SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (2): 278-292.DOI: 10.1016/j.cjche.2017.05.010

• Separation Science and Engineering • 上一篇    下一篇

Transport hindrances with electrodialytic recovery of citric acid from solution of strong electrolytes

Anusha Chandra1, Jogi Ganesh Dattatreya Tadimeti2, Sujay Chattopadhyay1   

  1. 1 Department of Polymer and Process Engineering, ⅡT Roorkee Saharanpur Campus, Saharanpur 247001, India;
    2 Department of Mechanical Engineering, Swarnandhra College of Engineering and Technology, Seetarampuram 534280, India
  • 收稿日期:2017-03-06 修回日期:2017-05-24 出版日期:2018-02-28 发布日期:2018-03-16
  • 通讯作者: Sujay Chattopadhyay

Transport hindrances with electrodialytic recovery of citric acid from solution of strong electrolytes

Anusha Chandra1, Jogi Ganesh Dattatreya Tadimeti2, Sujay Chattopadhyay1   

  1. 1 Department of Polymer and Process Engineering, ⅡT Roorkee Saharanpur Campus, Saharanpur 247001, India;
    2 Department of Mechanical Engineering, Swarnandhra College of Engineering and Technology, Seetarampuram 534280, India
  • Received:2017-03-06 Revised:2017-05-24 Online:2018-02-28 Published:2018-03-16
  • Contact: Sujay Chattopadhyay

摘要: Electrodialytic (ED) recovery of citric acid (CA) in the presence/absence of strong electrolytes (NaCl, CaCl2 and FeCl3) was separately analyzed under different process conditions. Recovery effectiveness was quantitatively estimated from current efficiency values. Efficiency attained optimum value with both flow rate and potential applied, while a monotonic rise was noted with temperature which got lowered beyond 0.1 mol·L-1 feed concentration. 40% drop in efficiency was recorded in the presence of strong electrolytes (NaCl, CaCl2 and FeCl3) in feed relative to their presence in concentrate. Severe transport hindrance and efficiency loss were attributed to adsorption and allied physicochemical changes occurred with anion/cation exchange membranes (AEM/CEM) and these were confirmed through contact angle/Chronopotentiometry/AFM/EDX. Sluggish potential rise (Galvanostatic mode) in Chronopotentiometric analysis indicated diffusion limiting transport of organic acids influenced AEM resistance. XRD and EDX analysis indicated the presence of salt hydrates/ions (Ca2+/Fe3+) over CEM justifying the resistance buildup due to adsorption of multivalent metal ion(s) and salts.

关键词: Electrodialysis, Adsorption, Electrolytes, Recovery, Chronopotentiometry, AFM

Abstract: Electrodialytic (ED) recovery of citric acid (CA) in the presence/absence of strong electrolytes (NaCl, CaCl2 and FeCl3) was separately analyzed under different process conditions. Recovery effectiveness was quantitatively estimated from current efficiency values. Efficiency attained optimum value with both flow rate and potential applied, while a monotonic rise was noted with temperature which got lowered beyond 0.1 mol·L-1 feed concentration. 40% drop in efficiency was recorded in the presence of strong electrolytes (NaCl, CaCl2 and FeCl3) in feed relative to their presence in concentrate. Severe transport hindrance and efficiency loss were attributed to adsorption and allied physicochemical changes occurred with anion/cation exchange membranes (AEM/CEM) and these were confirmed through contact angle/Chronopotentiometry/AFM/EDX. Sluggish potential rise (Galvanostatic mode) in Chronopotentiometric analysis indicated diffusion limiting transport of organic acids influenced AEM resistance. XRD and EDX analysis indicated the presence of salt hydrates/ions (Ca2+/Fe3+) over CEM justifying the resistance buildup due to adsorption of multivalent metal ion(s) and salts.

Key words: Electrodialysis, Adsorption, Electrolytes, Recovery, Chronopotentiometry, AFM