SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (7): 963-970.DOI: 10.1016/j.cjche.2016.06.006

• Chemical Engineering Thermodynamics • 上一篇    下一篇

Non-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 copolymers:Effect of sebacic acid as a third comonomer

Zhongqiang Wang1,2, Guosheng Hu1, Jingting Zhang1, Jiusheng Xu2, Wenbo Shi1   

  1. 1 Institute of Macromolecules and Bioengineering, School of Materials Science and Engineering, North University of China, Taiyuan 030051, China;
    2 Guangdong Sinoplast Advanced Material Co. Ltd., Dongguan 523860, China
  • 收稿日期:2016-05-31 修回日期:2016-06-19 出版日期:2017-07-28 发布日期:2017-08-17
  • 通讯作者: Guosheng Hu,E-mail address:huguosheng@nuc.edu.cn
  • 基金资助:
    Supported by the National Science and Technology Support Program of China (No. 2013BAE02B01), the Special Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2013B090500003), and the Commissioner Workstation Project of Guangdong Province (No. 2014A090906002).

Non-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 copolymers:Effect of sebacic acid as a third comonomer

Zhongqiang Wang1,2, Guosheng Hu1, Jingting Zhang1, Jiusheng Xu2, Wenbo Shi1   

  1. 1 Institute of Macromolecules and Bioengineering, School of Materials Science and Engineering, North University of China, Taiyuan 030051, China;
    2 Guangdong Sinoplast Advanced Material Co. Ltd., Dongguan 523860, China
  • Received:2016-05-31 Revised:2016-06-19 Online:2017-07-28 Published:2017-08-17
  • Supported by:
    Supported by the National Science and Technology Support Program of China (No. 2013BAE02B01), the Special Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2013B090500003), and the Commissioner Workstation Project of Guangdong Province (No. 2014A090906002).

摘要: Nylon 10T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 was investigated by means of differential scanning calorimetry (DSC). Jeziorny equation and Mo equation were applied to describe the non-isothermal crystallization kinetics of the Nylon 10T and the Nylon 10T/1010. The activation energies for non-isothermal crystallization were obtained by Vyazovkin's method and Friedman's method, respectively. These results showed that Jeziorny equation and Mo equation well described the non-isothermal crystallization kinetics of the Nylon 10T and the Nylon 10T/1010. It was found that the values of the activation energy for non-isothermal crystallization of the Nylon 10T/1010 were lower than those of the Nylon 10T at a given temperature or relative crystallinity degree, which revealed that crystallization ability of the Nylon 10T/1010 was higher. The crystal morphology was observed by means of a polarized optical microscope (POM) and X-ray diffraction (XRD). It was found that the addition of sebacic acid comonomer not only did not change the crystal form of the Nylon 10T, but also significantly increased the number and decreased the size of spherulites. Comparing with the Nylon 10T, the crystallization rate was increased with the addition of the sebacic acid comonomer.

关键词: Melt polymerization, Nylon 10T, Nylon 10T/1010, Semiaromatic polyamides, Crystallization kinetics, Non-isothermal crystallization

Abstract: Nylon 10T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 was investigated by means of differential scanning calorimetry (DSC). Jeziorny equation and Mo equation were applied to describe the non-isothermal crystallization kinetics of the Nylon 10T and the Nylon 10T/1010. The activation energies for non-isothermal crystallization were obtained by Vyazovkin's method and Friedman's method, respectively. These results showed that Jeziorny equation and Mo equation well described the non-isothermal crystallization kinetics of the Nylon 10T and the Nylon 10T/1010. It was found that the values of the activation energy for non-isothermal crystallization of the Nylon 10T/1010 were lower than those of the Nylon 10T at a given temperature or relative crystallinity degree, which revealed that crystallization ability of the Nylon 10T/1010 was higher. The crystal morphology was observed by means of a polarized optical microscope (POM) and X-ray diffraction (XRD). It was found that the addition of sebacic acid comonomer not only did not change the crystal form of the Nylon 10T, but also significantly increased the number and decreased the size of spherulites. Comparing with the Nylon 10T, the crystallization rate was increased with the addition of the sebacic acid comonomer.

Key words: Melt polymerization, Nylon 10T, Nylon 10T/1010, Semiaromatic polyamides, Crystallization kinetics, Non-isothermal crystallization