Stable interfaces constructed by concentrated ether electrolytes to render robust lithium metal batteries

doi:10.1016/j.cjche.2021.03.021

中国化学工程学报 ›› 2021, Vol. 37 ›› Issue (9): 152-158.DOI: 10.1016/j.cjche.2021.03.021

• Energy Science and Technology • 上一篇下一篇

Stable interfaces constructed by concentrated ether electrolytes to render robust lithium metal batteries

He Liu^1,2, Tao Li³, Xiangqun Xu⁴, Peng Shi⁴, Xueqiang Zhang⁴, Rui Xu^1,2, Xinbing Cheng⁴, Jiaqi Huang²

1. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;
2. Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China;
3. School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, China;
4. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

收稿日期:2021-01-17 修回日期:2021-03-05 出版日期:2021-09-28 发布日期:2021-11-02
通讯作者: Jiaqi Huang
基金资助:
This work was supported by Beijing Natural Science Foundation (JQ20004), National Natural Science Foundation of China (21805161, 21808121, and U1932220), China Post-Doctoral Science Foundation (2020M670155 and 2020T130054), Scientific and Technological Key Project of Shanxi Province (20191102003).

Stable interfaces constructed by concentrated ether electrolytes to render robust lithium metal batteries

He Liu^1,2, Tao Li³, Xiangqun Xu⁴, Peng Shi⁴, Xueqiang Zhang⁴, Rui Xu^1,2, Xinbing Cheng⁴, Jiaqi Huang²

1. School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;
2. Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China;
3. School of Resource Environment and Safety Engineering, University of South China, Hengyang 421001, China;
4. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2021-01-17 Revised:2021-03-05 Online:2021-09-28 Published:2021-11-02
Contact: Jiaqi Huang
Supported by:
This work was supported by Beijing Natural Science Foundation (JQ20004), National Natural Science Foundation of China (21805161, 21808121, and U1932220), China Post-Doctoral Science Foundation (2020M670155 and 2020T130054), Scientific and Technological Key Project of Shanxi Province (20191102003).

摘要/Abstract

摘要： Lithium metal batteries (LMBs) are highly considered as promising candidates for next-generation energy storage systems. However, routine electrolytes cannot tolerate the high potential at cathodes and low potential at anodes simultaneously, leading to severe interfacial reactions. Herein, a highly concentrated electrolyte (HCE) region trapped in porous carbon coating layer is adopted to form a stable and highly conductive solid electrolyte interphase (SEI) on Li metal surface. The protected Li metal anode can potentially match the high-voltage cathode in ester electrolytes. Synergistically, this ingenious design promises high-voltage-resistant interfaces at cathodes and stable SEI with abundance of inorganic components at anodes simultaneously in high-voltage LMBs. The feasibility of this interface-regulation strategy is demonstrated in Li|LiFePO₄ batteries, realizing a lifespan twice as long as the routine cells, with a huge capacity retention enhancement from 46.4% to 88.7% after 100 cycles. This contribution proof-of-concepts the emerging principles on the formation and regulation of stable electrode/electrolyte interfaces in the cathode and anode simultaneously towards the next-generation high-energy-density batteries.

关键词: Lithium metal anode, Dendrite, Solid electrolyte interphase, Ester electrolyte, Highly concentrated ether electrolyte

Abstract: Lithium metal batteries (LMBs) are highly considered as promising candidates for next-generation energy storage systems. However, routine electrolytes cannot tolerate the high potential at cathodes and low potential at anodes simultaneously, leading to severe interfacial reactions. Herein, a highly concentrated electrolyte (HCE) region trapped in porous carbon coating layer is adopted to form a stable and highly conductive solid electrolyte interphase (SEI) on Li metal surface. The protected Li metal anode can potentially match the high-voltage cathode in ester electrolytes. Synergistically, this ingenious design promises high-voltage-resistant interfaces at cathodes and stable SEI with abundance of inorganic components at anodes simultaneously in high-voltage LMBs. The feasibility of this interface-regulation strategy is demonstrated in Li|LiFePO₄ batteries, realizing a lifespan twice as long as the routine cells, with a huge capacity retention enhancement from 46.4% to 88.7% after 100 cycles. This contribution proof-of-concepts the emerging principles on the formation and regulation of stable electrode/electrolyte interfaces in the cathode and anode simultaneously towards the next-generation high-energy-density batteries.

Key words: Lithium metal anode, Dendrite, Solid electrolyte interphase, Ester electrolyte, Highly concentrated ether electrolyte

He Liu, Tao Li, Xiangqun Xu, Peng Shi, Xueqiang Zhang, Rui Xu, Xinbing Cheng, Jiaqi Huang. Stable interfaces constructed by concentrated ether electrolytes to render robust lithium metal batteries[J]. 中国化学工程学报, 2021, 37(9): 152-158.

参考文献

[1] Y.S. Ye, L.Y. Chou, Y.Y. Liu, H.S. Wang, H.K. Lee, W.X. Huang, J.Y. Wan, K. Liu, G. M. Zhou, Y.F. Yang, A.K. Yang, X. Xiao, X. Gao, D.T. Boyle, H. Chen, W.B. Zhang, S. C. Kim, Y. Cui, Ultralight and fire-extinguishing current collectors for highenergy and high-safety lithium-ion batteries, Nat. Energy 5(10) (2020) 786-793.
[2] L.L. Wang, R.C. Xie, B.B. Chen, X.R. Yu, J. Ma, C. Li, Z.W. Hu, X.W. Sun, C.J. Xu, S. M. Dong, T.S. Chan, J. Luo, G.L. Cui, L.Q. Chen, In-situ visualization of the spacecharge-layer effect on interfacial lithium-ion transport in all-solid-state batteries, Nat. Commun. 11(1) (2020) 5889.
[3] Y. Liang, C.-Z. Zhao, H. Yuan, Y. Chen, W. Zhang, J.-Q. Huang, D. Yu, Y. Liu, M.-M. Titirici, Y.-L. Chueh, H. Yu, Q. Zhang, A review of rechargeable batteries for portable electronic devices, InfoMat 1(1) (2019) 6-32.
[4] A. Parejiya, R. Amin, R. Essehli, D.L. Wood III, I. Belharouak, Electrochemical healing of dendrites in garnet-based solid electrolytes, ACS Energy Lett. 5(11) (2020) 3368-3373.
[5] W.H. Ren, C.F. Ding, X.W. Fu, Y. Huang, Advanced gel polymer electrolytes for safe and durable lithium metal batteries:Challenges, strategies, and perspectives, Energy Storage Mater. 34(2021) 515-535.
[6] P. Zhai, L. Liu, X. Gu, T. Wang, Y. Gong, Interface engineering for lithium metal anodes in liquid electrolyte, Adv. Energy Mater. 10(34) (2020) 2001257.
[7] S. Stalin, M. Tikekar, P. Biswal, G.J. Li, H.E.N. Johnson, Y. Deng, Q. Zhao, D. Vu, G. W. Coates, L.A. Archer, Designing polymeric interphases for stable lithium metal deposition, Nano Lett. 20(8) (2020) 5749-5758.
[8] P. Shi, X.Q. Zhang, X. Shen, B.Q. Li, R. Zhang, L.P. Hou, Q. Zhang, A pressure selfadaptable route for uniform lithium plating and stripping in composite anode, Adv. Funct. Mater. 31(5) (2021) 2004189.
[9] W. Jiang, L.J. Yan, X.M. Zeng, X.J. Meng, R.Z. Huang, X.X. Zhu, M. Ling, C.D. Liang, Adhesive sulfide solid electrolyte interface for lithium metal batteries, ACS Appl. Mater. Interfaces 12(49) (2020) 54876-54883.
[10] H. Liu, X.B. Cheng, R. Zhang, P. Shi, X. Shen, X.R. Chen, T. Li, J.Q. Huang, Q. Zhang, Mesoporous graphene hosts for dendrite-free lithium metal anode in working rechargeable batteries, Trans. Tianjin Univ. 26(2) (2020) 127-134.
[11] R.H. Wang, W.S. Cui, F.L. Chu, F.X. Wu, Lithium metal anodes:Present and future, J. Energy Chem. 48(2020) 145-159.
[12] H. Li, D.L. Chao, B. Chen, X. Chen, C. Chuah, Y.H. Tang, Y. Jiao, M. Jaroniec, S.Z. Qiao, Revealing principles for design of lean-electrolyte lithium metal anode via in situ spectroscopy, J. Am. Chem. Soc. 142(4) (2020) 2012-2022.
[13] C. Fear, M. Parmananda, V. Kabra, R. Carter, C.T. Love, P.P. Mukherjee, Mechanistic underpinnings of thermal gradient induced inhomogeneity in lithium plating, Energy Storage Mater. 35(2021) 500-511.
[14] H. Liu, X.-B. Cheng, J.-Q. Huang, H. Yuan, Y. Lu, C. Yan, G.-L. Zhu, R. Xu, C.-Z. Zhao, L.-P. Hou, C. He, S. Kaskel, Q. Zhang, Controlling dendrite growth in solidstate electrolytes, ACS Energy Lett. 5(3) (2020) 833-843.
[15] Y. Shi, J. Wan, G.X. Liu, T.T. Zuo, Y.X. Song, B. Liu, Y.G. Guo, R. Wen, L.J. Wan, Interfacial evolution of lithium dendrites and their solid electrolyte interphase shells of quasi-solid-state lithium-metal batteries, Angew. Chem. Int. Ed. 59(41) (2020) 18120-18125.
[16] L.P. Hou, X.Q. Zhang, B.Q. Li, Q. Zhang, Cycling a lithium metal anode at 90℃ in a liquid electrolyte, Angew. Chem. 132(35) (2020) 15221-15225.
[17] H. Dai, X. Gu, J. Dong, C. Wang, C. Lai, S. Sun, Stabilizing lithium metal anode by octaphenyl polyoxyethylene-lithium complexation, Nat. Commun. 11(1) (2020) 643.
[18] S. Li, Z. Luo, L. Li, J.G. Hu, G.Q. Zou, H.S. Hou, X.B. Ji, Recent progress on electrolyte additives for stable lithium metal anode, Energy Storage Mater. 32(2020) 306-319.
[19] T.Y. Wang, Y.B. Li, J.Q. Zhang, K. Yan, P. Jaumaux, J. Yang, C.Y. Wang, D. Shanmukaraj, B. Sun, M. Armand, Y. Cui, G.X. Wang, Immunizing lithium metal anodes against dendrite growth using protein molecules to achieve high energy batteries, Nat. Commun. 11(1) (2020) 5429.
[20] Z. Hou, J.L. Zhang, W.H. Wang, Q.W. Chen, B.H. Li, C.L. Li, Towards highperformance lithium metal anodes via the modification of solid electrolyte interphases, J. Energy Chem. 45(2020) 7-17.
[21] Y.T. He, Y.H. Zhang, P. Yu, F. Ding, X.F. Li, Z.H. Wang, Z. Lv, X.J. Wang, Z.G. Liu, X. Q. Huang, Ion association tailoring SEI composition for Li metal anode protection, J. Energy Chem. 45(2020) 1-6.
[22] S. Jin, Y.D. Ye, Y.J. Niu, Y.S. Xu, H.C. Jin, J.X. Wang, Z.W. Sun, A.M. Cao, X.J. Wu, Y. Luo, H.X. Ji, L.J. Wan, Solid-solution-based metal alloy phase for highly reversible lithium metal anode, J. Am. Chem. Soc. 142(19) (2020) 8818-8826.
[23] T.Z. Yang, Y.W. Sun, T. Qian, J. Liu, X.J. Liu, F. Rosei, C.L. Yan, Lithium dendrite inhibition via 3D porous lithium metal anode accompanied by inherent SEI layer, Energy Storage Mater. 26(2020) 385-390.
[24] R. Wang, J. Yu, J.T. Tang, R.J. Meng, L.F. Nazar, L.Z. Huang, X. Liang, Insights into dendrite suppression by alloys and the fabrication of a flexible alloy-polymer protected lithium metal anode, Energy Storage Mater. 32(2020) 178-184.
[25] S. Liu, Q.Q. Zhao, X.Y. Zhang, J.Y. Liu, L. Dai, L. Wang, J.Y. Luo, A high rate and long cycling life lithium metal anode with a self-repairing alloy coating, J. Mater. Chem. A 8(34) (2020) 17415-17419.
[26] Y.L. Cui, S.F. Liu, D.H. Wang, X.L. Wang, X.H. Xia, C.D. Gu, J.P. Tu, A facile way to construct stable and ionic conductive lithium sulfide nanoparticles composed solid electrolyte interphase on Li metal anode, Adv. Funct. Mater. 31(3) (2021) 2006380.
[27] R. Xu, X.B. Cheng, C. Yan, X.Q. Zhang, Y. Xiao, C.Z. Zhao, J.Q. Huang, Q. Zhang, Artificial interphases for highly stable lithium metal anode, Matter 1(2) (2019) 317-344.
[28] J.F. Ding, R. Xu, C. Yan, Y. Xiao, Y.R. Liang, H. Yuan, J.Q. Huang, Integrated lithium metal anode protected by composite solid electrolyte film enables stable quasi-solid-state lithium metal batteries, Chin. Chem. Lett. 31(9) (2020) 2339-2342.
[29] S.B. Zeng, G.M. Arumugam, W.T. Li, X.H. Liu, X. Li, H. Zhong, F. Guo, Y.H. Mai, Robust interface layers with redox shuttle reactions suppress the dendrite growth for stable solid-state Li metal batteries, J. Energy Chem. 51(2020) 222-229.
[30] Y.X. Yuan, F. Wu, G.H. Chen, Y. Bai, C. Wu, Porous LiF layer fabricated by a facile chemical method toward dendrite-free lithium metal anode, J. Energy Chem. 37(2019) 197-203.
[31] H. Jia, L. Zou, P. Gao, X. Cao, W. Zhao, Y. He, M.H. Engelhard, S.D. Burton, H. Wang, X. Ren, Q. Li, R. Yi, X. Zhang, C. Wang, Z. Xu, X. Li, J.-G. Zhang, W. Xu, High-performance silicon anodes enabled by nonflammable localized highconcentration electrolytes, Adv. Energy Mater. 9(31) (2019) 1900784.
[32] J.F. Qian, W.A. Henderson, W. Xu, P. Bhattacharya, M. Engelhard, O. Borodin, J. G. Zhang, High rate and stable cycling of lithium metal anode, Nat. Commun. 6(2015) 6362.
[33] S.J. Chen, J.X. Zhang, L. Nie, X.C. Hu, Y.Q. Huang, Y. Yu, W. Liu, All-solid-state batteries with a limited lithium metal anode at room temperature using a garnet-based electrolyte, Adv. Mater. 33(1) (2021) e2002325.
[34] H.Y. Huo, Y. Chen, R.Y. Li, N. Zhao, J. Luo, J.G. Pereira da Silva, R. Mücke, P. Kaghazchi, X.X. Guo, X.L. Sun, Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries, Energy Environ. Sci. 13(1) (2020) 127-134.
[35] G. Wang, C. Chen, Y.H. Chen, X.W. Kang, C.H. Yang, F. Wang, Y. Liu, X.H. Xiong, Self-stabilized and strongly adhesive supramolecular polymer protective layer enables ultrahigh-rate and large-capacity lithium-metal anode, Angew. Chem. Int. Ed. Engl. 59(5) (2020) 2055-2060.
[36] T. Krauskopf, F.H. Richter, W.G. Zeier, J. Janek, Physicochemical concepts of the lithium metal anode in solid-state batteries, Chem. Rev. 120(15) (2020) 7745-7794.
[37] X.B. Cheng, C.Z. Zhao, Y.X. Yao, H. Liu, Q. Zhang, Recent advances in energy chemistry between solid-state electrolyte and safe lithium-metal anodes, Chem 5(1) (2019) 74-96.
[38] J. Yun, B.K. Park, E.S. Won, S.H. Choi, H.C. Kang, J.H. Kim, M.S. Park, J.W. Lee, Bottom-up lithium growth triggered by interfacial activity gradient on porous framework for lithium-metal anode, ACS Energy Lett. 5(10) (2020) 3108-3114.
[39] Y.Y. Feng, C.F. Zhang, X.X. Jiao, Z.X. Zhou, J.X. Song, Highly stable lithium metal anode with near-zero volume change enabled by capped 3D lithophilic framework, Energy Storage Mater. 25(2020) 172-179.
[40] C.Y. Cui, C.Y. Yang, N. Eidson, J. Chen, F.D. Han, L. Chen, C. Luo, P.F. Wang, X.L. Fan, C.S. Wang, A highly reversible, dendrite-free lithium metal anode enabled by a lithium-fluoride-enriched interphase, Adv. Mater. 32(12) (2020) 1906427.
[41] H.D. Yuan, J.W. Nai, H. Tian, Z.J. Ju, W.K. Zhang, Y.J. Liu, X.Y. Tao, X.W.D. Lou, An ultrastable lithium metal anode enabled by designed metal fluoride spansules, Sci. Adv. 6(10) (2020) eaaz3112.
[42] W.B. Ye, F. Pei, X.N. Lan, Y. Cheng, X.L. Fang, Q.B. Zhang, N.F. Zheng, D.L. Peng, M.S. Wang, Lithium batteries:Stable nano-encapsulation of lithium through seed-free selective deposition for high-performance Li battery anodes, Adv. Energy Mater. 10(7) (2020) 2070031.
[43] J. Liu, H. Yuan, X.Y. Tao, Y.R. Liang, S.J. Yang, J.Q. Huang, T.Q. Yuan, M.M. Titirici, Q. Zhang, Recent progress on biomass-derived ecomaterials toward advanced rechargeable lithium batteries, EcoMat 2(1) (2020) e12019.
[44] X.Y. Xu, Y.Y. Liu, J.Y. Hwang, O.O. Kapitanova, Z.X. Song, Y.K. Sun, A. Matic, S.Z. Xiong, Role of Li-ion depletion on electrode surface:underlying mechanism for electrodeposition behavior of lithium metal anode, Adv. Energy Mater. 10(44) (2020) 2002390.
[45] G.M.A. Girard, X.E. Wang, R. Yunis, D.R. MacFarlane, A.J. Bhattacharyya, M. Forsyth, P.C. Howlett, Sustainable, dendrite free lithium-metal electrode cycling achieved with polymer composite electrolytes based on a poly(ionic liquid) host, Batter. Supercaps 2(3) (2019) 229-239.
[46] J. Liu, R. Xu, C. Yan, H. Yuan, J.F. Ding, Y. Xiao, T.Q. Yuan, J.Q. Huang, In situ regulated solid electrolyte interphase via reactive separators for highly efficient lithium metal batteries, Energy Storage Mater. 30(2020) 27-33.
[47] C. Yan, Y.X. Yao, W.L. Cai, L. Xu, S. Kaskel, H.S. Park, J.Q. Huang, The influence of formation temperature on the solid electrolyte interphase of graphite in lithium ion batteries, J. Energy Chem. 49(2020) 335-338.
[48] H. Liu, X.B. Cheng, R. Xu, X.Q. Zhang, C. Yan, J.Q. Huang, Q. Zhang, Plating/stripping behavior of actual lithium metal anode, Adv. Energy Mater. 9(44) (2019) 1902254.
[49] W. Lu, L.Q. Sun, Y. Zhao, T. Wu, L.N. Cong, J. Liu, Y.L. Liu, H.M. Xie, Elongating the cycle life of lithium metal batteries in carbonate electrolyte with gradient solid electrolyte interphase layer, Energy Storage Mater. 34(2021) 241-249.
[50] H.Y. Chen, J.W. Chen, W.G. Zhang, Q.M. Xie, Y.X. Che, H.R. Wang, L.D. Xing, K. Xu, W.S. Li, Enhanced cycling stability of high-voltage lithium metal batteries with a trifunctional electrolyte additive, J. Mater. Chem. A 8(42) (2020) 22054-22064.
[51] Y. Yang, C. Yan, J.Q. Huang, Research progress of solid electrolyte interphase in lithium batteries, Acta Phys. Chim. Sin. (2020) 2010076.
[52] C. Peschel, F. Horsthemke, M. Leißing, S. Wiemers-Meyer, J. Henschel, M. Winter, S. Nowak, Analysis of carbonate decomposition during solid electrolyte interphase formation in isotope-labeled lithium ion battery electrolytes:extending the knowledge about electrolyte soluble species, Batter. Supercaps 3(11) (2020) 1183-1192.
[53] Y. Zheng, F.A. Soto, V. Ponce, J.M. Seminario, X. Cao, J.G. Zhang, P.B. Balbuena, Localized high concentration electrolyte behavior near a lithium-metal anode surface, J. Mater. Chem. A 7(43) (2019) 25047-25055.
[54] Z.J. Zheng, H. Ye, Z.P. Guo, Recent progress in designing stable composite lithium anodes with improved wettability, Adv. Sci. (Weinh) 7(22) (2020) 2002212.
[55] J. Qian, S. Wang, Y. Li, M.L. Zhang, F.J. Wang, Y.Y. Zhao, Q. Sun, L. Li, F. Wu, R.J. Chen, Lithium induced nano-sized copper with exposed lithiophilic surfaces to achieve dense lithium deposition for lithium metal anode, Adv. Funct. Mater. 31(7) (2021) 2006950.
[56] M. Li, C.S. Wang, Z.W. Chen, K. Xu, J. Lu, New concepts in electrolytes, Chem. Rev. 120(14) (2020) 6783-6819.
[57] C. Yan, H. Yuan, H.S. Park, J.Q. Huang, Perspective on the critical role of interface for advanced batteries, J. Energy Chem. 47(2020) 217-220.
[58] Z.C. Wang, Y.Y. Sun, Y.Y. Mao, F.R. Zhang, L. Zheng, D.S. Fu, Y.B. Shen, J.C. Hu, H. L. Dong, J.J. Xu, X.D. Wu, Highly concentrated dual-anion electrolyte for nonflammable high-voltage Li-metal batteries, Energy Storage Mater. 30(2020) 228-237.
[59] R. Amine, J.Z. Liu, I. Acznik, T. Sheng, K. Lota, H. Sun, C.J. Sun, K. Fic, X.B. Zuo, Y. Ren, D.A. Ei-Hady, W. Alshitari, A.S. Al-Bogami, Z.H. Chen, K. Amine, G.L. Xu, Regulating the hidden solvation-ion-exchange in concentrated electrolytes for stable and safe lithium metal batteries, Adv. Energy Mater. 10(25) (2020) 2000901.
[60] Y. Maeyoshi, D. Ding, M. Kubota, H. Ueda, K. Abe, K. Kanamura, H. Abe, Longterm stable lithium metal anode in highly concentrated sulfolane-based electrolytes with ultrafine porous polyimide separator, ACS Appl. Mater. Interfaces 11(29) (2019) 25833-25843.
[61] J. Ko, Y.S. Yoon, Recent progress in LiF materials for safe lithium metal anode of rechargeable batteries:Is LiF the key to commercializing Li metal batteries?, Ceram Int. 45(1) (2019) 30-49.
[62] J. Chen, X.L. Fan, Q. Li, H.B. Yang, M.R. Khoshi, Y.B. Xu, S. Hwang, L. Chen, X. Ji, C. Y. Yang, H.X. He, C.M. Wang, E. Garfunkel, D. Su, O. Borodin, C.S. Wang, Electrolyte design for LiF-rich solid-electrolyte interfaces to enable highperformance microsized alloy anodes for batteries, Nat. Energy 5(5) (2020) 386-397.
[63] Q.F. Yang, C.L. Li, Li metal batteries and solid state batteries benefiting from halogen-based strategies, Energy Storage Mater. 14(2018) 100-117.
[64] S.F. Liu, X. Ji, N. Piao, J. Chen, N. Eidson, J.J. Xu, P.F. Wang, L. Chen, J.X. Zhang, T. Deng, S. Hou, T. Jin, H.L. Wan, J.R. Li, J.P. Tu, C.S. Wang, An inorganic-rich solid electrolyte interphase for advanced lithium-metal batteries in carbonate electrolytes, Angew. Chem. 133(7) (2021) 3705-3715.
[65] X.B. Cheng, C. Yan, H.J. Peng, J.Q. Huang, S.T. Yang, Q. Zhang, Sulfurized solid electrolyte interphases with a rapid Li⁺ diffusion on dendrite-free Li metal anodes, Energy Storage Mater. 10(2018) 199-205.
[66] R. Pathak, K. Chen, A. Gurung, K.M. Reza, B. Bahrami, J. Pokharel, A. Baniya, W. He, F. Wu, Y. Zhou, K. Xu, Q.Q. Qiao, Fluorinated hybrid solid-electrolyteinterphase for dendrite-free lithium deposition, Nat. Commun. 11(1) (2020) 1-10.
[67] Y.X. Yao, X.Q. Zhang, B.Q. Li, C. Yan, P.Y. Chen, J.Q. Huang, Q. Zhang, A compact inorganic layer for robust anode protection in lithium-sulfur batteries, InfoMat 2(2) (2020) 379-388.
[68] J.X. Chen, X.Q. Zhang, B.Q. Li, X.M. Wang, P. Shi, W.C. Zhu, A.B. Chen, Z.H. Jin, R. Xiang, J.Q. Huang, Q. Zhang, The origin of sulfuryl-containing components in SEI from sulfate additives for stable cycling of ultrathin lithium metal anodes, J. Energy Chem. 47(2020) 128-131.

Stable interfaces constructed by concentrated ether electrolytes to render robust lithium metal batteries

Stable interfaces constructed by concentrated ether electrolytes to render robust lithium metal batteries

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