Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

doi:10.1016/j.cjche.2021.08.009

Chinese Journal of Chemical Engineering ›› 2022, Vol. 48 ›› Issue (8): 36-43.DOI: 10.1016/j.cjche.2021.08.009

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

Min Lu¹, Mengxuan Liu¹, Chunli Xu¹, Yu Yin¹, Lei Shi², Hong Wu², Aihua Yuan¹, Xiao-Ming Ren³, Shaobin Wang⁴, Hongqi Sun²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Engineering, Edith Cowan University, Joondalup, WA 6027, Australia;
3. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China;
4. School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA 5005, Australia

Received:2021-05-13 Revised:2021-07-30 Online:2022-09-30 Published:2022-08-28
Contact: Yu Yin,E-mail:season_july@just.edu.cn;Aihua Yuan,E-mail:aihua.yuan@just.edu.cn;Hongqi Sun,E-mail:h.sun@ecu.edu.au
Supported by:
We would like to show our great appreciation for funding support from National Natural Science Foundation of China (51602133) and State Key Laboratory of Materials-Oriented Chemical Engineering (KL19-05). The authors also express thanks for taking TEM images from the Centre for Microscopy, Characterization and Analysis (CMCA) of the University of Western Australia.

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

Min Lu¹, Mengxuan Liu¹, Chunli Xu¹, Yu Yin¹, Lei Shi², Hong Wu², Aihua Yuan¹, Xiao-Ming Ren³, Shaobin Wang⁴, Hongqi Sun²

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. School of Engineering, Edith Cowan University, Joondalup, WA 6027, Australia;
3. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China;
4. School of Chemical Engineering and Advanced Materials, The University of Adelaide, Adelaide, SA 5005, Australia

通讯作者: Yu Yin,E-mail:season_july@just.edu.cn;Aihua Yuan,E-mail:aihua.yuan@just.edu.cn;Hongqi Sun,E-mail:h.sun@ecu.edu.au
基金资助:
We would like to show our great appreciation for funding support from National Natural Science Foundation of China (51602133) and State Key Laboratory of Materials-Oriented Chemical Engineering (KL19-05). The authors also express thanks for taking TEM images from the Centre for Microscopy, Characterization and Analysis (CMCA) of the University of Western Australia.

Abstract

Abstract: Refractory antibiotics in domestic wastewater are hard to be completely eliminated by conventional methods, and then lead to severe environmental contamination and adverse effects on public health. In present work, advanced oxidation processes (AOPs) are adopted to remove the antibiotic of sulfachloropyridazine (SCP). Nanosized Mn₂O₃ was fabricated on the SBA-15 material to catalytically activate potassium peroxydisulfate (PDS) to generate reactive oxygen radicals of ?OH and SO₄^- for SCP degradation. The effects of location and size of Mn₂O₃ were explored through choosing either the as-made or template-free SBA-15 as the precursor of substrate. Great influences from the site and size of Mn₂O₃ on the oxidation activity were discovered. It was found that Mn₂O₃ with a large size at the exterior of SBA-15 (Mn-tfSBA) was slightly easier to degrade SCP at a low manganese loading of 1.0–2.0?mmol?g^?1; however, complete SCP removal could only be achieved on the catalyst of Mn₂O₃ with a refined size at the interior of SBA-15 (Mn-asSBA). Moreover, the SO₄^- species were revealed to be the decisive radicals in the SCP degradation processes. Exploring the as-made mesoporous silica as a support provides a new idea for the further development of environmentally friendly catalysts.

Key words: Advanced oxidation processes (AOPs), Sulfate radical, Antibiotic degradation, Manganese, Mesoporous silica

摘要： Refractory antibiotics in domestic wastewater are hard to be completely eliminated by conventional methods, and then lead to severe environmental contamination and adverse effects on public health. In present work, advanced oxidation processes (AOPs) are adopted to remove the antibiotic of sulfachloropyridazine (SCP). Nanosized Mn₂O₃ was fabricated on the SBA-15 material to catalytically activate potassium peroxydisulfate (PDS) to generate reactive oxygen radicals of ?OH and SO₄^- for SCP degradation. The effects of location and size of Mn₂O₃ were explored through choosing either the as-made or template-free SBA-15 as the precursor of substrate. Great influences from the site and size of Mn₂O₃ on the oxidation activity were discovered. It was found that Mn₂O₃ with a large size at the exterior of SBA-15 (Mn-tfSBA) was slightly easier to degrade SCP at a low manganese loading of 1.0–2.0?mmol?g^?1; however, complete SCP removal could only be achieved on the catalyst of Mn₂O₃ with a refined size at the interior of SBA-15 (Mn-asSBA). Moreover, the SO₄^- species were revealed to be the decisive radicals in the SCP degradation processes. Exploring the as-made mesoporous silica as a support provides a new idea for the further development of environmentally friendly catalysts.

关键词: Advanced oxidation processes (AOPs), Sulfate radical, Antibiotic degradation, Manganese, Mesoporous silica

Min Lu, Mengxuan Liu, Chunli Xu, Yu Yin, Lei Shi, Hong Wu, Aihua Yuan, Xiao-Ming Ren, Shaobin Wang, Hongqi Sun. Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation[J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 36-43.

References

[1] X.W. Ao, J. Eloranta, C.H. Huang, D. Santoro, W.J. Sun, Z.D. Lu, C. Li, Peracetic acid-based advanced oxidation processes for decontamination and disinfection of water: a review, Water Res 188 (2021) 116479
[2] Z.L. Wu, Y.P. Wang, Z.K. Xiong, Z.M. Ao, S.Y. Pu, G. Yao, B. Lai, Core-shell magnetic Fe3O4@Zn/Co-ZIFs to activate peroxymonosulfate for highly efficient degradation of carbamazepine, Appl. Catal. B: Environ. 277 (2020) 119136
[3] D.S. Babu, V. Srivastava, P.V. Nidheesh, M.S. Kumar, Detoxification of water and wastewater by advanced oxidation processes, Sci. Total. Environ. 696 (2019) 133961
[4] A. Khamkeaw, M. Phisalaphong, B. Jongsomjit, K.A. Lin, A.C.K. Yip, Synthesis of mesoporous MFI zeolite via bacterial cellulose-derived carbon templating for fast adsorption of formaldehyde, J Hazard Mater 384 (2020) 121161
[5] C. Zhang, J.F. Li, F.Q. Cheng, Recycling of powder coke to cost effective adsorbent material and its application for tertiary treatment of coking wastewater, J. Clean. Prod. 261 (2020) 121114
[6] D.L. Xu, L.M. Bai, X.B. Tang, D.Y. Niu, X.S. Luo, X.W. Zhu, G.B. Li, H. Liang, A comparison study of sand filtration and ultrafiltration in drinking water treatment: Removal of organic foulants and disinfection by-product formation, Sci Total Environ 691 (2019) 322–331
[7] W. Pronk, A. Ding, E. Morgenroth, N. Derlon, P. Desmond, M. Burkhardt, B. Wu, A.G. Fane, Gravity-driven membrane filtration for water and wastewater treatment: a review, Water Res 149 (2019) 553–565
[8] Y.P. Guo, Z.Q. Zeng, Y.J. Liu, Z.G. Huang, Y. Cui, J.Y. Yang, One-pot synthesis of sulfur doped activated carbon as a superior metal-free catalyst for the adsorption and catalytic oxidation of aqueous organics, J. Mater. Chem. A 6 (9) (2018) 4055–4067
[9] J.R. de de Andrade, M.G.A. Vieira, M.G.C. da Silva, S.B. Wang, Oxidative degradation of pharmaceutical losartan potassium with N-doped hierarchical porous carbon and peroxymonosulfate, Chem. Eng. J. 382 (2020) 122971
[10] G.X. Song, Z.Y. Chu, W.Q. Jin, H.Q. Sun, Enhanced performance of g-C3N4/TiO2 photocatalysts for degradation of organic pollutants under visible light, Chin. J. Chem. Eng. 23 (8) (2015) 1326–1334
[11] H. Wu, X.Y. Xu, L. Shi, Y. Yin, L.C. Zhang, Z.T. Wu, X.G. Duan, S.B. Wang, H.Q. Sun, Manganese oxide integrated catalytic ceramic membrane for degradation of organic pollutants using sulfate radicals, Water Res 167 (2019) 115110
[12] X.G. Duan, H.Q. Sun, S.B. Wang, Metal-free carbocatalysis in advanced oxidation reactions, Acc Chem Res 51 (3) (2018) 678–687
[13] H.J. Zhou, L. Kang, M. Zhou, Z.X. Zhong, W.H. Xing, Membrane enhanced COD degradation of pulp wastewater using Cu2O/H2O2 heterogeneous Fenton process, Chin. J. Chem. Eng. 26 (9) (2018) 1896–1903
[14] J.L. Wang, S.Z. Wang, Reactive species in advanced oxidation processes: Formation, identification and reaction mechanism, Chem. Eng. J. 401 (2020) 126158
[15] D.L. Huang, G.X. Zhang, J. Yi, M. Cheng, C. Lai, P. Xu, C. Zhang, Y. Liu, C.Y. Zhou, W.J. Xue, R.Z. Wang, Z.H. Li, S. Chen, Progress and challenges of metal-organic frameworks-based materials for SR-AOPs applications in water treatment, Chemosphere 263 (2021) 127672
[16] C.Y. Chen, Z.H. Wu, S.S. Zheng, L.P. Wang, X.Z. Niu, J.Y. Fang, Comparative study for interactions of sulfate radical and hydroxyl radical with phenol in the presence of nitrite, Environ Sci Technol 54 (13) (2020) 8455–8463
[17] L.L. Zhu, J.H. Ji, J. Liu, S. Mine, M. Matsuoka, J.L. Zhang, M.Y. Xing, Designing 3D-MoS2 sponge as excellent cocatalysts in advanced oxidation processes for pollutant control, Angew Chem Int Ed Engl 59 (33) (2020) 13968–13976
[18] X.M. Lei, M.H. You, F. Pan, M. Liu, P. Yang, D.S. Xia, Q. Li, Y.T. Wang, J. Fu, CuFe2O4@GO nanocomposite as an effective and recoverable catalyst of peroxymonosulfate activation for degradation of aqueous dye pollutants, Chin. Chem. Lett. 30 (12) (2019) 2216–2220
[19] L.Y. Wang, J. Di, J. Nie, G.P. Ma, Multicomponent doped sugar-coated nanofibers for peroxymonosulfate activation, ACS Appl. Nano Mater. 2 (11) (2019) 6998–7007
[20] L. Du, W.H. Xu, S.B. Liu, X. Li, D.L. Huang, X.F. Tan, Y.G. Liu, Activation of persulfate by graphitized biochar for sulfamethoxazole removal: The roles of graphitic carbon structure and carbonyl group, J Colloid Interface Sci 577 (2020) 419–430
[21] S.S. Zhu, X.J. Li, J. Kang, X.G. Duan, S.B. Wang, Persulfate activation on crystallographic manganese oxides: mechanism of singlet oxygen evolution for nonradical selective degradation of aqueous contaminants, Environ Sci Technol 53 (1) (2019) 307–315
[22] I. Hussain, Y.Q. Zhang, M.Y. Li, S.B. Huang, W. Hayat, L.M. He, X.D. Du, G.Q. Liu, M.M. Du, Heterogeneously degradation of aniline in aqueous solution using persulfate catalyzed by magnetic BiFeO3 nanoparticles, Catal. Today 310 (2018) 130–140
[23] Y.J. Yao, J. Zhang, M.X. Gao, M.J. Yu, Y. Hu, Z.R. Cheng, S.B. Wang, Activation of persulfates by catalytic nickel nanoparticles supported on N-doped carbon nanofibers for degradation of organic pollutants in water, J Colloid Interface Sci 529 (2018) 100–110
[24] L.W. Chen, S.J. Yang, X. Zuo, Y. Huang, T.M. Cai, D.H. Ding, Biochar modification significantly promotes the activity of Co3O4 towards heterogeneous activation of peroxymonosulfate, Chem. Eng. J. 354 (2018) 856–865
[25] Y. Yin, H. Wu, L. Shi, J.Q. Zhang, X.Y. Xu, H.Y. Zhang, S.B. Wang, M. Sillanp??d, H.Q. Sun, Quasi single cobalt sites in nanopores for superior catalytic oxidation of organic pollutants, Environ. Sci.: Nano 5 (12) (2018) 2842–2852
[26] J.Z. Huang, H.C. Zhang, Mn-based catalysts for sulfate radical-based advanced oxidation processes: a review, Environ. Int. 133 (2019) 105141
[27] J.R. Yang, D.Q. Zeng, Q.G. Zhang, R.F. Cui, M. Hassan, L.Q. Dong, J. Li, Y.L. He, Single Mn atom anchored on N-doped porous carbon as highly efficient Fenton-like catalyst for the degradation of organic contaminants, Appl. Catal. B: Environ. 279 (2020) 119363
[28] Q.M. Sun, B.W.J. Chen, N. Wang, Q. He, A. Chang, C.M. Yang, H. Asakura, T. Tanaka, M.J. Hülsey, C.H. Wang, J.H. Yu, N. Yan, Zeolite-encaged Pd-Mn nanocatalysts for CO2 hydrogenation and formic acid dehydrogenation, Angew Chem Int Ed Engl 59 (45) (2020) 20183–20191
[29] B. Zhu, X.S. Li, P. Sun, J.L. Liu, X.Y. Ma, X.B. Zhu, A.M. Zhu, A novel process of ozone catalytic oxidation for low concentration formaldehyde removal, Chin. J. Catal. 38 (10) (2017) 1759–1769
[30] J.W. Fan, X. Jiang, H.Y. Min, D.D. Li, X.Q. Ran, L.Y. Zou, Y. Sun, W. Li, J.P. Yang, W. Teng, G.M. Li, D.Y. Zhao, Facile preparation of Cu–Mn/CeO2/SBA-15 catalysts using ceria as an auxiliary for advanced oxidation processes, J. Mater. Chem. A 2 (27) (2014) 10654
[31] X.Q. Fan, D.D. Liu, X.Y. Sun, X.H. Yu, D. Li, Y. Yang, H.Y. Liu, J.Y. Diao, Z.A. Xie, L. Kong, X. Xiao, Z. Zhao, Mn-doping induced changes in Pt dispersion and PtxMny alloying extent on Pt/Mn-DMSN catalyst with enhanced propane dehydrogenation stability, J. Catal. 389 (2020) 450–460
[32] Z. Wang, Y. Qin, F. Pan, Z. Li, W.D. Zhang, F. Wu, D. Chen, W.J. Wen, J.J. Li, Mesoporous silica-supported manganese oxides for complete oxidation of volatile organic compounds: influence of mesostructure, redox properties, and hydrocarbon dimension, Ind. Eng. Chem. Res. 57 (22) (2018) 7374–7382
[33] J. Yu, J. Zhang, T. Zeng, H. Wang, Y.P. Sun, L. Chen, S. Song, H.X. Shi, Stable incorporation of MnOx quantum dots into N-doped hollow carbon: a synergistic peroxymonosulfate activator for enhanced removal of bisphenol A, Sep. Purif. Technol. 213 (2019) 264–275
[34] J. Biemolt, K. van der Veen, N.J. Geels, G. Rothenberg, N. Yan, Efficient oxygen reduction to H2O2 in highly porous manganese and nitrogen co-doped carbon nanorods enabling electro-degradation of bulk organics, Carbon 155 (2019) 643–649
[35] Y. Yin, W.L. Li, C.L. Xu, L. Shi, L.C. Zhang, Z.M. Ao, M.X. Liu, M. Lu, X.G. Duan, S.B. Wang, S.M. Liu, H.Q. Sun, Ultrafine copper nanoclusters and single sites for Fenton-like reactions with high atom utilities, Environ. Sci.: Nano 7 (9) (2020) 2595–2606
[36] H. Liang, C. Jin, L. Ma, X.B. Feng, X.Y. Deng, S.L. Wu, X.M. Liu, C. Yang, Accelerated bone regeneration by gold-nanoparticle-loaded mesoporous silica through stimulating immunomodulation, ACS Appl Mater Interfaces 11 (44) (2019) 41758–41769
[37] Lu J, Wu JK, Jiang Y, Tan P, Zhang L, Lei Y, Liu XQ, Sun LB, Fabrication of microporous metal-organic frameworks in uninterrupted mesoporous tunnels: hierarchical structure for efficient trypsin immobilization and stabilization, Angew Chem Int Ed Engl 59 (16) (2020) 6428–6434
[38] X.S. Cheng, D.X. Wang, J.C. Liu, X. Kang, H.J. Yan, A.P. Wu, Y. Gu, C.G. Tian, H.G. Fu, Ultra-small Mo2N on SBA-15 as a highly efficient promoter of low-loading Pd for catalytic hydrogenation, Nanoscale 10 (47) (2018) 22348–22356
[39] Q.Y. Chu, J. Chen, W.H. Hou, H.X. Yu, P. Wang, R. Liu, G.L. Song, H.J. Zhu, P.P. Zhao, Enhancement of catalytic activity by homo-dispersing S2O82: Fe2O3 nanoparticles on SBA-15 through ultrasonic adsorption, Chin. J. Catal. 39 (5) (2018) 955–963
[40] M.X. Gu, Y. Kou, S.C. Qi, M.Q. Shao, M.B. Yue, X.Q. Liu, L.B. Sun, Highly dispersive cobalt oxide constructed in confined space for oxygen evolution reaction, ACS Sustain. Chem. Eng. 7 (2) (2019) 2837–2843
[41] P. Shukla, H.Q. Sun, S.B. Wang, H.M. Ang, M.O. Tadé, Co-SBA-15 for heterogeneous oxidation of phenol with sulfate radical for wastewater treatment, Catal. Today 175 (1) (2011) 380–385
[42] Sonal, K.K. Pant, S. Upadhyayula, An insight into the promotional effect on Fe-Co bimetallic catalyst in the Fischer Tropsch reaction: a DRIFTS study, Fuel 276 (2020) 118044
[43] H.M. Gobara, S.A. Hassan, A.M.A. El Naggar, R.S. Mohamed, A.A. Alkahlawy, A.A. Salem, H.M. Salem, Anomalous behavior of H2 storage in photocatalytic splitting of water over Fe nanoparticles loaded on Al-modified SBA-15 composites via microwave or ultrasonic treatment routes, Int. J. Hydrog. Energy 45 (46) (2020) 24710–24725
[44] T. Deng, G.Y. Xu, Y. Fu, One-pot cascade conversion of xylose to furfuryl alcohol over a bifunctional Cu/SBA-15-SO3H catalyst, Chin. J. Catal. 41 (3) (2020) 404–414
[45] Y. Yin, W.J. Jiang, X.Q. Liu, Y.H. Li, L.B. Sun, Dispersion of copper species in a confined space and their application in thiophene capture, J. Mater. Chem. 22 (35) (2012) 18514
[46] Y. Qin, Z.P. Qu, C. Dong, Y. Wang, N. Huang, Highly catalytic activity of Mn/SBA-15 catalysts for toluene combustion improved by adjusting the morphology of supports, J Environ Sci (China) 76 (2019) 208–216
[47] Y.F. Han, F.X. Chen, Z.Y. Zhong, K. Ramesh, L.W. Chen, E. Widjaja, Controlled synthesis, characterization, and catalytic properties of Mn(2)O(3) and Mn(3)O(4) nanoparticles supported on mesoporous silica SBA-15, J Phys Chem B 110 (48) (2006) 24450–24456
[48] F.L. Cao, H. Li, Z.M. Xu, J. Zhang, Y. Zhang, Y.N. Huo, Preparation of Mn2O3/SBA-15 catalyst with high loading and catalytic peroxidation for degradation of organic pollutants, J. Mol. Catal. A: Chem. 353-354 (2012) 215–219
[49] X.N. Li, X. Huang, S.B. Xi, S. Miao, J. Ding, W.Z. Cai, S. Liu, X.L. Yang, H.B. Yang, J.J. Gao, J.H. Wang, Y.Q. Huang, T. Zhang, B. Liu, Single cobalt atoms anchored on porous N-doped graphene with dual reaction sites for efficient Fenton-like catalysis, J Am Chem Soc 140 (39) (2018) 12469–12475
[50] Y.W. Liu, Z. Li, Q.Y. Yu, Y.F. Chen, Z.W. Chai, G.F. Zhao, S.J. Liu, W.C. Cheong, Y. Pan, Q.H. Zhang, L. Gu, L.R. Zheng, Y. Wang, Y. Lu, D.S. Wang, C. Chen, Q. Peng, Y.Q. Liu, L.M. Liu, J.S. Chen, Y.D. Li, A general strategy for fabricating isolated single metal atomic site catalysts in Y zeolite, J Am Chem Soc 141 (23) (2019) 9305–9311
[51] J. Kang, X.G. Duan, L. Zhou, H.Q. Sun, M.O. Tadé, S.B. Wang, Carbocatalytic activation of persulfate for removal of antibiotics in water solutions, Chem. Eng. J. 288 (2016) 399–405
[52] X.H. Sun, M.B. Feng, S.Y. Dong, Y. Qi, L. Sun, N. Nesnas, V.K. Sharma, Removal of sulfachloropyridazine by ferrate(VI): Kinetics, reaction pathways, biodegradation, and toxicity evaluation, Chem. Eng. J. 372 (2019) 742–751
[53] X. Tao, P. Pan, T.B. Huang, L. Chen, H.D. Ji, J.J. Qi, F.B. Sun, W. Liu, In-situ construction of Co(OH)2 nanoparticles decorated urchin-like WO3 for highly efficient degradation of sulfachloropyridazine via peroxymonosulfate activation: Intermediates and DFT calculation, Chem. Eng. J. 395 (2020) 125186
[54] D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores, Science 279 (5350) (1998) 548–552
[55] Y. Yin, L. Shi, W.L. Li, X.N. Li, H. Wu, Z.M. Ao, W.J. Tian, S.M. Liu, S.B. Wang, H.Q. Sun, Boosting Fenton-like reactions via single atom Fe catalysis, Environ Sci Technol 53 (19) (2019) 11391–11400
[56] Y. Yin, Z.F. Yang, Z.H. Wen, A.H. Yuan, X.Q. Liu, Z.Z. Zhang, H. Zhou, Modification of as synthesized SBA-15 with Pt nanoparticles: nanoconfinement effects give a boost for hydrogen storage at room temperature, Sci Rep 7 (1) (2017) 4509
[57] Y.C. Wang, M.X. Gu, L. Huang, S.C. Qi, P. Tan, X.Q. Liu, L.B. Sun, Unusual copper oxide dispersion achieved by combining the confinement effect and guest-host interaction modulation, Ind. Eng. Chem. Res. 59 (37) (2020) 16296–16304
[58] T. Iida, M. Sato, C. Numako, A. Nakahira, S. Kohara, T. Okubo, T. Wakihara, Preparation and characterization of Silicalite-1 zeolites with high manganese contents from mechanochemically pretreated reactants, J. Mater. Chem. A 3 (11) (2015) 6215–6222
[59] L.Y. Shi, Y.X. Li, D.M. Xue, M.Q. Shao, M.X. Gu, X.Q. Liu, L.B. Sun, Facile fabrication of small-sized palladium nanoparticles in nanoconfined spaces for low-temperature CO oxidation, Ind. Eng. Chem. Res., 59 (2020) 19145-19152
[60] L.Y. Shi, Y.X. Li, D.M. Xue, P. Tan, Y. Jiang, X.Q. Liu, L.B. Sun, Fabrication of highly dispersed nickel in nanoconfined spaces of as-made SBA-15 for dry reforming of methane with carbon dioxide, Chem. Eng. J. 390 (2020) 124491

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jing Huang, Honghui Cai, Qian Zhao, Yunpeng Zhou, Haibo Liu, Jing Wang. Dual-functional pyrene implemented mesoporous silicon material used for the detection and adsorption of metal ions [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 108-117.
[2]	Peipei Ai, Huiqing Jin, Jie Li, Xiaodong Wang, Wei Huang. Ultra-stable Cu-based catalyst for dimethyl oxalate hydrogenation to ethylene glycol [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 186-193.
[3]	Jingjing Pan, Haoran Sun, Keyi Chen, Yuhao Zhang, Pengnian Shan, Weilong Shi, Feng Guo. Nanodiamonds decorated yolk-shell ZnFe₂O₄ sphere as magnetically separable and recyclable composite for boosting antibiotic degradation performance [J]. Chinese Journal of Chemical Engineering, 2023, 54(2): 162-172.
[4]	Jiancheng Shu, Xiangfei Zeng, Danyang Sun, Yong Yang, Zuohua Liu, Mengjun Chen, Daoyong Tan. Enhanced Mn²⁺ solidification and NH₄⁺-N removal from electrolytic manganese metal residue via surfactants [J]. Chinese Journal of Chemical Engineering, 2022, 49(9): 205-212.
[5]	Xian-Tai Zhou, Ling-Ling Wang, Yang Li, Hong-Bing Ji. Liquid-phase epoxidation of propylene with molecular oxygen by chloride manganese meso-tetraphenylporphyrins [J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 61-65.
[6]	Yaping Wang, Songyue Cheng, Wendi Fan, Yikun Jiang, Jie Yang, Zaizai Tong, Guohua Jiang. Dual responsive block copolymer coated hollow mesoporous silica nanoparticles for glucose-mediated transcutaneous drug delivery [J]. Chinese Journal of Chemical Engineering, 2022, 51(11): 35-42.
[7]	Jiahao Wei, Fan Li, Lina Zhou, Dandan Han, Junbo Gong. Strategies for enhancing peroxymonosulfate activation by heterogenous metal-based catalysis: A review [J]. Chinese Journal of Chemical Engineering, 2022, 50(10): 12-28.
[8]	Mingming Guo, Lizhong Liu, Jia-nan Gu, Hongbo Zhang, Xin Min, Jianxing Liang, Jinping Jia, Kan Li, Tonghua Sun. Catalytic performance improvement of volatile organic compounds oxidation over MnO_x and GdMnO₃ composite oxides from spent lithium-ion batteries: Effect of acid treatment [J]. Chinese Journal of Chemical Engineering, 2021, 34(6): 278-288.
[9]	Xinyu Wang, Xinghua Qin, Qiongqiong Lu, Mingming Han, Ahmad Omar, Daria Mikhailova. Mixed phase sodium manganese oxide as cathode for enhanced aqueous zinc-ion storage [J]. Chinese Journal of Chemical Engineering, 2020, 28(8): 2214-2220.
[10]	Zheng Zhang, Yuanhui Ji, Wei Chen. Hollow MnO₂/GNPs serving as a multiresponsive nanocarrier for controlled drug release [J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1405-1414.
[11]	Jiwei Liu, Yufeng Du, Wuyang Sun, Quanchao Chang, Changsheng Peng. A granular adsorbent-supported Fe/Ni nanoparticles activating persulfate system for simultaneous adsorption and degradation of ciprofloxacin [J]. Chinese Journal of Chemical Engineering, 2020, 28(4): 1077-1084.
[12]	Dong Sun, Lin Yang, Ning Liu, Wenju Jiang, Xia Jiang, Jianjun Li, Zhengyou Yang, Zhengping Song. Sulfur resource recovery based on electrolytic manganese residue calcination and manganese oxide ore desulfurization for the clean production of electrolytic manganese [J]. Chinese Journal of Chemical Engineering, 2020, 28(3): 864-870.
[13]	Dong Sun, Guangzhi Xin, Lu Yao, Lin Yang, Xia Jiang, Wenju Jiang. Manganese leaching in high concentration flue gas desulfurization process with semi-oxidized manganese ore [J]. Chinese Journal of Chemical Engineering, 2020, 28(2): 571-578.
[14]	Haibo Zhuang, Yanjun Zhong, Lin Yang. Adsorption equilibrium and kinetics studies of divalent manganese from phosphoric acid solution by using cationic exchange resin [J]. Chinese Journal of Chemical Engineering, 2020, 28(11): 2758-2770.
[15]	Wenjuan Yan, Wenxiang Zhang, Qi Xia, Shuaishuai Wang, Shuxia Zhang, Jian Shen, Xin Jin. Highly dispersed metal incorporated hexagonal mesoporous silicates for catalytic cyclohexanone oxidation to adipic acid [J]. Chinese Journal of Chemical Engineering, 2020, 28(10): 2542-2548.