Synergistic Multilayer Adsorption for Low Concentration Dyestuffs by Biomass

摘要/Abstract

摘要： Due to the high cost of adsorbents and their thermal regeneration in recent years,much research has focused on the search for cheaper adsorbents for treating wastewater from textile industry.The single component adsorption of an acidic dye,Acid Yellow 117,and a basic dye,Methylene Blue,onto several adsorbents—bamboo,waste wood,bamboo char,waste wood char,bamboo activated carbon,wood activated carbon and active carbon F400 were conducted.Based on a Langmuir analysis,the monolayer adsorption capacities were determined.Three of the adsorbents were selected for binary layer adsorption to check the multilayer concept and the potential application for better adsorbent usage.The two cheapest adsorbents,bamboo and wood are compared with the commercial activated carbon F400,and all three systems were successful.

关键词: multilayer, adsorption, biomass, dyestuffs

Abstract: Due to the high cost of adsorbents and their thermal regeneration in recent years,much research has focused on the search for cheaper adsorbents for treating wastewater from textile industry.The single component adsorption of an acidic dye,Acid Yellow 117,and a basic dye,Methylene Blue,onto several adsorbents—bamboo,waste wood,bamboo char,waste wood char,bamboo activated carbon,wood activated carbon and active carbon F400 were conducted.Based on a Langmuir analysis,the monolayer adsorption capacities were determined.Three of the adsorbents were selected for binary layer adsorption to check the multilayer concept and the potential application for better adsorbent usage.The two cheapest adsorbents,bamboo and wood are compared with the commercial activated carbon F400,and all three systems were successful.

Key words: multilayer, adsorption, biomass, dyestuffs

Keith Kim Hung Choy, Gordon Mckay. Synergistic Multilayer Adsorption for Low Concentration Dyestuffs by Biomass[J]. , 2012, 20(3): 560-566.

参考文献

1 Gottlieb, A., Shaw, C., Smith, A., Wheatley, A., Forsythe, S., "Toxicity of textile reactive azo dyes after hydrolysis and decolorisation", J. Biotechnol., 101, 49-56 (2003).
2 Mathura, N., Bhatnagara, P., Nagarb, P., Bijarnia, M.K., "Mutagenicity assessment of effluents from textile/dye industries of Sanganer, Jaipur (India): A case study", Ecotoxicol. Environ. Safety, 61 (1), 105-113 (2005).
3 Carliell, C.M., Barclay, S.J., Shaw, C., Wheatley, A.D., Buckley, C.A, "The effect of salts used in textile dyeing on microbial decolourisation of a reactive azo dye", Environ. Technol., 19 (11), 1133-1137 (1998).
4 McKay, G., Use of Adsorbents for the Removal of Pollutants from Wastewaters, CRC Press, Boca Raton, FL, USA (1995).
5 Poots, V.J.P., McKay, G., Healy, J.J., "The removal of basic dye from effluent using Naturally occurring adsorbents (I) Peat", Water Res., 10, 1061-1066 (1976).
6 Walker, G.M., Weatherley, L.R., "Adsorption of acid dyes on to granular activated carbon in fixed beds", Water Res., 31 (8), 2093-2101 (1998).
7 Ho, Y.S., McKay, G., "Sorption of dye from aqueous solution by peat", Chem. Eng. J., 70 (2), 115-124 (1998).
8 Ho, Y.S., McKay, G., "The kinetics of sorption of divalent metal ions onto sphagnum moss moss", Water Res., 34 (3), 735-742 (1999).
9 Davies, R.A., Kaempf, H.J., Clemens, M.M., "Granular carbon for the treatment of textile effluents", Chem. Ind., 827-831 (1973).
10 McKay, G., "Adsorption of dyestuffs from aqueous solutions with activated carbon (I) Equilibrium and batch contact time studies", J. Chem. Technol. Biotechnol., 32, 759-772 (1982).
11 McKay, G., El Geundi, M.S., Nassar, M.M., "Equilibrium studies during the removal of dyestuffs from aqueous solutions using bagasse pith", Water Res., 21 (12), 1513-1518 (1987).
12 Namasivayam, C., Muniasamy, N., Gayatri, K., Rani, M., Ranganathan, K., "Removal of dyes from aqueous solutions by cellulosic waste orange peel", Biores. Technol., 57, 37-42 (1996).
13 Namasivayam, C., Prabha, D., Kumutha, M., "Removal of direct red and acid brilliant blue by adsorption on to banana pith", Bioresour. Technol., 64 (1), 77-79 (1998).
14 Chen, B., Hui, C.W., McKay, G., "Pore-surface diffusion modelling for dyes from effluents on pith", Langmuir, 17, 740-748 (2001).
15 Namasivayam, C., Radhika, R., Suba, S., "Uptake of dyes by a promising locally available agricultural solid waste: Coir pith", Waste Manage., 21 (4), 381-387 (2001).
16 Namasivayam, C., Kavitha, D., "Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste", J. Dyes Pigments, 54 (1), 47-58 (2002).
17 McKay, G., Otterburn, M.S., Sweeney, A.G., "Fuller's earth and fired clay as adsorbents for dyestuffs-Equilibrium and rate studies", Water, Air, Soil Poll., 24, 307-313 (1985).
18 Atun, G., Hisarli, G., Sheldrick, W. S., Muhler, M., "Adsorptive removal of methylene blue from colored effluents on fuller's earth", J. Colloid Interface Sci., 261 (1), 32-39 (2003).
19 Poots, V.J.P., McKay, G., Healy, J.J., "Removal of acid dye from effluent using natural adsorbents (2) Wood", Water Res., 10 (12), 1067-1070 (1976).
20 Asfour, H.M., Nassar, M.M., Fadali, O.A., Elgeundi, M.S., "Color removal from textile effluents using hardwood sawdust as an adsorbent", 35 (1), 28-35 (1985).
21 McKay, G., Ho, Y.S., " Kinetic models for the sorption of dye from aqueous solution by wood", Trans. I. Chem. E., 70, 115-124 (1998).
22 Ho, Y.S., McKay, G., "Pseudo-second order model for sorption processes", Process Biochem., 34 (5), 451-465 (1998).
23 Elgeundi, M.S., "Color removal from textile effluents by adsorption techniques", Water Res., 25 (3), 271-273 (1991).
24 Namasivayam, C., Arasi, D., "Removal of Congo red from wastewater by adsorption onto waste red mud", Chemosphere, 34 (2), 401-417 (1997).
25 Namasivayam, C., Yamuna, R.T., Arasi, D., "Removal of acid violet from wastewater by adsorption on waste red mud", Environ. Geol., 41 (3-4), 269-273 (2001).
26 Namasivayam, C., Yamuna, R.T., Arasi, D., "Removal of procion orange from wastewater by adsorption on waste red mud", Sep. Sci. Technol., 37 (10), 2421-2431 (2002).
27 Marshall, W.E., Champagne, E.T., "Agricultural by-products as adsorbents for metal-ions in laboratory prepared solutions and in manufacturing waste-water", J. Environ. Sci. Health A Environ. Sci. Eng. Toxic Hazard. Subt. Control, 30 (2), 241-261 (1995).
28 Marshall, W.E., Johns, M.M., "Agricultural by-products as metal adsorbents: Sorption properties and resistance to mechanical abrasion", J. Chem. Technol. Biotechnol., 66 (2), 192-198 (1996).
29 Valix, M., Cheung, W.H., McKay, G., "Preparation of activated carbon using low temperature carbonisation and physical activation of high ash raw bagasse for acid dye adsorption", Chemosphere, 56 (5), 493-501 (2004).
30 Yoshida, H., Fukuda, S., Okamoto, A., Kataoka, T., "Recovery of direct dye and acid dye by adsorption on chitosan fiber-Equilibria", Water Sci. Technol., 23 (7-9), 1667-1676 (1991).
31 Yoshida, H., Okamoto, A., Kataoka, T., "Adsorption of acid dye on cross-linked chitosan fibers-Equilibria", Chem. Eng. Sci., 48 (12), 2267-2272 (1993).
32 Yoshida, H., Takemori, T., "Adsorption of direct dye on cross-linked chitosan fiber: Breakthrough curve", Water Sci. Technol., 35 (7), 29-37 (1997).
33 Kim, C.Y., Choi, H.M., Cho, H.T., "Effect of deacetylation on sorption of dyes and chromium on chitin", J. Appl. Polym. Sci., 63 (6), 725-736 (1997).
34 Knorr, D., "Dye binding-properties of chitin and chitosan", J. Food Sci., 48 (1): 36-41 (1983).
35 dos Anjos, F.S.C., Vieira, E.F.S., Cestari, A.R., "Interaction of indigo carmine dye with chitosan evaluated by adsorption and thermochemical data", J. Colloid Interface Sci., 253 (2), 243-246 (2002).
36 Shimizu, Y., Kono, K., Kim, I.S., Takagishi, T., "Effects of added metal-ions on the interaction of chitin and partially deacetylated chitin with an azo-dye carrying hydroxyl-groups", J. Appl. Polym. Sci., 55 (2), 255-261 (1995).
37 Gerente, C., Lee, V.K.C., Le Cloirec, P., McKay, G., "Application of chitosan for the removal of metals from wastewaters by adsorption-Mechanisms and models review", Criti. Rev. Envir. Sci. Technol., 37, 41-127 (2007).
38 Wong, Y.C., Szeto, Y.S., Cheung, W.H., McKay, G., "Effect of temperature, particle and percentage deacetylation on the adsorption of acid dyes on chitosan", Adsorption, 14, 11-20 (2008).
39 Langmuir, I., "The adsorption of gases on plane surfaces of glass, mica and platinum", J. Am. Chem. Soc., 40 (9), 1361-1403 (1918).
40 Freundlich, H., "Concerning adsorption in solutions", Z. Physik Chem., A57 (4), 385-470 (1906).

[1]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions[J]. 中国化学工程学报, 2023, 60(8): 26-36.
[2]	Jing Huang, Honghui Cai, Qian Zhao, Yunpeng Zhou, Haibo Liu, Jing Wang. Dual-functional pyrene implemented mesoporous silicon material used for the detection and adsorption of metal ions[J]. 中国化学工程学报, 2023, 60(8): 108-117.
[3]	Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. 中国化学工程学报, 2023, 60(8): 212-227.
[4]	Alexander Nti Kani, Evans Dovi, Aaron Albert Aryee, Runping Han, Zhaohui Li, Lingbo Qu. Mechanisms and reusability potentials of zirconium-polyaziridine-engineered tiger nut residue towards anionic pollutants[J]. 中国化学工程学报, 2023, 60(8): 275-292.
[5]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework[J]. 中国化学工程学报, 2023, 59(7): 9-15.
[6]	Hui Jiang, Zijian Zhao, Ning Yu, Yi Qin, Zhengwei Luo, Wenhua Geng, Jianliang Zhu. Synthesis, characterization, and performance comparison of boron using adsorbents based on N-methyl-D-glucosamine[J]. 中国化学工程学报, 2023, 59(7): 16-31.
[7]	Jian Han, Xinhua Liu, Shanwei Hu, Nan Zhang, Jingjing Wang, Bin Liang. Optimization of decoupling combustion characteristics of coal briquettes and biomass pellets in household stoves[J]. 中国化学工程学报, 2023, 59(7): 182-192.
[8]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application[J]. 中国化学工程学报, 2023, 59(7): 262-269.
[9]	Shanghong Ma, Haitao Zhang, Jianbo Qu, Xiuzhong Zhu, Qingfei Hu, Jianyong Wang, Peng Ye, Futao Sai, Shiwei Chen. Preparation of waterborne polyurethane/β-cyclodextrin composite nanosponge by ion condensation method and its application in removing of dyes from wastewater[J]. 中国化学工程学报, 2023, 58(6): 124-136.
[10]	Wende Tian, Jiawei Zhang, Zhe Cui, Haoran Zhang, Bin Liu. Microscopic mechanism study and process optimization of dimethyl carbonate production coupled biomass chemical looping gasification system[J]. 中国化学工程学报, 2023, 58(6): 291-305.
[11]	Qi Yang, Weikang Dai, Maoshuai Li, Jie Wei, Yi Feng, Cheng Yang, Wanxin Yang, Ying Zheng, Jie Ding, Mei-Yan Wang, Xinbin Ma. Enhanced selective hydrogenation of glycolaldehyde to ethylene glycol over Cu⁰-Cu⁺ sites[J]. 中国化学工程学报, 2023, 57(5): 141-150.
[12]	Yueting Shi, Junhai Zhao, Lingli Chen, Hongru Li, Shengtao Zhang, Fang Gao. Double open mouse-like terpyridine parts based amphiphilic ionic molecules displaying strengthened chemical adsorption for anticorrosion of copper in sulfuric acid solution[J]. 中国化学工程学报, 2023, 57(5): 233-246.
[13]	Jian Wang, Yuanhui Shen, Donghui Zhang, Zhongli Tang, Wenbin Li. Integrated vacuum pressure swing adsorption and Rectisol process for CO₂ capture from underground coal gasification syngas[J]. 中国化学工程学报, 2023, 57(5): 265-279.
[14]	Yujia Cui, Zhiqiang Tan, Yanan Wang, Shuxian Shi, Xiaonong Chen. One-step crosslinking preparation of tannic acid particles for the adsorption and separation of cationic dyes[J]. 中国化学工程学报, 2023, 57(5): 309-318.
[15]	Shanshan Mao, Tao Shen, Qing Zhao, Tong Han, Fan Ding, Xin Jin, Manglai Gao. Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets[J]. 中国化学工程学报, 2023, 57(5): 319-328.