SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (1): 130-136.DOI: 10.1016/j.cjche.2016.06.001

• Energy, Resources and Environmental Technology • 上一篇    下一篇

Modification of methyl oleate for silicon-based biological lubricating base oil

Shixing Cui, Zhi Yun, Xia Gui   

  1. College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
  • 收稿日期:2016-04-26 修回日期:2016-06-02 出版日期:2017-01-28 发布日期:2017-02-15
  • 通讯作者: Zhi Yun,E-mail address:yunzhi@njtech.edu.cn
  • 基金资助:
    Supported by the National Natural Science Foundation of China (21306088), National Key Technologies R & D Program of China (2015BAD15B07), State Key Laboratory of Chemical Engineering (SKL-ChE-13A01, Tsinghua University, China) and Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD, China).

Modification of methyl oleate for silicon-based biological lubricating base oil

Shixing Cui, Zhi Yun, Xia Gui   

  1. College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
  • Received:2016-04-26 Revised:2016-06-02 Online:2017-01-28 Published:2017-02-15
  • Supported by:
    Supported by the National Natural Science Foundation of China (21306088), National Key Technologies R & D Program of China (2015BAD15B07), State Key Laboratory of Chemical Engineering (SKL-ChE-13A01, Tsinghua University, China) and Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD, China).

摘要: A new kind of silicon-based biological lubricating base oil with good viscosity-temperature behavior, viscosity index, thermostability, oxidation stability and wear resistance performance was synthesized as a derivative of methyl oleate. Trimethylsilylation reaction was introduced to further improve methyl oleate oxidation stability and lubricity after epoxidation and open-ring reactions. The order of effectiveness of acid binding agent was N,N-diisopropylethylamine (DIEA) > pyridine > diethylamine > triethylamine, and the effects of various parameters on the trimethylsilylation reaction as well as on the silicon-oxygen bond stability and reaction yield were studied. A maximum yield of 34.54% was achieved at hydroxyl/trimethyl chlorosilane/DIEA molar ratio of 1:1.25:1, reaction temperature 40℃, reaction time 1.5 h.

关键词: Methyl oleate, Trimethyl chlorosilane, Acid binding agent, N,N-diisopropylethylamine, Lubricity, Silicon-based biological lubricating base oil

Abstract: A new kind of silicon-based biological lubricating base oil with good viscosity-temperature behavior, viscosity index, thermostability, oxidation stability and wear resistance performance was synthesized as a derivative of methyl oleate. Trimethylsilylation reaction was introduced to further improve methyl oleate oxidation stability and lubricity after epoxidation and open-ring reactions. The order of effectiveness of acid binding agent was N,N-diisopropylethylamine (DIEA) > pyridine > diethylamine > triethylamine, and the effects of various parameters on the trimethylsilylation reaction as well as on the silicon-oxygen bond stability and reaction yield were studied. A maximum yield of 34.54% was achieved at hydroxyl/trimethyl chlorosilane/DIEA molar ratio of 1:1.25:1, reaction temperature 40℃, reaction time 1.5 h.

Key words: Methyl oleate, Trimethyl chlorosilane, Acid binding agent, N,N-diisopropylethylamine, Lubricity, Silicon-based biological lubricating base oil