SCI和EI收录∣中国化工学会会刊

›› 2009, Vol. 17 ›› Issue (1): 171-174.

• RESEARCH NOTES • Previous Articles     Next Articles

Rapid and Continuous Production of LiFePO4/C Nanoparticles in Super Heated Water

YU Wenli1, ZHAO Yaping1, RAO Qunli2   

  1. 1. School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240, China;
    2. Instrumental Analysis Centre, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2008-03-05 Revised:2008-07-18 Online:2009-01-28 Published:2009-01-28
  • Supported by:
    Supported by Shanghai Special Foundation on Nanomaterials (0243nm305)

Rapid and Continuous Production of LiFePO4/C Nanoparticles in Super Heated Water

于文利1, 赵亚平1, 饶群力2   

  1. 1. School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240, China;
    2. Instrumental Analysis Centre, Shanghai Jiao Tong University, Shanghai 200240, China
  • 通讯作者: ZHAO Yaping, E-mail: ypzhao@sjtu.edu.cn
  • 基金资助:
    Supported by Shanghai Special Foundation on Nanomaterials (0243nm305)

Abstract: A rapid and continuous method for production of LiFePO4/C nanoparticles in super heated water is described, wherein soluble starch was used as carbon precursor.The effects of pH, flow rate, temperature, and pressure on the formation of LiFePO4/C particles were investigated.Results showed that the pH value was the key factor on the formation of phase pure LiFePO4, which only formed at pH=7;the LiFePO4/C occurred as particles with about 70-200 nm size and LiFePO4 was covered by a thin carbon layer;higher flow rate, higher pressure, and lower temperature led to smaller particles of LiFePO4/C.

Key words: LiFePO4/C, nanoparticle, super heated water

摘要: A rapid and continuous method for production of LiFePO4/C nanoparticles in super heated water is described,wherein soluble starch was used as carbon precursor.The effects of pH,flow rate,temperature,and pressure on the formation of LiFePO4/C particles were investigated.Results showed that the pH value was the key factor on the formation of phase pure LiFePO4,which only formed at pH=7;the LiFePO4/C occurred as particles with about 70-200 nm size and LiFePO4 was covered by a thin carbon layer;higher flow rate,higher pressure,and lower temperature led to smaller particles of LiFePO4/C.

关键词: LiFePO4/C, nanoparticle, super heated water