Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)

doi:10.1016/S1004-9541(13)60621-7

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (11): 1260-1268.DOI: 10.1016/S1004-9541(13)60621-7

Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)

岳敏^1,2, 张猛¹, 刘斌³, 许醒¹, 李小明¹, 岳钦艳¹, 马春元²

1 School of Environmental Science and Engineering, Shandong University, Jinan 250100, China;
2 Postdoctoral Research Station of Power Engineering and Engineering Thermophysics, Shandong University, Jinan 250063, China;
3 Shandong Quality Inspection Center for Medical Devices, Jinan 250101, China

收稿日期:2012-04-23 修回日期:2012-10-15 出版日期:2013-11-28 发布日期:2013-11-26
通讯作者: YUE Min
基金资助:
Supported by the Independent Innovation Foundation of Shandong University (2012TS036).

Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)

YUE Min^1,2, ZHANG Meng¹, LIU Bin³, XU Xing¹, LI Xiaoming¹, YUE Qinyan¹, MA Chunyuan²

1 School of Environmental Science and Engineering, Shandong University, Jinan 250100, China;
2 Postdoctoral Research Station of Power Engineering and Engineering Thermophysics, Shandong University, Jinan 250063, China;
3 Shandong Quality Inspection Center for Medical Devices, Jinan 250101, China

Received:2012-04-23 Revised:2012-10-15 Online:2013-11-28 Published:2013-11-26
Contact: YUE Min
Supported by:
Supported by the Independent Innovation Foundation of Shandong University (2012TS036).

摘要/Abstract

摘要： Modified peanut shell (MPS) was prepared by amination reaction with peanut shell (PS) as the starting material. The sorption of Cr(Ⅵ) oxyanions on MPS in static and column tests were investigated. In addition, the sorption isotherm and kinetic models were applied to confirm the sorption capacity and the sorption mechanisms. BET surface area analysis showed the physicochemical characteristics of the samples. The results of zeta potential, Fourier transform infrared (FT-IR) and Raman spectra analysis illustrated that chemical adsorption and ion exchange are the potential sorption mechanism. The static sorption test showed that the maximum sorption capacity (q_max) of MPS for Cr(Ⅵ) increased with temperature, which indicated that the Cr(Ⅵ) sorption process was endothermic. The saturated sorption capacity of Cr(Ⅵ) in the column sorption test was 138.34 mg·g^-1, which accounted for 93.9% of the q_max at 25 ℃. The regeneration capacity of MPS was evaluated using HCl solution as an eluent. The high regeneration efficiency (82.6%) validated the dominance of the ion exchange mechanism in the Cr(Ⅵ) sorption process with Cl^- ions displacing Cr(Ⅵ) oxyanion on MPS. The Langmuir isotherm model showed a higher correlation coefficient than the other adsorption isotherm models. And in the kinetic study, a pseudo-second-order model fit the data best.

关键词: modified peanut shell, amination, Cr(Ⅵ), adsorption, mechanism

Abstract: Modified peanut shell (MPS) was prepared by amination reaction with peanut shell (PS) as the starting material. The sorption of Cr(Ⅵ) oxyanions on MPS in static and column tests were investigated. In addition, the sorption isotherm and kinetic models were applied to confirm the sorption capacity and the sorption mechanisms. BET surface area analysis showed the physicochemical characteristics of the samples. The results of zeta potential, Fourier transform infrared (FT-IR) and Raman spectra analysis illustrated that chemical adsorption and ion exchange are the potential sorption mechanism. The static sorption test showed that the maximum sorption capacity (q_max) of MPS for Cr(Ⅵ) increased with temperature, which indicated that the Cr(Ⅵ) sorption process was endothermic. The saturated sorption capacity of Cr(Ⅵ) in the column sorption test was 138.34 mg·g^-1, which accounted for 93.9% of the q_max at 25 ℃. The regeneration capacity of MPS was evaluated using HCl solution as an eluent. The high regeneration efficiency (82.6%) validated the dominance of the ion exchange mechanism in the Cr(Ⅵ) sorption process with Cl^- ions displacing Cr(Ⅵ) oxyanion on MPS. The Langmuir isotherm model showed a higher correlation coefficient than the other adsorption isotherm models. And in the kinetic study, a pseudo-second-order model fit the data best.

Key words: modified peanut shell, amination, Cr(Ⅵ), adsorption, mechanism

岳敏, 张猛, 刘斌, 许醒, 李小明, 岳钦艳, 马春元. Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)[J]. Chinese Journal of Chemical Engineering, 2013, 21(11): 1260-1268.

YUE Min, ZHANG Meng, LIU Bin, XU Xing, LI Xiaoming, YUE Qinyan, MA Chunyuan. Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)[J]. Chin.J.Chem.Eng., 2013, 21(11): 1260-1268.

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Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)

Characteristics of Amine Surfactant Modified Peanut Shell and Its Sorption Property for Cr(Ⅵ)

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