Synthesis and characterization of poppy seed oil methyl esters

doi:10.1016/j.cjche.2016.01.007

›› 2016, Vol. 24 ›› Issue (8): 1087-1096.DOI: 10.1016/j.cjche.2016.01.007

• Energy, Resources and Environmental Technology • 上一篇下一篇

Synthesis and characterization of poppy seed oil methyl esters

Umer Rashid^1,2, Muhammad Ibrahim³, Imededdine Arbi Nehdi², Saud Ibrahim Al-Resayes², Sammi Ullah⁴, Muhammad Aamer Mehmood⁵, Saira Shahzadi⁶

1 Institute of Advanced Technology, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;
2 Chemistry Department, College of Science, King Saud University, Riyadh 1145, Saudi Arabia;
3 Department of Environmental Sciences & Engineering, Faculty of Engineering, Government College University Faisalabad, Faisalabad 38000, Pakistan;
4 Department of Chemistry, Government College University Faisalabad, Faisalabad 38000, Pakistan;
5 Department of Bioinformatics & Biotechnology, Government College University Faisalabad, Faisalabad 38000, Pakistan;
6 Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan

收稿日期:2015-08-03 修回日期:2015-11-30 出版日期:2016-08-28 发布日期:2016-09-21
通讯作者: Umer Rashid

Synthesis and characterization of poppy seed oil methyl esters

Umer Rashid^1,2, Muhammad Ibrahim³, Imededdine Arbi Nehdi², Saud Ibrahim Al-Resayes², Sammi Ullah⁴, Muhammad Aamer Mehmood⁵, Saira Shahzadi⁶

1 Institute of Advanced Technology, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;
2 Chemistry Department, College of Science, King Saud University, Riyadh 1145, Saudi Arabia;
3 Department of Environmental Sciences & Engineering, Faculty of Engineering, Government College University Faisalabad, Faisalabad 38000, Pakistan;
4 Department of Chemistry, Government College University Faisalabad, Faisalabad 38000, Pakistan;
5 Department of Bioinformatics & Biotechnology, Government College University Faisalabad, Faisalabad 38000, Pakistan;
6 Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan

Received:2015-08-03 Revised:2015-11-30 Online:2016-08-28 Published:2016-09-21

摘要/Abstract

摘要： Response surface methodology (RSM) was used to determine the optimum conditions of the methanolysis of crude poppy seed oil using NaOCH₃ as catalyst. The experiments were run according to five levels, four variable central composite rotatable design (CCRD) using RSM. The reaction variables, i.e., molar ratio of methanol/oil (3:1-9:1), catalyst concentration (0.5 wt%-1.25 wt% NaOCH₃), reaction temperature (25-65℃), and reaction time (20-90 min) were studied. We demonstrated that the molar ratio of methanol/oil, catalyst concentration, and reaction temperature were the significant parameters affecting the yield of poppy seed oil methyl esters (PSOMEs). The optimum transesterification reaction conditions, established using the RSM, which offered a 89.35% PSOME yield, were found to be 7.5:1 molar ratio of methanol/oil, 0.75% catalyst concentration, 45℃ reaction temperature, and 90 min reaction time. The proposed process provided an average biodiesel yield of more than 85%. A linear correlation was constructed between the observed and predicted values of the yield. The gas chromatography (GC) analyses have shown that PSOMEs contain linoleic-, oleic-, palmitic-, and stearic-acids as main fatty acids. The FTIR spectrum of the PSOMEs was also analyzed to confirm the completion of the transesterification reaction. The fuel properties of the PSOMEs were discussed in light of biodiesel standards (ASTM D 6751 and EN 14214).

关键词: Poppy oil, Optimization, Gas chromatography, FTIR, Fuel properties

Abstract: Response surface methodology (RSM) was used to determine the optimum conditions of the methanolysis of crude poppy seed oil using NaOCH₃ as catalyst. The experiments were run according to five levels, four variable central composite rotatable design (CCRD) using RSM. The reaction variables, i.e., molar ratio of methanol/oil (3:1-9:1), catalyst concentration (0.5 wt%-1.25 wt% NaOCH₃), reaction temperature (25-65℃), and reaction time (20-90 min) were studied. We demonstrated that the molar ratio of methanol/oil, catalyst concentration, and reaction temperature were the significant parameters affecting the yield of poppy seed oil methyl esters (PSOMEs). The optimum transesterification reaction conditions, established using the RSM, which offered a 89.35% PSOME yield, were found to be 7.5:1 molar ratio of methanol/oil, 0.75% catalyst concentration, 45℃ reaction temperature, and 90 min reaction time. The proposed process provided an average biodiesel yield of more than 85%. A linear correlation was constructed between the observed and predicted values of the yield. The gas chromatography (GC) analyses have shown that PSOMEs contain linoleic-, oleic-, palmitic-, and stearic-acids as main fatty acids. The FTIR spectrum of the PSOMEs was also analyzed to confirm the completion of the transesterification reaction. The fuel properties of the PSOMEs were discussed in light of biodiesel standards (ASTM D 6751 and EN 14214).

Key words: Poppy oil, Optimization, Gas chromatography, FTIR, Fuel properties

Umer Rashid, Muhammad Ibrahim, Imededdine Arbi Nehdi, Saud Ibrahim Al-Resayes, Sammi Ullah, Muhammad Aamer Mehmood, Saira Shahzadi. Synthesis and characterization of poppy seed oil methyl esters[J]. , 2016, 24(8): 1087-1096.

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Synthesis and characterization of poppy seed oil methyl esters

Synthesis and characterization of poppy seed oil methyl esters

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