SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2021, Vol. 32 ›› Issue (4): 203-211.DOI: 10.1016/j.cjche.2020.07.027

• Catalysis, Kinetics and Reaction Engineering • 上一篇    下一篇

Dehydrogenation of isobutane to isobutene over a Pt-Cu bimetallic catalyst in the presence of LaAlO3 perovskite

Yanyong Li1, Meng Ge1, Jiameng Wang1, Mengquan Guo1, Fanji Liu1, Mingxun Han1, Yanhong Xu2, Lihong Zhang1   

  1. 1 Department of Catalysis Science and Technology, Tianjin Key Laboratory of Applied Catalysis Science&Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
    2 Department of Materials Engineering, Xuzhou College of Industrial Technology, Xuzhou 221140, China
  • 收稿日期:2020-02-25 修回日期:2020-07-09 出版日期:2021-04-28 发布日期:2021-06-19
  • 通讯作者: Lihong Zhang
  • 基金资助:
    This work was supported by the National Natural Science Foundation of China (21776214) and State Key Laboratory of Chemical Resource Engineering.

Dehydrogenation of isobutane to isobutene over a Pt-Cu bimetallic catalyst in the presence of LaAlO3 perovskite

Yanyong Li1, Meng Ge1, Jiameng Wang1, Mengquan Guo1, Fanji Liu1, Mingxun Han1, Yanhong Xu2, Lihong Zhang1   

  1. 1 Department of Catalysis Science and Technology, Tianjin Key Laboratory of Applied Catalysis Science&Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
    2 Department of Materials Engineering, Xuzhou College of Industrial Technology, Xuzhou 221140, China
  • Received:2020-02-25 Revised:2020-07-09 Online:2021-04-28 Published:2021-06-19
  • Contact: Lihong Zhang
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (21776214) and State Key Laboratory of Chemical Resource Engineering.

摘要: In this study, isobutane dehydrogenation to isobutene reaction was carried out in a series of Pt-Cu bimetallic catalysts prepared by co-impregnation method. The catalysts were characterized by means of several techniques, including XRD, N2 adsorption-desorption, TEM, XPS, H2-TPR and TG. The results show that the existence of LaAlO3 perovskite can enhance the dispersion and sintering resistance of metal nanoparticles and facilitate the transfer of carbon deposits from active sites to the support. Interestingly, the perovskite nanoparticles can also inhibit the reduction of CuOx and the formation of PtCu alloys, resulting in the suitable interaction between Pt and Cu. The Pt-Cu/LaAlO3/SiO2 catalyst exhibits the optimal dehydrogenation performance with an isobutane conversion of 47% and isobutene selectivity of 92% after 310 min reaction, which was ascribed to the unique role of LaAlO3 perovskite as well as the appropriate Pt-Cu interaction.

关键词: Isobutane dehydrogenation, Catalyst, Nanoparticles, Silica, LaAlO3 perovskite, Pt-Cu interaction

Abstract: In this study, isobutane dehydrogenation to isobutene reaction was carried out in a series of Pt-Cu bimetallic catalysts prepared by co-impregnation method. The catalysts were characterized by means of several techniques, including XRD, N2 adsorption-desorption, TEM, XPS, H2-TPR and TG. The results show that the existence of LaAlO3 perovskite can enhance the dispersion and sintering resistance of metal nanoparticles and facilitate the transfer of carbon deposits from active sites to the support. Interestingly, the perovskite nanoparticles can also inhibit the reduction of CuOx and the formation of PtCu alloys, resulting in the suitable interaction between Pt and Cu. The Pt-Cu/LaAlO3/SiO2 catalyst exhibits the optimal dehydrogenation performance with an isobutane conversion of 47% and isobutene selectivity of 92% after 310 min reaction, which was ascribed to the unique role of LaAlO3 perovskite as well as the appropriate Pt-Cu interaction.

Key words: Isobutane dehydrogenation, Catalyst, Nanoparticles, Silica, LaAlO3 perovskite, Pt-Cu interaction