Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell

doi:10.1016/j.cjche.2020.02.031

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (6): 1591-1602.DOI: 10.1016/j.cjche.2020.02.031

• Separation Science and Engineering • 上一篇下一篇

Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell

Atefeh Moosavi¹, Ali Akbar Amooey², Ali Alinejad mir², Mojtaba Hedayati Marzbali³

1 Faculty of Chemistry, University of Mazandaran, Babolsar, Iran;
2 Department of Chemical Engineering, University of Mazandaran, Babolsar, Iran;
3 Chemical & Environmental Engineering, School of Engineering, RMIT University, Melbourne, Victoria 3000, Australia

收稿日期:2019-09-10 修回日期:2020-02-09 出版日期:2020-06-28 发布日期:2020-07-29
通讯作者: Ali Akbar Amooey

Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell

Atefeh Moosavi¹, Ali Akbar Amooey², Ali Alinejad mir², Mojtaba Hedayati Marzbali³

1 Faculty of Chemistry, University of Mazandaran, Babolsar, Iran;
2 Department of Chemical Engineering, University of Mazandaran, Babolsar, Iran;
3 Chemical & Environmental Engineering, School of Engineering, RMIT University, Melbourne, Victoria 3000, Australia

Received:2019-09-10 Revised:2020-02-09 Online:2020-06-28 Published:2020-07-29
Contact: Ali Akbar Amooey

摘要/Abstract

摘要： Removal of dyestuffs such as Acidic Fuchsine (AF) and Malachite Green (MG) being present in many forms in industries is vital to protect water reservoirs from their catastrophic effects on the ecosystem. This study attempts to effectively eliminate these dyes using a low-cost and eco-friendly material. Eggshell, as a biocompatible by-product, was initially characterized, then some modifications were conducted, and its morphology and chemical structure were then examined through (Atomic force microscopy) AFM, (Fourier-Transform Infrared Spectroscopy) FTIR, (Energy-Dispersive X-ray Spectroscopy) EDS and (Brunauer-Emmett-Teller) BET analyses. They revealed that the modifications on raw material gave rise to a natural nano-adsorbent presenting porous medium appropriate for targeted adsorbate molecules with the average particle size and average pore diameter of 54 and ~2 nm, respectively. Functional groups on the adsorbent surface were also of importance to assist the adsorption of AF and MG. The effect of contact time, adsorbent dose, solution pH and initial concentration was evaluated. Pseudo-second order model accurately correlated the experimental kinetic data for both dyes. Moreover, the participation of intra-particle diffusion along with film diffusion in controlling the process was suggested. Langmuir isotherm model fitted very well to the equilibrium data for both dyes and maximum monolayer adsorption capacity of AF and MG was accordingly calculated to be 5000 and 3333.33mg·g^-1 respectively. The inherent characteristics of eggshell make it a potential material to remove contaminants from wastewater in future applications.

关键词: Egg shell, Acidic Fuchsine, Malachite Green, Ultrahigh adsorption

Abstract: Removal of dyestuffs such as Acidic Fuchsine (AF) and Malachite Green (MG) being present in many forms in industries is vital to protect water reservoirs from their catastrophic effects on the ecosystem. This study attempts to effectively eliminate these dyes using a low-cost and eco-friendly material. Eggshell, as a biocompatible by-product, was initially characterized, then some modifications were conducted, and its morphology and chemical structure were then examined through (Atomic force microscopy) AFM, (Fourier-Transform Infrared Spectroscopy) FTIR, (Energy-Dispersive X-ray Spectroscopy) EDS and (Brunauer-Emmett-Teller) BET analyses. They revealed that the modifications on raw material gave rise to a natural nano-adsorbent presenting porous medium appropriate for targeted adsorbate molecules with the average particle size and average pore diameter of 54 and ~2 nm, respectively. Functional groups on the adsorbent surface were also of importance to assist the adsorption of AF and MG. The effect of contact time, adsorbent dose, solution pH and initial concentration was evaluated. Pseudo-second order model accurately correlated the experimental kinetic data for both dyes. Moreover, the participation of intra-particle diffusion along with film diffusion in controlling the process was suggested. Langmuir isotherm model fitted very well to the equilibrium data for both dyes and maximum monolayer adsorption capacity of AF and MG was accordingly calculated to be 5000 and 3333.33mg·g^-1 respectively. The inherent characteristics of eggshell make it a potential material to remove contaminants from wastewater in future applications.

Key words: Egg shell, Acidic Fuchsine, Malachite Green, Ultrahigh adsorption

Atefeh Moosavi, Ali Akbar Amooey, Ali Alinejad mir, Mojtaba Hedayati Marzbali. Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell[J]. 中国化学工程学报, 2020, 28(6): 1591-1602.

参考文献

[1] N.P. Raval, P.U. Shah, N.K. Shah, Malachite green "a cationic dye" and its removal from aqueous solution by adsorption, Appl Water Sci 7(2017) 3407-3445.
[2] A.A. Mir, A.A. Amooey, S. Ghasemi, Adsorption of direct yellow 12 from aqueous solutions by an iron oxide-gelatin nanoadsorbent; kinetic, isotherm and mechanism analysis, J. Clean. Prod. 170(2018) 570-580.
[3] R. Saravanan, E. Sacari, F. Gracia, M.M. Khan, E. Mosquera, V.K. Gupta, Conducting PANI stimulated ZnO system for visible light photocatalytic degradation of coloured dyes, J. Mol. Liq. 221(2016) 1029-1033.
[4] A. Khaled, A. El Nemr, A. El-Sikaily, O. Abdelwahab, Treatment of artificial textile dye effluent containing Direct Yellow 12 by orange peel carbon, Desalination 238(2009) 210-232.
[5] L. Saikia, D. Bhuyan, M. Saikia, B. Malakar, D.K. Dutta, P. Sengupta, Photocatalytic performance of ZnO nanomaterials for self-sensitized degradation of malachite green dye under solar light, Appl. Catal. A Gen. 490(2015) 42-49.
[6] A. Gupta, D.V. Nandanwar, S.R. Dhakate, Electrospun self-assembled ZnO nanofibers structures for photocatalytic activity in natural solar radiations to degrade acid fuchsin dye, Adv. Mater. Lett. 6(2015) 706-710.
[7] X.J. Zhou, W.Q. Guo, S.S. Yang, H.S. Zheng, N.Q. Ren, Ultrasonic-assisted ozone oxidation process of triphenylmethane dye degradation:Evidence for the promotion effects of ultrasonic on malachite green decolorization and degradation mechanism, Bioresour. Technol. 128(2013) 827-830.
[8] G.W. Abou-el-souod, M.M. El-sheekh, biodegradation of basic fuchsin and methyl red by the blue green algae hydrocoleum oligotrichum and Oscillatoria limnetica, 15(2016) 279-286.
[9] A. Taamallah, S. Merouani, O. Hamdaoui, Sonochemical degradation of basic fuchsin in water, Desalin. Water Treat. 57(2016) 27314-27330.
[10] M.H. Marzbali, A.A. Mir, M. Pazoki, R. Pourjamshidian, M. Tabeshnia, Removal of direct yellow 12 from aqueous solution by adsorption onto spirulina algae as a highefficiency adsorbent, J. Environ. Chem. Eng 5(2017) 1946-1956.
[11] V.K. Gupta, A. Mittal, V. Gajbe, J. Mittal, Adsorption of basic fuchsin using waste materials-bottom ash and deoiled soya-as adsorbents, J. Colloid Interface Sci. 319(2008) 30-39.
[12] S. Chowdhury, R. Mishra, P. Saha, P. Kushwaha, Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk, Desalination 265(2011) 159-168.
[13] S.-H. Huo, X.-P. Yan, Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution, J. Mater. Chem. 22(2012) 7449.
[14] Y. Zhou, X. Hu, M. Zhang, X. Zhuo, J. Niu, Preparation and characterization of modified cellulose for adsorption of Cd (II), Hg (II), and acid fuchsin from aqueous solutions, Ind. Eng. Chem. Res. 52(2013) 876-884.
[15] K.Z. Elwakeel, A.M. Yousif, Adsorption of malathion on thermally treated egg shell material, Water Sci. Technol. 61(2010) 1035-1041.
[16] S.E. Kuh, D.S. Kim, Removal characteristics of cadmium ion by waste egg shell, Environ. Technol. (United Kingdom) 21(2000) 883-890.
[17] M. Gaonkar, A.P. Chakraborty, Application of eggshell as fertilizer and calcium supplement tablet, Int. J. Innov. Res. Sci. Eng. Technol. 5(3) (2016) 3520-3525.
[18] R. Mohammadi, M.A. Mohammadifar, A.M. Mortazavian, M. Rouhi, J.B. Ghasemi, Z. Delshadian, Extraction optimization of pepsin-soluble collagen from eggshell membrane by response surface methodology (RSM), Food Chem. 190(2016) 186-193.
[19] C. Arunlertaree, W. Kaewsomboon, A. Kumsopa, P. Pokethitiyook, P. Panyawathanakit, Removal of lead from battery manufacturing wastewater by egg shell, Songklanakarin J. Sci. Technol. 29(2007) 857-868.
[20] W.T. Tsai, J.M. Yang, C.W. Lai, Y.H. Cheng, C.C. Lin, C.W. Yeh, Characterization and adsorption properties of eggshells and eggshell membrane, Bioresour. Technol. 97(2006) 488-493.
[21] G. Busca, C. Resini, Vibrational Spectroscopy for the Analysis of Geological and Inorganic Materials, John Wiley & Sons, New Jersoy, 2006.
[22] B. Koumanova, P. Peeva, S.J. Allen, K.a. Gallagher, M.G. Healy, Biosorption from aqueous solutions by eggshell membranes and Rhizopus oryzae:Equilibrium and kinetic studies, J. Chem. Technol. Biotechnol. 77(2002) 539-545.
[23] T.E. Köse, B. Kivanç, Adsorption of phosphate from aqueous solutions using calcined waste eggshell, Chem. Eng. J. 178(2011) 34-39.
[24] M. Hedayati, M. Esmaieli, Tetracycline adsorption by H3PO4-activated carbon produced from apricot nut shells:A batch study, Process. Saf. Environ. Prot. 102(2016) 700-709.
[25] S.N. Mohseni, A.A. Amooey, H. Tashakkorian, A.I. Amouei, Removal of dexamethasone from aqueous solutions using modified clinoptilolite zeolite (equilibrium and kinetic), Int. J. Environ. Sci. Technol. 13(9) (2016) 2261-2268.

Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell

Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell

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