Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin

doi:10.1016/j.cjche.2019.02.021

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (10): 2544-2550.DOI: 10.1016/j.cjche.2019.02.021

• Energy, Resources and Environmental Technology • 上一篇下一篇

Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin

Nawei Chen, Guo Qiu, Chongpin Huang, Li Liu, Guangchao Li, Biaohua Chen

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

收稿日期:2018-11-30 修回日期:2019-02-21 出版日期:2019-10-28 发布日期:2020-01-17
通讯作者: Chongpin Huang
基金资助:
Supported by the National Natural Science Foundation of China (21476021).

Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin

Nawei Chen, Guo Qiu, Chongpin Huang, Li Liu, Guangchao Li, Biaohua Chen

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2018-11-30 Revised:2019-02-21 Online:2019-10-28 Published:2020-01-17
Contact: Chongpin Huang
Supported by:
Supported by the National Natural Science Foundation of China (21476021).

摘要/Abstract

摘要： The adsorption of Cr(VI) from soil onto lignin-based weakly acidic cation exchange resin (LBR) has been investigated. Lignin is a three-dimensional amorphous polymer composed of methoxylated phenylpropane units. The unique structure and chemical properties render the lignin suitable for the remediation of hexavalent chromium in the soil. Soil column leaching experiments were conducted to optimize the adsorption conditions. The effects of contact time, pH, adsorbent dosage and temperature on the adsorption of Cr(VI) onto the LBR have been investigated. Experiment data were then correlated with Freundlich and Langmuir isotherms. The Langmuir isotherm model fits the experimental data better than the Freundlich isotherm. It was found that the LBR has a high adsorption capability for Cr(VI) (3.95 mg·g^-1) with a removal rate of 91.9%. Thus, LBR can serve as a good absorbent for the reduction of the concentration of Cr(VI) in soil.

Abstract: The adsorption of Cr(VI) from soil onto lignin-based weakly acidic cation exchange resin (LBR) has been investigated. Lignin is a three-dimensional amorphous polymer composed of methoxylated phenylpropane units. The unique structure and chemical properties render the lignin suitable for the remediation of hexavalent chromium in the soil. Soil column leaching experiments were conducted to optimize the adsorption conditions. The effects of contact time, pH, adsorbent dosage and temperature on the adsorption of Cr(VI) onto the LBR have been investigated. Experiment data were then correlated with Freundlich and Langmuir isotherms. The Langmuir isotherm model fits the experimental data better than the Freundlich isotherm. It was found that the LBR has a high adsorption capability for Cr(VI) (3.95 mg·g^-1) with a removal rate of 91.9%. Thus, LBR can serve as a good absorbent for the reduction of the concentration of Cr(VI) in soil.

Nawei Chen, Guo Qiu, Chongpin Huang, Li Liu, Guangchao Li, Biaohua Chen. Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin[J]. 中国化学工程学报, 2019, 27(10): 2544-2550.

Nawei Chen, Guo Qiu, Chongpin Huang, Li Liu, Guangchao Li, Biaohua Chen. Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin[J]. Chinese Journal of Chemical Engineering, 2019, 27(10): 2544-2550.

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Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin

Removal of hexavalent chromium in soil by lignin-based weakly acidic cation exchange resin

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