Promoted catalytic property of Cu/SSZ-13 by introducing a minority of Mn for NO removal from diesel engine exhaust

doi:10.1016/j.cjche.2024.03.022

Chinese Journal of Chemical Engineering ›› 2024, Vol. 71 ›› Issue (7): 172-182.DOI: 10.1016/j.cjche.2024.03.022

Promoted catalytic property of Cu/SSZ-13 by introducing a minority of Mn for NO removal from diesel engine exhaust

Runnong Yang^1,2,5, Wuyuan Liu², Zhaoying Wang², Ming Sun^1,2, Guangying Fu³, Zihan Gao², Wenjian Jiao⁴, Rui Li³, Lin Yu^1,2

1. Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang 515200, China;
2. Guangdong Engineering Technology Research Center of Modern Fine Chemical Engineering, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
3. Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China;
4. Testing and Certification Business Department, China Automotive Technology and Research Center Company Limited, Wuhan 430056, China;
5. Guangdong Foran Technology Company Limited, Foshan 528000, China

Received:2023-09-11 Revised:2024-03-11 Online:2024-08-30 Published:2024-07-28
Contact: Lin Yu,E-mail:gych@gdut.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (22278086). Thanks to the technique support of the Analysis and Test Center of the Guangdong University of Technology.

Promoted catalytic property of Cu/SSZ-13 by introducing a minority of Mn for NO removal from diesel engine exhaust

Runnong Yang^1,2,5, Wuyuan Liu², Zhaoying Wang², Ming Sun^1,2, Guangying Fu³, Zihan Gao², Wenjian Jiao⁴, Rui Li³, Lin Yu^1,2

1. Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center, Jieyang 515200, China;
2. Guangdong Engineering Technology Research Center of Modern Fine Chemical Engineering, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
3. Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China;
4. Testing and Certification Business Department, China Automotive Technology and Research Center Company Limited, Wuhan 430056, China;
5. Guangdong Foran Technology Company Limited, Foshan 528000, China

通讯作者: Lin Yu,E-mail:gych@gdut.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (22278086). Thanks to the technique support of the Analysis and Test Center of the Guangdong University of Technology.

Abstract

Abstract: The Cu-exchanged SSZ-13 with the small-pore chabazite framework is considered as a highly efficient catalyst for selective catalytic reduction of NO with NH₃ (NH₃-SCR). In order to further improve the catalytic property, a series of Mn ion-assisted Cu/SSZ-13 powder catalysts were prepared by co-exchange method and stepwise exchange method. It is found that the NH₃-SCR activity, N₂ selectivity, hydrothermal stability and sulfur resistance of Cu/SSZ-13 are promoted by introducing a minority of Mn (0.15% to 0.23% (mass)) through co-exchange method. Characterization results reveal that the Cu, Mn co-exchange enables the higher amounts of Cu²⁺ active sites, the abundant medium strong and strong acid, the optimized ratio of Lewis acid to Brønsted acid etc., which are required for a good NH₃-SCR catalytic property over broad temperature range and under harsh working environment. Moreover, a monolithic catalyst was prepared by impregnating a cordierite ceramic support into the coating slurry containing the optimized CuMn/SSZ-13 powder. The diesel engine bench tests show that Cu, Mn co-exchange gives the monolith catalyst a better catalytic property than commercial catalysts. This work provides an important guidance for the rational design of secondary-ion-assisted zeolites applied in NH₃-SCR.

Key words: MnCu/SSZ-13, Co-exchange, Zeolite, Catalysis, Selective catalytic reduction

摘要： The Cu-exchanged SSZ-13 with the small-pore chabazite framework is considered as a highly efficient catalyst for selective catalytic reduction of NO with NH₃ (NH₃-SCR). In order to further improve the catalytic property, a series of Mn ion-assisted Cu/SSZ-13 powder catalysts were prepared by co-exchange method and stepwise exchange method. It is found that the NH₃-SCR activity, N₂ selectivity, hydrothermal stability and sulfur resistance of Cu/SSZ-13 are promoted by introducing a minority of Mn (0.15% to 0.23% (mass)) through co-exchange method. Characterization results reveal that the Cu, Mn co-exchange enables the higher amounts of Cu²⁺ active sites, the abundant medium strong and strong acid, the optimized ratio of Lewis acid to Brønsted acid etc., which are required for a good NH₃-SCR catalytic property over broad temperature range and under harsh working environment. Moreover, a monolithic catalyst was prepared by impregnating a cordierite ceramic support into the coating slurry containing the optimized CuMn/SSZ-13 powder. The diesel engine bench tests show that Cu, Mn co-exchange gives the monolith catalyst a better catalytic property than commercial catalysts. This work provides an important guidance for the rational design of secondary-ion-assisted zeolites applied in NH₃-SCR.

关键词: MnCu/SSZ-13, Co-exchange, Zeolite, Catalysis, Selective catalytic reduction

Runnong Yang, Wuyuan Liu, Zhaoying Wang, Ming Sun, Guangying Fu, Zihan Gao, Wenjian Jiao, Rui Li, Lin Yu. Promoted catalytic property of Cu/SSZ-13 by introducing a minority of Mn for NO removal from diesel engine exhaust[J]. Chinese Journal of Chemical Engineering, 2024, 71(7): 172-182.

References

[1] L.P. Han, S.X. Cai, M. Gao, J.Y. Hasegawa, P.L. Wang, J.P. Zhang, L.Y. Shi, D.S. Zhang, Selective catalytic reduction of NO_x with NH₃ by using novel catalysts: State of the art and future prospects, Chem. Rev. 119 (19) (2019) 10916-10976.
[2] M. Kim, S. Cho, K. Jang, S. Hong, J. Na, I. Moon, Data-driven robust optimization for minimum nitrogen oxide emission under process uncertainty, Chem. Eng. J. 428 (2022) 130971.
[3] R.N. Yang, Z.H. Gao, M. Sun, G.Y. Fu, G. Cheng, W.Y. Liu, X.B. Yang, X.Y. Zhao, L. Yu, A highly active VO-MnO/CeO₂ for selective catalytic reduction of NO: The balance between redox property and surface acidity, J. Rare Earths 39 (11) (2021) 1370-1381.
[4] H.H. Li, W. Zhao, L.C. Wu, Q. Wang, D.H. Shang, Q. Zhong, Boosting low-temperature selective catalytic reduction of NO with NH₃ of V₂O₅/TiO₂ catalyst via B-doping, Chin. J. Chem. Eng. 44 (2022) 377-383.
[5] W.J. Zhang, G.F. Liu, J. Jiang, Y.C. Tan, Q. Wang, C.H. Gong, D.K. Shen, C.F. Wu, Temperature sensitivity of the selective catalytic reduction (SCR) performance of Ce-TiO₂ in the presence of SO₂, Chemosphere 243 (2020) 125419.
[6] X.M. Wu, Z.Y. Chen, X.L. Yu, Z.W. Huang, H.Z. Shen, G.H. Jing, Mechanism by which three-dimensional ordered mesoporous CeO₂ promotes the activity of VOx-MnO_x/CeO₂ catalysts for NO_x abatement: Atomic-scale insight into the catalytic cycle, Chem. Eng. J. 399 (2020) 125629.
[7] P. Sazama, R. Pilar, L. Mokrzycki, A. Vondrova, D. Kaucky, J. Plsek, S. Sklenak, P. Stastny, P. Klein, Remarkably enhanced density and specific activity of active sites in Al-rich Cu-, Fe- and Co-beta zeolites for selective catalytic reduction of NO_x, Appl. Catal. B Environ. 189 (2016) 65-74.
[8] J. Ding, X. Huang, Q.L. Yang, L.Z. Wang, Y. Peng, J.H. Li, J. Huang, Micro-structured Cu-ZSM-5 catalyst on aluminum microfibers for selective catalytic reduction of NO by ammonia, Catal. Today 384-386 (2022) 106-112.
[9] W.T. Lv, P.T. Meng, Z.F. Qin, J.F. Li, M. Dong, J.G. Wang, W.B. Fan, A comparison of Al-rich Cu-SSZ-13 zeolites synthesized by different methods in their Al distribution, hydrothermal stability and catalytic performance in the selective catalytic reduction of NO_x with NH₃, Microporous Mesoporous Mater. 313 (2021) 110851.
[10] H.W. Zhao, X.M. Wu, Z.W. Huang, Z.Y. Chen, G.H. Jing, A comparative study of the thermal and hydrothermal aging effect on Cu-SSZ-13 for the selective catalytic reduction of NO with NH₃, Chin. J. Chem. Eng. 45 (2022) 68-77.
[11] B. Guan, J.Y. Chen, J.F. Guo, Z.Q. Liu, C.Z. Zheng, J.F. Zhou, T.X. Su, Y.Y. Zhang, Y.H. Yuan, H.T. Dang, B.Y. Xu, C.Z. Xu, W.B. Zeng, Z. Huang, Study on effect and mechanism of alkaline earth metal poisoning on Cu/SSZ-13 catalysts for selective catalytic reduction of NO_x with NH₃, Ind. Eng. Chem. Res. 62 (25) (2023) 9662-9672.
[12] J.B. He, S. Impeng, J. Zhang, J.P. Zhang, P.L. Wang, D.S. Zhang, SO₂^- tolerant NO_x reduction over SO₄^2--coordinated Cu-SAPO-34 catalysts via protecting the reduction and re-oxidation of Cu sites, Chem. Eng. J. 448 (2022) 137720.
[13] G.Y. Fu, R.N. Yang, Y.Q. Liang, X.F. Yi, R. Li, N.N. Yan, A.M. Zheng, L. Yu, X.B. Yang, J.X. Jiang, Enhanced hydrothermal stability of Cu/SSZ-39 with increasing Cu contents, and the mechanism of selective catalytic reduction of NO, Microporous Mesoporous Mater. 320 (2021) 111060.
[14] N.N. Yan, C. Ma, Y. Cao, X.N. Liu, L. Cao, P. Guo, P. Tian, Z.M. Liu, Rational design of a novel catalyst Cu-SAPO-42 for NH₃-SCR reaction, Small 16 (33) (2020) 2000902.
[15] J.H. Wang, H.W. Zhao, G. Haller, Y.D. Li, Recent advances in the selective catalytic reduction of NO_x with NH₃ on Cu-Chabazite catalysts, Appl. Catal. B Environ. 202 (2017) 346-354.
[16] Z.C. Zhao, R. Yu, R.R. Zhao, C. Shi, H. Gies, F.S. Xiao, D. De Vos, T. Yokoi, X.H. Bao, U. Kolb, M. Feyen, R. McGuire, S. Maurer, A. Moini, U. Muller, W.P. Zhang, Cu-exchanged Al-rich SSZ-13 zeolite from organotemplate-free synthesis as NH₃-SCR catalyst: Effects of Na⁺ ions on the activity and hydrothermal stability, Appl. Catal. B Environ. 217 (2017) 421-428.
[17] R.N. Yang, L. Yu, X.Y. Zhao, X.B. Yang, Z.H. Gao, G.Y. Fu, J.X. Jiang, W.L. Lian, W.Y. Liu, Q. Fan, Phi zeolite synthesized by template-free method for selective catalytic reduction of NO, CIESC J. 71 (12) (2020) 5578-5588.
[18] T. Usui, Z.D. Liu, S. Ibe, J. Zhu, C. Anand, H. Igarashi, N. Onaya, Y. Sasaki, Y. Shiramata, T. Kusamoto, T. Wakihara, Improve the hydrothermal stability of Cu-SSZ-13 zeolite catalyst by loading a small amount of Ce, ACS Catal. 8 (10) (2018) 9165-9173.
[19] D.Y. Guo, R.T. Guo, C.P. Duan, Y.Z. Liu, G.L. Wu, Y. Qin, W.G. Pan, The enhanced K resistance of Cu-SSZ-13 catalyst for NH₃-SCR reaction by the modification with Ce, Mol. Catal. 502 (2021) 111392.
[20] H. Lee, I. Song, S.W. Jeon, D.H. Kim, Control of the Cu ion species in Cu-SSZ-13 via the introduction of Co²⁺ co-cations to improve the NH₃-SCR activity, Catal. Sci. Technol. 11 (14) (2021) 4838-4848.
[21] J.G. Wang, J.Z. Liu, X.J. Tang, C. Xing, T.S. Jin, The promotion effect of niobium on the low-temperature activity of Al-rich Cu-SSZ-13 for selective catalytic reduction of NO_x with NH₃, Chem. Eng. J. 418 (2021) 129433.
[22] F. Gao, Y.L. Wang, N.M. Washton, M. Kollar, J. Szanyi, C.H.F. Peden, Effects of alkali and alkaline earth cocations on the activity and hydrothermal stability of Cu/SSZ-13 NH₃-SCR catalysts, ACS Catal. 5 (11) (2015) 6780-6791.
[23] M.Y. Chen, J.Y. Li, W.J. Xue, S. Wang, J.F. Han, Y.Z. Wei, D.H. Mei, Y. Li, J.H. Yu, Unveiling secondary-ion-promoted catalytic properties of Cu-SSZ-13 zeolites for selective catalytic reduction of NO x, J. Am. Chem. Soc. 144 (28) (2022) 12816-12824.
[24] L.M. Huang, X.M. Wang, S.L. Yao, B.Q. Jiang, X.Y. Chen, X. Wang, Cu-Mn bimetal ion-exchanged SAPO-34 as an active SCR catalyst for removal of NO from diesel engine exhausts, Catal. Commun. 81 (2016) 54-57.
[25] C.M. Song, L.H. Zhang, Z.G. Li, Y.R. Lu, K.X. Li, Co-exchange of Mn: A simple method to improve both the hydrothermal stability and activity of Cu-SSZ-13 NH₃-SCR catalysts, Catalysts 9 (5) (2019) 455.
[26] G. Yang, Y. Wang, D.H. Zhou, J.Q. Zhuang, X.C. Liu, X.W. Han, X.H. Bao, On configuration of exchanged La³⁺ on ZSM-5: A theoretical approach to the improvement in hydrothermal stability of La-modified ZSM-5 zeolite, J. Chem. Phys. 119 (18) (2003) 9765-9770.
[27] S.H. Li, H.Y. Kong, W.P. Zhang, A density functional theory modeling on the framework stability of Al-rich Cu-SSZ-13 zeolite modified by metal ions, Ind. Eng. Chem. Res. 59 (13) (2020) 5675-5685.
[28] X.L. Li, J.J. Feng, Z.G. Xu, J.Q. Wang, Y.J. Wang, W. Zhao, Cerium modification for improving the performance of Cu-SSZ-13 in selective catalytic reduction of NO by NH₃, React. Kinet. Mech. Catal. 128 (1) (2019) 163-174.
[29] Z.H. Wang, X. Xu, Y. Zhu, H. He, N.L. Wang, X.B. Yang, L.C. Liu, One-pot synthesis of hierarchical MnCu-SSZ-13 catalyst with excellent NH₃-SCR activity at low temperatures, Microp. Mesop. Mater. 333 (2022) 111720.
[30] J. Ji, X.L. Lu, C. Chen, M. He, H.B. Huang, Potassium-modulated δ-MnO₂ as robust catalysts for formaldehyde oxidation at room temperature, Appl. Catal. B Environ. 260 (2020) 118210.
[31] S.H. Sui, P.Y. Zhang, H.Y. Zhang, R.R. Cao, Low-temperature catalytic degradation of the odorous pollutant hexanal by γ-MnOOH: The effect of Mn vacancies, Chin. J. Catal. 40 (10) (2019) 1525-1533.
[32] J.X. Liu, Y.H. Du, J. Liu, Z. Zhao, K. Cheng, Y.S. Chen, Y.C. Wei, W.Y. Song, X. Zhang, Design of MoFe/Beta@CeO₂ catalysts with a core-shell structure and their catalytic performances for the selective catalytic reduction of NO with NH₃, Appl. Catal. B Environ. 203 (2017) 704-714.
[33] U. Deka, A. Juhin, E.A. Eilertsen, H. Emerich, M.A. Green, S.T. Korhonen, B.M. Weckhuysen, A.M. Beale, Confirmation of isolated Cu²⁺ ions in SSZ-13 zeolite as active sites in NH₃-selective catalytic reduction, J. Phys. Chem. C 116 (7) (2012) 4809-4818.
[34] S.T. Korhonen, D.W. Fickel, R.F. Lobo, B.M. Weckhuysen, A.M. Beale, Isolated Cu²⁺ ions: Active sites for selective catalytic reduction of NO, Chem. Commun. 47 (2) (2011) 800-802.
[35] M.H. Xu, J. Wang, T. Yu, J.Q. Wang, M.Q. Shen, New insight into Cu/SAPO-34 preparation procedure: Impact of NH₄-SAPO-34 on the structure and Cu distribution in Cu-SAPO-34 NH₃-SCR catalysts, Appl. Catal. B Environ. 220 (2018) 161-170.
[36] S.J. Ming, L. Pang, C. Fan, W. Guo, Y.H. Dong, P. Liu, Z. Chen, T. Li, Chemical deactivation of Cu-SAPO-18 deNO catalyst caused by basic inorganic contaminants in diesel exhaust, Chin. J. Catal. 40 (4) (2019) 590-599.
[37] N. Zhu, W.P. Shan, Y.L. Shan, J.P. Du, Z.H. Lian, Y. Zhang, H. He, Effects of alkali and alkaline earth metals on Cu-SSZ-39 catalyst for the selective catalytic reduction of NO with NH₃, Chem. Eng. J. 388 (2020) 124250.
[38] D. Wang, Y. Peng, Q.L. Yang, F.Y. Hu, J.H. Li, J. Crittenden, NH₃-SCR performance of WO₃ blanketed CeO₂ with different morphology: Balance of surface reducibility and acidity, Catal. Today 332 (2019) 42-48.
[39] M. Jablonska, R. Palkovits, Copper based catalysts for the selective ammonia oxidation into nitrogen and water vapour-recent trends and open challenges, Appl. Catal. B Environ. 181 (2016) 332-351.
[40] A. Sultana, T. Nanba, M. Haneda, M. Sasaki, H. Hamada, Influence of co-cations on the formation of Cu⁺ species in Cu/ZSM-5 and its effect on selective catalytic reduction of NO_x with NH₃. Appl. Catal. B: Environ. 101 (2010) 61-67.
[41] F. Benaliouche, Y. Boucheffa, P. Ayrault, S. Mignard, P. Magnoux, NH₃-TPD and FTIR spectroscopy of pyridine adsorption studies for characterization of Ag- and Cu-exchanged X zeolites. Micro. Meso. Mater. 111 (2008) 80-88.
[42] Z.X. Chen, M.Q. Shen, C. Wang, J.Q. Wang, J. Wang, G.R. Shen, Improvement of alkali metal resistance for NH₃-SCR catalyst Cu/SSZ-13: Tune the crystal size, Catalysts 11 (8) (2021) 979.
[43] Z. Liu, Y. Yi, J. Li, S.I. Woo, B. Wang, X. Cao, Z. Li, A superior catalyst with dual redox cycles for the selective reduction of NO(x) by ammonia, Chem. Commun. 49 (70) (2013) 7726-7728.
[44] D.L. Yuan, X.Y. Li, Q.D. Zhao, J.J. Zhao, S.M. Liu, M.Tade, Effect of surface Lewis acidity on selective catalytic reduction of NO by C₃H₆ over calcined hydrotalcite, Appl. Catal. A Gen. 451 (2013) 176-183.
[45] W.Y. Liu, Z.H. Gao, X.Y. Zhao, J.J. Gao, R.N. Yang, L. Yu, Promotion effect of chromium on the activity and SO₂ resistance of CeO₂-TiO₂ catalysts for the NH₃-SCR reaction, Ind. Eng. Chem. Res. 60 (31) (2021) 11676-11688.
[46] Y.L. Shan, J.P. Du, Y.B. Yu, W.P. Shan, X.Y. Shi, H. He, Precise control of post-treatment significantly increases hydrothermal stability of in-situ synthesized cu-zeolites for NH₃-SCR reaction. Appl. Catal. B: Enviro. 266 (2020) 118655.
[47] Y. Ma, X.D. Wu, S.Q. Cheng, L.M. Cao, L.P. Liu, Y.F. Xu, J.B. Liu, R. Ran, Z.C. Si, D. Weng, Relationships between copper speciation and Broensted acidity evolution over Cu-SSZ-13 during hydrothermal aging, Appl. Catal. A Gen. 602 (2020) 117650.
[48] L.J. Jiang, Q.C. Liu, G.J. Ran, M. Kong, S. Ren, J. Yang, J.L. Li, V₂O₅-modified Mn-Ce/AC catalyst with high SO₂ tolerance for low-temperature NH₃-SCR of NO. Chem. Eng. J. 370 (2019) 810-821.
[49] Y.L. Li, W.M. Liu, R. Yan, J. Liang, T. Dong, Y.Y. Mi, P. Wu, Z. Wang, H.G. Peng, T.C. An, Hierarchical three-dimensionally ordered macroporous Fe-V binary metal oxide catalyst for low temperature selective catalytic reduction of NO_x from marine diesel engine exhaust, Appl. Catal. B Environ. 268 (2020) 118455.
[50] Y. Jangjou, Q. Do, Y.T. Gu, L.G. Lim, H. Sun, D. Wang, A. Kumar, J.H. Li, L.C. Grabow, W.S. Epling, Nature of Cu active centers in Cu-SSZ-13 and their responses to SO₂ exposure, ACS Catal. 8 (2) (2018) 1325-1337.
[51] C.L. Yu, B.C. Huang, L.F. Dong, F. Chen, Y. Yang, Y.M. Fan, Y.X. Yang, X.Q. Liu, X.N. Wang, Effect of Pr/Ce addition on the catalytic performance and SO 2 resistance of highly dispersed MnO x/SAPO-34 catalyst for NH 3-SCR at low temperature, Chem. Eng. J. 316 (2017) 1059-1068.
[52] R.V. Siriwardane, J.A. Poston, E.P. Fisher, M.S. Shen, A.L. Miltz, Decomposition of the sulfates of copper, iron (II), iron (III), nickel, and zinc: XPS, SEM, DRIFTS, XRD, and TGA study, Appl. Surf. Sci. 152 (3-4) (1999) 219-236.
[53] L.Q. Mao, A. T-Raissi, C.P. Huang, N.Z. Muradov, Thermal decomposition of (NH₄)₂SO₄ in presence of Mn₃O₄, Int. J. Hydrog. Energy 36 (10) (2011) 5822-5827.
[54] H. Liu, Z.X. Fan, C.Z. Sun, S.H. Yu, S. Feng, W. Chen, D.Z. Chen, C.J. Tang, F. Gao, L. Dong, Improved activity and significant SO₂ tolerance of samarium modified CeO₂-TiO₂ catalyst for NO selective catalytic reduction with NH₃. Appl. Catal. B: Environ. 244 (2019) 671-683.
[55] J. Li, Study of optimized engine-bench evaluation methods of urea-SCR catalyst for diesel vehicle applications, Ph. D. Thesis, Tianjin Univ., China, 2015.

Promoted catalytic property of Cu/SSZ-13 by introducing a minority of Mn for NO removal from diesel engine exhaust

Promoted catalytic property of Cu/SSZ-13 by introducing a minority of Mn for NO removal from diesel engine exhaust

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jiaxin Zhang, Lu Wang, Zhiqiang Ma, Chuanjun Di, Guanghui Chen, Jipeng Dong, Jianlong Li, Fei Gao. One-step preparation of efficient cuprous chloride catalyst for direct synthesis of trimethoxysilane [J]. Chinese Journal of Chemical Engineering, 2024, 71(7): 161-171.
[2]	B. A. Abdulkadir, R. S. R. Mohd Zaki, A. T. Abd Wahab, S. N. Miskan, Anh-Tam Nguyen, Dai-Viet N. Vo, H. D. Setiabudi. A concise review on surface and structural modification of porous zeolite scaffold for enhanced hydrogen storage [J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 33-53.
[3]	Yanli Qu, Peng Dong, Li Yang, Yuanyuan Yue, Haoliang Wang, Jingcai Cheng, Chao Yang. Synthesis of NaY zeolite from a submolten depolymerized perlite: Alkalinity effect and crystallization kinetics [J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 130-138.
[4]	Pei Li, Bianfang Shi, Junyao Shen, Ran Cui, Wenze Guo, Ling Zhao, Zhenhao Xi. Phosphotungstic acid immobilized on amino-functionalized TS-1 zeolite as a solid acid catalyst for the synthesis of tributyl citrate [J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 199-210.
[5]	Shiqi Zhang, Shengzhi Gan, Baoyu Liu, Jinxiang Dong. Production of linear alkylbenzene over Ce containing Beta zeolites [J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 220-227.
[6]	Siyue Wang, Jinhong Li, Qingxin Xu, Shengjie Song, Yu'ni Jiang, Lidong Chen, Xin Shi, Weiguo Cheng. Synthesis of spherical nano-ZSM-5 zeolite with intergranular mesoporous for alkylation of ethylbenzene with ethanol to produce m-diethylbenzene [J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 298-309.
[7]	Yi-Fei Liang, Jin-Rong Lu, Shang-Kun Tian, Wen-Quan Cui, Li Liu. Pt nanoclusters modified porous g-C₃N₄ nanosheets to significantly enhance hydrogen production by photocatalytic water reforming of methanol [J]. Chinese Journal of Chemical Engineering, 2024, 66(2): 40-50.
[8]	Tiesen Li, Ting Chen, Yinghui Ye, Peng Dong, Tinghai Wang, Qingyan Cui, Chan Wang, Yuanyuan Yue. OSDA-free synthesis of FeZSM-22 zeolite from natural minerals for n-octane hydroisomerization [J]. Chinese Journal of Chemical Engineering, 2024, 66(2): 51-59.
[9]	Zhihao Guo, Jiuxuan Zhang, Lanlan Chen, Chaoqun Fan, Hong Jiang, Rizhi Chen. Hollow ZIF-67-derived Co@N-doped carbon nanotubes boosting the hydrogenation of phenolic compounds to alcohols [J]. Chinese Journal of Chemical Engineering, 2024, 66(2): 157-166.
[10]	Yinghui Liu, Shaoduo Liu, Xiaosheng Wang, Hongjing Wang, Ranjia Li, Changchun Yu, Chunming Xu, Yuxiang Liu, Zhengqiu Xie, Yongqiang Wang, Pan Tang. Synthesis of mordenite by solvent-free method and its application in the dimethyl ether carbonylation reaction [J]. Chinese Journal of Chemical Engineering, 2024, 66(2): 216-223.
[11]	Wen Xiao, Peng Dong, Chan Wang, Jingdong Xu, Tiesen Li, Haibo Zhu, Tinghai Wang, Renwei Xu, Yuanyuan Yue. Facile synthesis of hierarchical NaX zeolite from natural kaolinite for efficient Knoevenagel condensation [J]. Chinese Journal of Chemical Engineering, 2024, 65(1): 75-84.
[12]	Guixian Li, Tao Tian, Hanxu Li, Jinlian Li, Tingna Shao, Qi Zhang, Peng Dong. Anti-carbon deposition performance of twinned HZSM-5 encapsulated Ru in the toluene alkylation with methanol [J]. Chinese Journal of Chemical Engineering, 2023, 61(9): 1-8.
[13]	Ting Li, Hongxia Guo, Xiao Wang, Huan Wang, Li Liu, Wenquan Cui, Xiaoran Sun, Yinghua Liang. Loading CuO on the surface of MgO with low-coordination basic O^2- sites for effective enhanced CO₂ capture and photothermal synergistic catalytic reduction of CO₂ to ethanol [J]. Chinese Journal of Chemical Engineering, 2023, 61(9): 58-67.
[14]	Baoyu Liu, Feng Xiong, Jianwen Zhang, Manna Wang, Yi Huang, Yanxiong Fang, Jinxiang Dong. Enhanced ortho-selective t–butylation of phenol over sulfonic acid functionalized mesopore MTW zeolites [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 1-7.
[15]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 205-211.