SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (1): 109-115.DOI: 10.1016/j.cjche.2017.02.007

• Catalysis, kinetics and reaction engineering • 上一篇    下一篇

Rh2O3/monoclinic CePO4 composite catalysts for N2O decomposition and CO oxidation

Huan Liu, Zhen Ma   

  1. Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
  • 收稿日期:2017-01-06 修回日期:2017-02-05 出版日期:2018-01-28 发布日期:2018-03-01
  • 通讯作者: Zhen Ma,E-mail address:zhenma@fudan.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21177028, 21477022).

Rh2O3/monoclinic CePO4 composite catalysts for N2O decomposition and CO oxidation

Huan Liu, Zhen Ma   

  1. Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
  • Received:2017-01-06 Revised:2017-02-05 Online:2018-01-28 Published:2018-03-01
  • Contact: Zhen Ma,E-mail address:zhenma@fudan.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China (21177028, 21477022).

摘要: CePO4 (in particular, monoclinic CePO4) has been rarely used to make supported catalysts. Herein, monoclinic CePO4 nanoparticles were prepared by calcining hexagonal CePO4 nanorods (prepared by precipitation) in air at 900℃. Monoclinic CePO4 nanowires were prepared by calcining hexagonal CePO4 nanowires (prepared by hydrothermal synthesis at 150℃) in air at 900℃. Both monoclinic CePO4 materials were used to support Rh2O3 by impregnation using Rh(NO3)3 as a precursor (followed by calcination). The catalytic performance of Rh2O3/monoclinic CePO4 composite materials in N2O decomposition and CO oxidation was investigated. It was found that Rh2O3 supported on monoclinic CePO4 nanowires was much more active than Rh2O3 supported on monoclinic CePO4 nanoparticles. The stability of catalysts as a function of reaction time on stream was studied in both reactions. The influence of co-fed CO2, O2, and H2O on the catalytic activity in N2O decomposition was also studied. These catalysts were characterized by employing N2 adsorption-desorption, ICP-OES, XRD, TEM, XPS, H2-TPR, O2-TPD, and CO2-TPD. The correlation between physicochemical properties and catalytic properties was discussed.

关键词: Rh2O3, CePO4, N2O decomposition, CO oxidation, Catalyst

Abstract: CePO4 (in particular, monoclinic CePO4) has been rarely used to make supported catalysts. Herein, monoclinic CePO4 nanoparticles were prepared by calcining hexagonal CePO4 nanorods (prepared by precipitation) in air at 900℃. Monoclinic CePO4 nanowires were prepared by calcining hexagonal CePO4 nanowires (prepared by hydrothermal synthesis at 150℃) in air at 900℃. Both monoclinic CePO4 materials were used to support Rh2O3 by impregnation using Rh(NO3)3 as a precursor (followed by calcination). The catalytic performance of Rh2O3/monoclinic CePO4 composite materials in N2O decomposition and CO oxidation was investigated. It was found that Rh2O3 supported on monoclinic CePO4 nanowires was much more active than Rh2O3 supported on monoclinic CePO4 nanoparticles. The stability of catalysts as a function of reaction time on stream was studied in both reactions. The influence of co-fed CO2, O2, and H2O on the catalytic activity in N2O decomposition was also studied. These catalysts were characterized by employing N2 adsorption-desorption, ICP-OES, XRD, TEM, XPS, H2-TPR, O2-TPD, and CO2-TPD. The correlation between physicochemical properties and catalytic properties was discussed.

Key words: Rh2O3, CePO4, N2O decomposition, CO oxidation, Catalyst