SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (7): 1630-1641.DOI: 10.1016/j.cjche.2018.11.001

• Catalysis, Kinetics and Reaction Engineering • 上一篇    下一篇

Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO2 nano material under visible light irradiation

K. V. Divya Lakshmi, T. Siva Rao, J. Swathi Padmaja, I. Manga Raju, M. Ravi Kumar   

  1. Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam 530003, India
  • 收稿日期:2018-06-13 出版日期:2019-07-28 发布日期:2019-10-14
  • 通讯作者: T. Siva Rao

Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO2 nano material under visible light irradiation

K. V. Divya Lakshmi, T. Siva Rao, J. Swathi Padmaja, I. Manga Raju, M. Ravi Kumar   

  1. Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam 530003, India
  • Received:2018-06-13 Online:2019-07-28 Published:2019-10-14
  • Contact: T. Siva Rao

摘要: Undoped and Ni-S co-doped mesoporous TiO2 nano materials were synthesized by using sol-gel method. The characteristic features of as prepared catalyst samples were investigated using various advanced spectroscopic and analytical techniques. The characterization results of the samples revealed that all the samples exhibited anatase phase (XRD), decreasing band gap (2.68 eV) (UV-Vis-DRS), small particle size (9.2 nm) (TEM), high surface area (142.156 m2·g-1) (BET), particles with spherical shape and smooth morphology (SEM); there is a frequency shift observed for co-doped sample (FT-IR) and the elemental composition electronic states and position of the doped elements (Ni and S) in the TiO2 lattice analyzed by XPS and EDX. These results supported the photocatalytic degradation of Bismarck Brown Red (BBR) achieved with in 110 min and also exhibited the antibacterial activity on Staphylococcus aureus (MTCC-3160), Pseudomonas fluorescence (MTCC-1688) under visible light irradiation.

关键词: Sol-gel, Ni-S co-doped TiO2, Photocatalysis under visible light, Degradation of Bismarck Brown Red, Antibacterial activity

Abstract: Undoped and Ni-S co-doped mesoporous TiO2 nano materials were synthesized by using sol-gel method. The characteristic features of as prepared catalyst samples were investigated using various advanced spectroscopic and analytical techniques. The characterization results of the samples revealed that all the samples exhibited anatase phase (XRD), decreasing band gap (2.68 eV) (UV-Vis-DRS), small particle size (9.2 nm) (TEM), high surface area (142.156 m2·g-1) (BET), particles with spherical shape and smooth morphology (SEM); there is a frequency shift observed for co-doped sample (FT-IR) and the elemental composition electronic states and position of the doped elements (Ni and S) in the TiO2 lattice analyzed by XPS and EDX. These results supported the photocatalytic degradation of Bismarck Brown Red (BBR) achieved with in 110 min and also exhibited the antibacterial activity on Staphylococcus aureus (MTCC-3160), Pseudomonas fluorescence (MTCC-1688) under visible light irradiation.

Key words: Sol-gel, Ni-S co-doped TiO2, Photocatalysis under visible light, Degradation of Bismarck Brown Red, Antibacterial activity