Thermal coupling study during the co-processing of coal and biomass in the lab-scale adiabatic reactor

doi:10.1016/j.cjche.2024.10.018

Abstract

Abstract: A lab-scale adiabatic reactor has been self-made to characterize the coupled properties of heat and reactions during the co-thermal-processing of coal and biomass with steam or steam/O₂ gasification agents. Results showed that the synergistic effects caused by heat transfer between corncob and coal at different mixing ratios were heavily determined by coal rank and gasification agent. During steam co-processing, the heat transfer from corncob char to adjacent bituminous coal char promoted the water-gas reaction on coal char and contributed to synergistic effects; the heat transfer from anthracite char to adjacent corncob char reduced the kinetic rate of the water-gas reaction on coal char and contributed to inhibitory effects, and the inhibitory effect caused by heat transfer was greater than the promotion effects of biomass mass transfer. The introduction of O₂ diminished the impact of inter-particle heat transfer and altered the intensity of synergy, decreasing the values of synergy factor of bituminous coal/corncob blends by 17% and increasing the value of synergy factor of anthracite/corncob blends by 142.5%. This study provides sufficient support for the process conditions selection for the production of syngas with specific H₂/CO molar ratios and the desired level of gasification performance.

Key words: Co-processing, Element utilization efficiency, Reaction heat, Heat transfer, Synergistic effect

摘要： A lab-scale adiabatic reactor has been self-made to characterize the coupled properties of heat and reactions during the co-thermal-processing of coal and biomass with steam or steam/O₂ gasification agents. Results showed that the synergistic effects caused by heat transfer between corncob and coal at different mixing ratios were heavily determined by coal rank and gasification agent. During steam co-processing, the heat transfer from corncob char to adjacent bituminous coal char promoted the water-gas reaction on coal char and contributed to synergistic effects; the heat transfer from anthracite char to adjacent corncob char reduced the kinetic rate of the water-gas reaction on coal char and contributed to inhibitory effects, and the inhibitory effect caused by heat transfer was greater than the promotion effects of biomass mass transfer. The introduction of O₂ diminished the impact of inter-particle heat transfer and altered the intensity of synergy, decreasing the values of synergy factor of bituminous coal/corncob blends by 17% and increasing the value of synergy factor of anthracite/corncob blends by 142.5%. This study provides sufficient support for the process conditions selection for the production of syngas with specific H₂/CO molar ratios and the desired level of gasification performance.

关键词: Co-processing, Element utilization efficiency, Reaction heat, Heat transfer, Synergistic effect

Laisong Wang, Zhidi Du, Jie Feng, Xiaolong Shi, Wenying Li. Thermal coupling study during the co-processing of coal and biomass in the lab-scale adiabatic reactor[J]. Chinese Journal of Chemical Engineering, 2025, 78(2): 303-313.

Laisong Wang, Zhidi Du, Jie Feng, Xiaolong Shi, Wenying Li. Thermal coupling study during the co-processing of coal and biomass in the lab-scale adiabatic reactor[J]. 中国化学工程学报, 2025, 78(2): 303-313.

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