enhanced thermal-stability and super structural property (S_Lang?=?4962.6?m²·g^-1, V_micro?=?1.67?cm³·g^-1). Such character endows the obtained adsorbent with ultrahigh adsorption capture performance of VOCs specific to benzene (16.58?mmol·g^-1) and toluene (15.50?mmol·g^-1), far beyond traditional zeolite and activated carbon even MOFs materials. The structural expression characters were accurately correlated with excellent adsorption efficiency of VOCs by studying synthetic factor-controlling comparative samples. Ulteriorly, adsorption selectivity prediction at different relative humidity was demonstrated through DIH (difference of the isosteric heats), exceedingly highlighting great superiority (nearly sixfold) in selective adsorption of toluene compared to volatile benzene. Our findings provide the possibility for practical industrial application and fabrication of waste biomass-derived outstanding biochar adsorbent in the environmental treatment of threatening VOCs pollutants.

关键词: Thermal-stability, Carbon absorbent, VOCs, Shaddock peel, Capture

Fu Yang, Wenhao Li, Rui Ou, Yutong Lu, Xuexue Dong, Wenlong Tu, Wenjian Zhu, Xuyu Wang, Lulu Li, Aihua Yuan, Jianming Pan. Superb VOCs capture engineering carbon adsorbent derived from shaddock peel owning uncompromising thermal-stability and adsorption property[J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 120-133.

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Superb VOCs capture engineering carbon adsorbent derived from shaddock peel owning uncompromising thermal-stability and adsorption property

Superb VOCs capture engineering carbon adsorbent derived from shaddock peel owning uncompromising thermal-stability and adsorption property

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