A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane

doi:10.1016/j.cjche.2017.10.023

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (4): 786-794.DOI: 10.1016/j.cjche.2017.10.023

• Process Systems Engineering and Process Safety • 上一篇下一篇

A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane

Xian Chen¹, Yunpeng Li¹, Ge Xu¹, Jihai Tang^1,2, Zhuxiu Zhang¹, Ming Chen¹, Zhaoyang Fei¹, Mifen Cui¹, Xu Qiao^1,2

1 State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing 210009, China

收稿日期:2017-06-07 修回日期:2017-10-24 出版日期:2018-04-28 发布日期:2018-05-19
通讯作者: Jihai Tang,E-mail addresses:jhtang@njtech.edu.cn;Xu Qiao,E-mail addresses:qct@njtech.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21276126, 61203020); Prospective Joint Research Project of Jiangsu Province (BY2014005-02, BY2015005-02); The Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane

Xian Chen¹, Yunpeng Li¹, Ge Xu¹, Jihai Tang^1,2, Zhuxiu Zhang¹, Ming Chen¹, Zhaoyang Fei¹, Mifen Cui¹, Xu Qiao^1,2

1 State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing 210009, China

Received:2017-06-07 Revised:2017-10-24 Online:2018-04-28 Published:2018-05-19
Contact: Jihai Tang,E-mail addresses:jhtang@njtech.edu.cn;Xu Qiao,E-mail addresses:qct@njtech.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (21276126, 61203020); Prospective Joint Research Project of Jiangsu Province (BY2014005-02, BY2015005-02); The Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要/Abstract

摘要： In this paper, we developed a novel process integrating vacuum distillation with atmospheric chlorination reaction (VD-ACR) to realize the flexible production of tetrachloroethane (TeCA) and pentachloroethane (PCA) from 1,2-dichloroethane (DCA). During the simulation, the distillation column and reactors were operated for separation and chlorination respectively under variable pressures and temperatures. It is interesting to note that VD-ACR processes producing pure TeCA or PCA can exhibit the similar configuration parameters after optimization, which enables the flexible production of TeCA and PCA with different molar ratios via changing operating parameters. The molar ratio of TeCA/PCA can be fine-tuned within the range of 0.9:0.1-0.1:0.9 through adjusting the amount of chlorine pumped into side reactors, giving rise to the increase of the heat duty of reboiler by five times. A pilot-scale experiment was then operated based-upon this VD-ACR process and the result matched well with the simulation. Therefore, the VD-ACR model presented in this study will be beneficial for the industrial-scale flexible production of TeCA and PCA from DCA.

关键词: Vacuum distillation, Atmospheric chlorination, Flexible production, Tetrachloroethane, Pentachloroethane, Pilot-scale

Abstract: In this paper, we developed a novel process integrating vacuum distillation with atmospheric chlorination reaction (VD-ACR) to realize the flexible production of tetrachloroethane (TeCA) and pentachloroethane (PCA) from 1,2-dichloroethane (DCA). During the simulation, the distillation column and reactors were operated for separation and chlorination respectively under variable pressures and temperatures. It is interesting to note that VD-ACR processes producing pure TeCA or PCA can exhibit the similar configuration parameters after optimization, which enables the flexible production of TeCA and PCA with different molar ratios via changing operating parameters. The molar ratio of TeCA/PCA can be fine-tuned within the range of 0.9:0.1-0.1:0.9 through adjusting the amount of chlorine pumped into side reactors, giving rise to the increase of the heat duty of reboiler by five times. A pilot-scale experiment was then operated based-upon this VD-ACR process and the result matched well with the simulation. Therefore, the VD-ACR model presented in this study will be beneficial for the industrial-scale flexible production of TeCA and PCA from DCA.

Key words: Vacuum distillation, Atmospheric chlorination, Flexible production, Tetrachloroethane, Pentachloroethane, Pilot-scale

Xian Chen, Yunpeng Li, Ge Xu, Jihai Tang, Zhuxiu Zhang, Ming Chen, Zhaoyang Fei, Mifen Cui, Xu Qiao. A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 786-794.

参考文献

[1] M.F. Malone, R.S. Huss, M.F. Doherty, Green chemical engineering aspects of reactive distillation, Environ. Sci. Technol. 37(2003) 5325-5329.

[2] J.L. DeGarmo, V.N. Parulekar, V. Pinjala, Consider reactive distillation, Chem. Eng. Prog. 88(1992) 43-50.

[3] J.J. Siirola, Industrial applications of chemical process synthesis, Adv. Chem. Eng. 23(1996) 1-62.

[4] D.B. Kaymak, W.L. Luyben, Quantitative comparison of reactive distillation with conventional multiunit reactor/column/recycle systems for different chemical equilibrium constants, Ind. Eng. Chem. Res. 43(2004) 2493-2507.

[5] H. Tian, S.Y. Zhao, H.D. Zheng, Z.X. Huang, Optimization of coproduction of ethyl acetate and n-butyl acetate by reactive distillation, Chin. J. Chem. Eng. 23(2015) 667-674.

[6] C.L. Cheng, Y.H. Chung, H.Y. Lee, Design and control of reactive distillation process for the production of methyl valerate, Ind. Eng. Chem. Res. 55(2016) 1347-1360.

[7] U. Sahapatsombud, A. Arpornwichanop, S. Assabumrungrat, Simulation studies on reactive distillation for synthesis of tert-amyl ethyl ether, Korean J. Chem. Eng. 22(2005) 387-392.

[8] S.J. Wang, S.H. Cheng, P.H. Chiu, Design and control of a thermally coupled reactive distillation process synthesizing diethyl carbonate, Ind. Eng. Chem. Res. 53(2014) 5982-5995.

[9] Z. Lei, C. Dai, Y. Wang, Process optimization on alkylation of benzene with propylene, Energy Fuel 23(2009) 3159-3166.

[10] D.B. Kaymak, W.L. Luyben, O.J. Smith, Effect of relative volatility on the quantitative comparison of reactive distillation and conventional multi-unit systems, Ind. Eng. Chem. Res. 43(2004) 3151-3162.

[11] D.B. Kaymak, W.L. Luyben, Optimum design of a column/side reactor process, Ind. Eng. Chem. Res. 46(2007) 5175-5185.

[12] R. Knishna, Reactive separations:more ways to skin a cat, Chem. Eng. Sci. 57(2002) 1491-1504.

[13] C. Noeres, E.Y. Kenid, A. Gorak, Modeling of reactive separation process:reactive absorption and reactive distillation, Chem. Eng. Process. 42(2003) 157-178.

[14] R. Thery, X.M. Meyer, X. Joulia, Analysis of the feasibility synthesis and conception of processes of reactive distillation:state of the art and critical analysis, Can. J. Chem. Eng. 83(2005) 242-266.

[15] S.B. Gadewar, L. Tao, M.F. Malone, Process alternatives for coupling reaction and distillation, Chem. Eng. Res. Des. 82(2004) 140-147.

[16] J. Ye, J. Li, Y. Sha, Evaluation of reactive distillation and side reactor configuration for direct hydration of cyclohexene to cyclohexanol, Ind. Eng. Chem. Res. 53(2014) 1461-1469.

[17] L.H. Ding, J.H. Tang, M.F. Cui, X. Chen, C.M. Bo, X. Qiao, Optimum design of coupled atmospheric reaction-vaccum distillation technology for benzyl chloride production, CIESC J. 62(2011) 2323-2327(in Chinese).

[18] C.M. Bo, J.H. Tang, Y.J. Bo, X. Qiao, L.H. Ding, S. Zhang, The design and control of distillation column with side reactors for chlorobenzene production, Chin. J. Chem. Eng. 20(2012) 1113-1120.

[19] T. Ouni, K. Jakobsson, A. Pyhalathi, Enhancing productivity of side reactor configuration through optimizing the reaction conditions, Chem. Eng. Res. Des. 82(2004) 167-174.

[20] Y. Correia, J.C. Stini, Process for Obtaining 1,1,1,2-tetrachloroethane, USA, 1975235777.

[21] H.J. Boonman, V. Hagspiel, P.M. Kort, Dedicated vs product flexible production technology:strategic capacity investment choice, Eur. J. Oper. Res. 244(2015) 141-152.

[22] W. Chen, Study on Reaction Kinetics and Reactive Distillation of Consecutive MultiStep Photo-Chlorination of Dichloroethane, M. S. Thesis Nanjing Tech Univ., Nanjing 2014(in Chinese).

[23] Z.X. Huang, J.L. Li, L.Y. Wang, H.M. Jiang, T. Qiu, Novel procedure for the synthesis of dimethyl carbonate by reactive distillation, Ind. Eng. Chem. Res. 53(2014) 3321-3328.

[24] M.G. Sneesby, M.O. Tade, R. Datta, T.N. Smith, ETBE synthesis via reactive distillation. 1. Steady-state simulation and design aspects, Ind. Eng. Chem. Res. 36(1997) 1855-1869.

A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane

A novel process integrating vacuum distillation with atmospheric chlorination reaction for flexible production of tetrachloroethane and pentachloroethane

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