Kinetics of Non-catalyzed Decomposition of Glucose in High-temperature Liquid Water

Abstract

Abstract: The decomposition kinetics of glucose was studied in high-temperature liquid water(HTLW) from 180 to 220℃ under a pressure of 10 MPa.It was found the main products from glucose decomposition were 5-hydroxymethylfurfural(5-HMF)and levulinic acid(LA).The decomposition kinetics of 5-HMF and stability of LA in HTLW were further investigated.A kinetic model for glucose decomposition was proposed accordingly.In the model,a series of first-order reactions with the consideration of parallel by-reactions were used to illustrate the decomposition of glucose.The decomposition activation energies of glucose,5-HMF,and LA were evaluated as 118.85,95.40,and 31.29 kJ·mol^-1,respectively.

Key words: high-temperature hydrothermal decomposition, glucose, 5-hydroxymethylfurfural, levulinic acid, reaction kinetics

摘要： The decomposition kinetics of glucose was studied in high-temperature liquid water(HTLW) from 180 to 220℃ under a pressure of 10 MPa.It was found the main products from glucose decomposition were 5-hydroxymethylfurfural(5-HMF)and levulinic acid(LA).The decomposition kinetics of 5-HMF and stability of LA in HTLW were further investigated.A kinetic model for glucose decomposition was proposed accordingly.In the model,a series of first-order reactions with the consideration of parallel by-reactions were used to illustrate the decomposition of glucose.The decomposition activation energies of glucose,5-HMF,and LA were evaluated as 118.85,95.40,and 31.29 kJ·mol^-1,respectively.

关键词: high-temperature hydrothermal decomposition, glucose, 5-hydroxymethylfurfural, levulinic acid, reaction kinetics

JING Qi, LÜ Xiuyang. Kinetics of Non-catalyzed Decomposition of Glucose in High-temperature Liquid Water[J]. , 2008, 16(6): 890-894.

荆琪, 吕秀阳. Kinetics of Non-catalyzed Decomposition of Glucose in High-temperature Liquid Water[J]. , 2008, 16(6): 890-894.

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