Extraction of rubidium by t-BAMBP in cyclohexane

doi:10.1016/j.cjche.2015.04.005

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (7): 1110-1113.DOI: 10.1016/j.cjche.2015.04.005

Extraction of rubidium by t-BAMBP in cyclohexane

Jiawei Wang, Dehua Che, Wei Qin

State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

收稿日期:2014-01-08 修回日期:2014-05-13 出版日期:2015-07-28 发布日期:2015-08-21
通讯作者: Wei Qin
基金资助:
Supported by the research fund for the Doctoral Program of Education Ministry of China (20120002110098).

Extraction of rubidium by t-BAMBP in cyclohexane

Jiawei Wang, Dehua Che, Wei Qin

State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2014-01-08 Revised:2014-05-13 Online:2015-07-28 Published:2015-08-21
Contact: Wei Qin
Supported by:
Supported by the research fund for the Doctoral Program of Education Ministry of China (20120002110098).

摘要/Abstract

摘要： 4-Tert-butyl-2-(α-methylbenzyl) phenol (t-BAMBP)was used in cyclohexane in the extraction of rubidiumfrom brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied. t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0 mol·L^-1. The stoichiometry of the complex of t-BAMBP with rubidium is 4:1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data.

关键词: Solvent extraction, Selectivity, Rubidium, t-BAMBP, Cyclohexane

Abstract: 4-Tert-butyl-2-(α-methylbenzyl) phenol (t-BAMBP)was used in cyclohexane in the extraction of rubidiumfrom brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied. t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0 mol·L^-1. The stoichiometry of the complex of t-BAMBP with rubidium is 4:1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data.

Key words: Solvent extraction, Selectivity, Rubidium, t-BAMBP, Cyclohexane

Jiawei Wang, Dehua Che, Wei Qin. Extraction of rubidium by t-BAMBP in cyclohexane[J]. Chinese Journal of Chemical Engineering, 2015, 23(7): 1110-1113.

Jiawei Wang, Dehua Che, Wei Qin. Extraction of rubidium by t-BAMBP in cyclohexane[J]. Chin.J.Chem.Eng., 2015, 23(7): 1110-1113.

参考文献

[1] W.C. Butterman, R.G. Jr Reese, Mineral Commodity Profiles—Rubidium, U. S. geological survey, 06 18 2013. [http://pubs.usgs.gov/of/2003/of03-045/of03-045.pdf].

[2] F.S.Wagner, Rubidiumand Rubidium Compounds, 4th ed., Kirk-Othmer Encyclopedia of Chemical Technology, 21, Wiley & Sons, New York 1997, p. 593.

[3] L.C. Carrico, J.B. Hedrick, Rubidium, a chapter from mineral facts and problems, U.S. Bur. Min. Bull. 675 (1985) 673-678.

[4] Rare Metal Handbook Editorial Committee, Rare Metal Handbook, Metallurgical Industry Press, Beijing, 1992.

[5] K.B. Brown, Chemical Technology Division, Chemical Development Section C, Progress Report for October-December 1961 (No. ORNL-TM-107), Oak Ridge national Lab., Tenn., 1962.

[6] K.B. Brown, Chemical Technology Division, Chemical Development Section C, Progress Report for January-March 1962 (No. ORNL-TM-181), Oak Ridge national Lab., Tenn., 1962.

[7] K.B. Brown, Chemical Technology Division, Chemical Development Section C, Progress Report for April-June 1962 (No. ORNL-TM-265), Oak Ridge national Lab., Tenn., 1962.

[8] K.B. Brown, Chemical Technology Division, Chemical Development Section C, Progress Report for July-December 1962 (No. ORNL-TM-449), Oak Ridge national Lab., Tenn., 1963.

[9] K.B. Brown, Chemical Technology Division, Chemical Development Section C, Progress Report on Separations Chemistry and Separation Progress Research for January-June 1963 (No. ORNL-TM-3496), Oak Ridge national Lab., Tenn., 1963.

[10] D.E. Horner, Solvent extraction chemistry symposium. Part II. Fission product recovery from waste solutions by solvent extraction, Nucl. Sci. Eng. 17 (1963) 234-246.

[11] W.J. Ross, J.C. White, Determination of cesium and rubidium after extraction with 4-sec-butyl-2 (α-methylbenzyl) phenol, Anal. Chem. 36 (10) (1964) 1998-2000.

[12] W.D. Arnold, D.J. Crouse, K.B. Brown, Solvent extraction of cesium (and rubidium) from ore liquors with substituted phenols, Ind. Eng. Chem. Process. Des. Dev. 4 (3) (1965) 249-254.

[13] B.Z. Egan, R.A. Zingaro, B.M. Benjamin, Extraction of alkali metals by 4-sec-butyl-2-(α-methylbenzyl) phenol (BAMBP), Inorg. Chem. 4 (7) (1965) 1055-1061.

[14] B.Z. Egan,W.D. Arnold, The purity, properties, and analytical determination of 4-secbutyl-2-(α-methylbenzyl) phenol, Anal. Chem. 38 (7) (1966) 950-952.

[15] G.S. Rodionova, V.V. Alekseeva, V.V. Starostin, Influence of the structures of various phenols on the extraction of rubidium and caesium, Zh. Org. Khim. 15 (1) (1970) 176-178.

[16] J. Rais, J. Krtil, V. Chotivka, Extraction and separation of ¹³⁷Cs and ⁸⁶Rb by means of 4-t-butyl-2 (α-methylbenzyl) phenol, Talanta 18 (2) (1971) 213-218.

[17] Z.Y. Chen, F.Z. Chen, Study on reaction mechanism and thermodynamic functions of t-BAMBP extracting rubidium and cesium, Chin. J. Rare Met. 19 (5) (1995) 330-333 (in Chinese).

[18] Z.Y. Chen, Impact of concentration of extractant and diluent on the extraction of rubidium and cesium, Chin. J. Rare Met. 16 (6) (1992) 405-410 (in Chinese).

[19] J.A. Dean, Lang's Handbook of Chemistry, McGraw-Hill, New York, 1999.

[20] J.W. Roddy, C.F. Coleman, Investigation of intermolecular association of 4-sec-butyl-2-(α-methylbenzyl) phenol (BAMBP) by use of dielectric and isopiestic measurements, J. Inorg. Nucl. Chem. 35 (12) (1973) 4271-4278.

[21] P.A. Kollman, I.D. Kuntz, Hydration number of Li⁺, J. Am. Chem. Soc. 96 (15) (1974) 4766-4769.

编辑推荐 0

Metrics

阅读次数

全文

493

HTML			PDF

最新录用	在线预览	正式出版	最新录用	在线预览	正式出版
0	0	0	0	0	493

来源	本网站	其他网站

次数	75	418
比例	15%	85%

摘要

3207

最新录用	在线预览	正式出版

0	0	3207

来源	本网站	其他网站

次数	149	3058
比例	5%	95%

Extraction of rubidium by t-BAMBP in cyclohexane

Extraction of rubidium by t-BAMBP in cyclohexane

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐 0

Metrics

本文评价

[1]	Qunfeng Zhang, Bingcheng Li, Yuan Zhou, Deshuo Zhang, Chunshan Lu, Feng Feng, Jinghui Lv, Qingtao Wang, Xiaonian Li. Regulation of the selective hydrogenation performance of sulfur-doped carbon-supported palladium on chloronitrobenzene[J]. 中国化学工程学报, 2023, 58(6): 69-75.
[2]	Yunchang Fan, Chunyan Zhu, Sheli Zhang, Lei Zhang, Qiang Wang, Feng Wang. Efficient and selective extraction of sinomenine by deep eutectic solvents[J]. 中国化学工程学报, 2023, 57(5): 109-117.
[3]	Shanshan Mao, Tao Shen, Qing Zhao, Tong Han, Fan Ding, Xin Jin, Manglai Gao. Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets[J]. 中国化学工程学报, 2023, 57(5): 319-328.
[4]	Tutuk Djoko Kusworo, Monica Yulfarida, Andri Cahyo Kumoro, Dani Puji Utomo. Purification of bioethanol fermentation broth using hydrophilic PVA crosslinked PVDF-GO/TiO₂ membrane[J]. 中国化学工程学报, 2023, 55(3): 123-136.
[5]	Zhongqi Ren, Jie Wang, Hewei Zhang, Fan Zhang, Shichao Tian, Zhiyong Zhou. Adsorption of rubidium ion from aqueous solution by surface ion imprinted materials[J]. 中国化学工程学报, 2023, 54(2): 1-10.
[6]	Guolang Zhou, Xiaowei Li, Linlin Chen, Guiling Luo, Jun Gu, Jie Zhu, Jiangtao Yu, Jingzhou Yin, Yanhong Chao, Wenshuai Zhu. Construction of porous disc-like lithium manganate for rapid and selective electrochemical lithium extraction from brine[J]. 中国化学工程学报, 2023, 54(2): 316-322.
[7]	Monique Juna L. Leite, Ingrid Ramalho Marques, Mariane Carolina Proner, Pedro H.H. Araújo, Alan Ambrosi, Marco Di Luccio. Catalytically active membranes for esterification: A review[J]. 中国化学工程学报, 2023, 53(1): 142-154.
[8]	Fengfeng Gao, Jinhua Luo, Xuefeng Zhang, Xiaogang Hao, Guoqing Guan, Zhong Liu, Jun Li, Qinglong Luo. Electrodeposited iodide ions imprinted polypyrrole@bismuth oxyiodide film for an electrochemically switched renewable extractor towards iodide ions[J]. 中国化学工程学报, 2022, 49(9): 161-169.
[9]	Dengke Pang, Zhihong Zhang, Yongquan Zhou, Zhenhai Fu, Quan Li, Yongming Zhang, Guangguo Wang, Zhuanfang Jing. The process and mechanism for cesium and rubidium extraction with saponified 4-tert-butyl-2-(α-methylbenzyl) phenol[J]. 中国化学工程学报, 2022, 46(6): 31-39.
[10]	Wenjian Zhu, Xuhua Shen, Rui Ou, Manoj Murugesan, Aihua Yuan, Jianfeng Liu, Xiaocai Hu, Zhen Yang, Ming Shen, Fu Yang. Superhigh selective capture of volatile organic compounds exploiting cigarette butts-derived engineering carbonaceous adsorbent[J]. 中国化学工程学报, 2022, 46(6): 194-206.
[11]	Jipeng Dong, Fei Wang, Guanghui Chen, Shougui Wang, Cailin Ji, Fei Gao. Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture[J]. 中国化学工程学报, 2022, 46(6): 207-213.
[12]	Ding-Ming Xue, Wen-Juan Zhang, Xiao-Qin Liu, Shi-Chao Qi, Lin-Bing Sun. Fabrication of azobenzene-functionalized porous polymers for selective CO₂ capture[J]. 中国化学工程学报, 2022, 43(3): 24-30.
[13]	Bo Wu, Xing Yu, Min Huang, Liangshu Zhong, Yuhan Sun. Rh single atoms embedded in CeO₂ nanostructure boost CO₂ hydrogenation to HCOOH[J]. 中国化学工程学报, 2022, 43(3): 62-69.
[14]	Xiangzhao Hu, Junjie Sun, Wanzhen Zheng, Sixing Zheng, Yu Xie, Xiang Gao, Bin Yang, Zhongjian Li, Lecheng Lei, Yang Hou. Layered bismuth oxide/bismuth sulfide supported on carrageenan derived carbon for efficient carbon dioxide electroreduction to formate[J]. 中国化学工程学报, 2022, 43(3): 116-123.
[15]	Pengtao Guo, Miao Chang, Tongan Yan, Yuxiao Li, Dahuan Liu. A pillared-layer metal-organic framework for efficient separation of C₃H₈/C₂H₆/CH₄ in natural gas[J]. 中国化学工程学报, 2022, 42(2): 10-16.