Efficient adsorption to hexavalent chromium by iron oxalate modified D301: Characterization, performance and mechanisms

doi:10.1016/j.cjche.2020.06.031

中国化学工程学报 ›› 2021, Vol. 33 ›› Issue (5): 61-69.DOI: 10.1016/j.cjche.2020.06.031

• Separation Science and Engineering • 上一篇下一篇

Efficient adsorption to hexavalent chromium by iron oxalate modified D301: Characterization, performance and mechanisms

Dongmei Jia¹, Huamin Cai^1,2, Yongzheng Duan¹, Jiangbao Xia³, Jia Guo²

1 School of Chemical Engineering and Safety, Binzhou University, Binzhou 256603, China;
2 School of Chemical Engineering and Pharmaceutical, Wuhan Institute of Technology, Wuhan 430073, China;
3 Shandong Key Laboratory of Eco-Environmental Science for the Yellow River Delta, Binzhou University, Binzhou 256603, China

收稿日期:2020-04-23 修回日期:2020-06-14 出版日期:2021-05-28 发布日期:2021-08-19
通讯作者: Dongmei Jia
基金资助:
The research has been funded by the National Key Research & Development Program of China (2017YFC0505904), National Natural Science Foundation of China (51808040), Taishan Scholars Program of Shandong Province.

Efficient adsorption to hexavalent chromium by iron oxalate modified D301: Characterization, performance and mechanisms

Dongmei Jia¹, Huamin Cai^1,2, Yongzheng Duan¹, Jiangbao Xia³, Jia Guo²

1 School of Chemical Engineering and Safety, Binzhou University, Binzhou 256603, China;
2 School of Chemical Engineering and Pharmaceutical, Wuhan Institute of Technology, Wuhan 430073, China;
3 Shandong Key Laboratory of Eco-Environmental Science for the Yellow River Delta, Binzhou University, Binzhou 256603, China

Received:2020-04-23 Revised:2020-06-14 Online:2021-05-28 Published:2021-08-19
Contact: Dongmei Jia
Supported by:
The research has been funded by the National Key Research & Development Program of China (2017YFC0505904), National Natural Science Foundation of China (51808040), Taishan Scholars Program of Shandong Province.

摘要/Abstract

摘要： Chromium is a common harmful pollutant with high toxicity and low bearing capacity of soil and water. Excellent salinity resistance, a wide pH range, and high regeneration capacity were essential for qualified adsorbents used in removing hexavalent chromium (Cr(VI)) from polluted water. Herein, iron oxalate modified weak basic resin (IO@D301) for the removal of Cr(VI) was prepared by the impregnation method. The IO@D301 was characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Owing to abundant amine, carboxyl groups and iron ions existing on the surface, IO@D301 possesses high adsorption and salinity resistance capacity for Cr(VI). The maximum adsorption capacity of IO301 towards Cr(VI) reached 201.30 mg·g^-1 at 293 K and a pH of 5. The adsorption equilibrium was well fitted by the Freundlich model, and the adsorption process was described by the pseudofirst-order kinetics model as spontaneous and exothermic. The mechanism may be identified as electrostatic attraction, coordination, and reduction, which was confirmed by FT-IR and X-ray photoelectron spectroscopy.

关键词: D301, Iron oxalate, Chromium, Adsorption

Abstract: Chromium is a common harmful pollutant with high toxicity and low bearing capacity of soil and water. Excellent salinity resistance, a wide pH range, and high regeneration capacity were essential for qualified adsorbents used in removing hexavalent chromium (Cr(VI)) from polluted water. Herein, iron oxalate modified weak basic resin (IO@D301) for the removal of Cr(VI) was prepared by the impregnation method. The IO@D301 was characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Owing to abundant amine, carboxyl groups and iron ions existing on the surface, IO@D301 possesses high adsorption and salinity resistance capacity for Cr(VI). The maximum adsorption capacity of IO301 towards Cr(VI) reached 201.30 mg·g^-1 at 293 K and a pH of 5. The adsorption equilibrium was well fitted by the Freundlich model, and the adsorption process was described by the pseudofirst-order kinetics model as spontaneous and exothermic. The mechanism may be identified as electrostatic attraction, coordination, and reduction, which was confirmed by FT-IR and X-ray photoelectron spectroscopy.

Key words: D301, Iron oxalate, Chromium, Adsorption

Dongmei Jia, Huamin Cai, Yongzheng Duan, Jiangbao Xia, Jia Guo. Efficient adsorption to hexavalent chromium by iron oxalate modified D301: Characterization, performance and mechanisms[J]. 中国化学工程学报, 2021, 33(5): 61-69.

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Efficient adsorption to hexavalent chromium by iron oxalate modified D301: Characterization, performance and mechanisms

Efficient adsorption to hexavalent chromium by iron oxalate modified D301: Characterization, performance and mechanisms

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