SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (2): 548-555.DOI: 10.1016/j.cjche.2019.07.014

• Energy, Resources and Environmental Technology • 上一篇    下一篇

Mild oxidative degradation of spent auricularia auricular substrate and molecular composition of carboxylic acids in the resulting soluble portion

Xiaoli Xue1,2, Zhimin Zong1, Guanghui Liu1, Xianyong Wei1,3   

  1. 1 Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou 221116, China;
    2 Key Laboratory of Changbai Mountain Animal and Plant Resource Utilization and Protection of Universities in Jilin Province, Jilin Agricultural Science and Technology University, Jilin 132101, China;
    3 State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China
  • 收稿日期:2019-03-07 修回日期:2019-07-21 出版日期:2020-02-28 发布日期:2020-05-21
  • 通讯作者: Zhimin Zong
  • 基金资助:
    This work was supported by the Seed Fund from Jilin Agricultural Science and Technology University ([2016] No.Z02) and Undergraduate Scientific and Technical innovation of Jilin Province (Grant [2016] No. 030).

Mild oxidative degradation of spent auricularia auricular substrate and molecular composition of carboxylic acids in the resulting soluble portion

Xiaoli Xue1,2, Zhimin Zong1, Guanghui Liu1, Xianyong Wei1,3   

  1. 1 Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou 221116, China;
    2 Key Laboratory of Changbai Mountain Animal and Plant Resource Utilization and Protection of Universities in Jilin Province, Jilin Agricultural Science and Technology University, Jilin 132101, China;
    3 State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China
  • Received:2019-03-07 Revised:2019-07-21 Online:2020-02-28 Published:2020-05-21
  • Contact: Zhimin Zong
  • Supported by:
    This work was supported by the Seed Fund from Jilin Agricultural Science and Technology University ([2016] No.Z02) and Undergraduate Scientific and Technical innovation of Jilin Province (Grant [2016] No. 030).

摘要: Spent auricularia auricular substrate (SAAS) was oxidatively degraded with aqueous hydrogen peroxide (AHPO)/ acetic anhydride (AAH) to produce carboxylic acids (CAs) under mild conditions. The results show that up to 53.6% of the organic matter in SAAS was converted to the soluble species (SSs). In total 122 CAs were detected in the SSs by the analysis with a gas chromatograph/mass spectrometer, which can be classified into 29 group components, mainly being aliphatic acids and along with small amount of aromatic acids. Among the aliphatic acids, normal alkanedioic acids are the most abundant. The detected aromatic acids include benzoic acids, phthalic acids, trimellitic acids, pyromellitic acids, and their derivatives. The synergistic oxidation and the released ·OH, CH3COO·, and HOO· induced by AHPO/AAH play crucial roles in oxidatively degrading SAAS.

关键词: Spent auricularia auricular substrate, Mild oxidation, Aliphatic acids, Aromatic acids

Abstract: Spent auricularia auricular substrate (SAAS) was oxidatively degraded with aqueous hydrogen peroxide (AHPO)/ acetic anhydride (AAH) to produce carboxylic acids (CAs) under mild conditions. The results show that up to 53.6% of the organic matter in SAAS was converted to the soluble species (SSs). In total 122 CAs were detected in the SSs by the analysis with a gas chromatograph/mass spectrometer, which can be classified into 29 group components, mainly being aliphatic acids and along with small amount of aromatic acids. Among the aliphatic acids, normal alkanedioic acids are the most abundant. The detected aromatic acids include benzoic acids, phthalic acids, trimellitic acids, pyromellitic acids, and their derivatives. The synergistic oxidation and the released ·OH, CH3COO·, and HOO· induced by AHPO/AAH play crucial roles in oxidatively degrading SAAS.

Key words: Spent auricularia auricular substrate, Mild oxidation, Aliphatic acids, Aromatic acids