Kinetics of non-catalyzed decomposition of d-xylose in high temperature liquid water

Abstract

Abstract: The kinetics of non-catalyzed decompositions of xylose and its decomposition product furfural in high temperature liquid water (HTLW) was studied for temperature from 180 to 220℃ and under pressure of 10MPa. The main products of xylose decomposition were furfural and formic acid, and furfural further degraded to formic acid under HTLW condition. With the assumption of first order kinetics equation, the evaluated activation energy of xylose and furfural decomposition was 123.27kJ•mol－1 and 58.84kJ•mol－1, respectively.

Key words: high temperature liquid water, xylose, furfural, decomposition, reaction kinetics

摘要： The kinetics of non-catalyzed decompositions of xylose and its decomposition product furfural in high temperature liquid water (HTLW) was studied for temperature from 180 to 220℃ and under pressure of 10MPa. The main products of xylose decomposition were furfural and formic acid, and furfural further degraded to formic acid under HTLW condition. With the assumption of first order kinetics equation, the evaluated activation energy of xylose and furfural decomposition was 123.27kJ•mol－1 and 58.84kJ•mol－1, respectively.

关键词: high temperature liquid water;xylose;furfural;decomposition;reaction kinetics

JING Qi, LÜ, Xiuyang. Kinetics of non-catalyzed decomposition of d-xylose in high temperature liquid water[J]. , DOI: .

荆琪, 吕秀阳. 高温液态水中木糖无催化分解反应动力学[J]. , DOI: .

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