Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets

doi:10.1016/j.cjche.2022.09.001

中国化学工程学报 ›› 2023, Vol. 57 ›› Issue (5): 319-328.DOI: 10.1016/j.cjche.2022.09.001

• Full Length Article • 上一篇下一篇

Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets

Shanshan Mao¹, Tao Shen¹, Qing Zhao¹, Tong Han², Fan Ding¹, Xin Jin¹, Manglai Gao¹

1. State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, China;
2. Unconventional Natural Gas Institute, China University of Petroleum, Beijing 102249, China

收稿日期:2022-04-28 修回日期:2022-08-30 出版日期:2023-05-28 发布日期:2023-07-08
通讯作者: Manglai Gao,E-mail:mlgao@cup.edu.cn
基金资助:
The support to this work from the National Natural Science Foundation of China (21776306) is acknowledged.

Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets

Shanshan Mao¹, Tao Shen¹, Qing Zhao¹, Tong Han², Fan Ding¹, Xin Jin¹, Manglai Gao¹

1. State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, China;
2. Unconventional Natural Gas Institute, China University of Petroleum, Beijing 102249, China

Received:2022-04-28 Revised:2022-08-30 Online:2023-05-28 Published:2023-07-08
Contact: Manglai Gao,E-mail:mlgao@cup.edu.cn
Supported by:
The support to this work from the National Natural Science Foundation of China (21776306) is acknowledged.

摘要/Abstract

摘要： The introduction of bifunctional groups into low-cost adsorbents for selective adsorption of Ag(I) through synergistic effect will have a profound impact on the recovery of precious metals. Organo silica nanosheets (organo-SiNSs) functionalized by series of azole derivatives (2-mercaptoimidazole (MI), 2-mercaptobenzimidazole (MBT) and 1H-1,2,4-triazole-3-thiol (MTT)), are fabricated and employed for selective removal of Ag(I). The structures of the organo-SiNSs are investigated using several characterization methods. The results of batch adsorption experiments display that the maximum adsorption amounts are 70.3, 103.2 and 139.5 mg·g^-1 on MI-SiNSs, MBI-SiNSs and MTT-SiNSs for Ag(I) ions, and reach rapid equilibrium within 10–30 min. The adsorption processes are chemisorption and fit pseudo-second-order kinetic model and Langmuir adsorption isotherm model. Notably, MTT-SiNSs is greatly selective for Ag(I) in multicomponent system, and the distribution coefficient value of Ag(I) ions reaches 2331.26 ml·g^-1. The reusability of organo-SiNSs is verified by four cycles of regeneration tests with 0.1 mol·L^–1 HNO₃ as the eluent. A combination of experimental, structural along with theoretical analysis is conducted to proclaim the structure-adsorptivity relationship: (i) The adsorption mechanisms are attributed to complexation. (ii) The amino group and sulfhydryl group of MTT-SiNSs as well as MBI-SiNSs may have synergistic impacts on Ag(I) capture. (iii) The differences in adsorption behavior and selectivity of the three organo-SiNSs are mainly related to the form of function groups, charge density and steric hindrance of adsorbent. This work not only sheds light on the promise of functionalized organo-SiNSs for the rapid and selective removal/enrichment of Ag(I) ions in complex water systems, but also provides new insights for designing cost-effective SiNSs-based adsorbents.

关键词: Organo silica nanosheets, Adsorption, Silver ions, Selectivity, Mechanism, Waste treatment

Abstract: The introduction of bifunctional groups into low-cost adsorbents for selective adsorption of Ag(I) through synergistic effect will have a profound impact on the recovery of precious metals. Organo silica nanosheets (organo-SiNSs) functionalized by series of azole derivatives (2-mercaptoimidazole (MI), 2-mercaptobenzimidazole (MBT) and 1H-1,2,4-triazole-3-thiol (MTT)), are fabricated and employed for selective removal of Ag(I). The structures of the organo-SiNSs are investigated using several characterization methods. The results of batch adsorption experiments display that the maximum adsorption amounts are 70.3, 103.2 and 139.5 mg·g^-1 on MI-SiNSs, MBI-SiNSs and MTT-SiNSs for Ag(I) ions, and reach rapid equilibrium within 10–30 min. The adsorption processes are chemisorption and fit pseudo-second-order kinetic model and Langmuir adsorption isotherm model. Notably, MTT-SiNSs is greatly selective for Ag(I) in multicomponent system, and the distribution coefficient value of Ag(I) ions reaches 2331.26 ml·g^-1. The reusability of organo-SiNSs is verified by four cycles of regeneration tests with 0.1 mol·L^–1 HNO₃ as the eluent. A combination of experimental, structural along with theoretical analysis is conducted to proclaim the structure-adsorptivity relationship: (i) The adsorption mechanisms are attributed to complexation. (ii) The amino group and sulfhydryl group of MTT-SiNSs as well as MBI-SiNSs may have synergistic impacts on Ag(I) capture. (iii) The differences in adsorption behavior and selectivity of the three organo-SiNSs are mainly related to the form of function groups, charge density and steric hindrance of adsorbent. This work not only sheds light on the promise of functionalized organo-SiNSs for the rapid and selective removal/enrichment of Ag(I) ions in complex water systems, but also provides new insights for designing cost-effective SiNSs-based adsorbents.

Key words: Organo silica nanosheets, Adsorption, Silver ions, Selectivity, Mechanism, Waste treatment

Shanshan Mao, Tao Shen, Qing Zhao, Tong Han, Fan Ding, Xin Jin, Manglai Gao. Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets[J]. 中国化学工程学报, 2023, 57(5): 319-328.

参考文献

[1] J. R., B. Gurunathan, S. K, S. Varjani, H.H. Ngo, E. Gnansounou, Advancements in heavy metals removal from effluents employing nano-adsorbents: Way towards cleaner production, Environ. Res. 203 (2022) 111815.
[2] S. Krishnan, S. Chatterjee, A. Solanki, N. Guha, M.K. Singh, A.K. Gupta, D.K. Rai, Aminotetrazole-functionalized SiO₂ coated MgO nanoparticle composites for removal of acid fuchsin dye and detection of heavy metal ions, ACS Appl. Nano Mater. 3 (11) (2020) 11203–11216.
[3] Y.C. Liu, M.H. Gao, L. Zheng, J. Zhao, H. Wang, K. Han, Y.H. Zhou, Understanding the high adsorption–reduction performance of triethanolamine modified graphene oxide for silver ions, Colloids Surf. A 567 (2019) 96–103.
[4] S.U. Lee, Y.S. Jun, E.Z. Lee, N.S. Heo, W.H. Hong, Y.S. Huh, Y.K. Chang, Selective silver ion adsorption onto mesoporous graphitic carbon nitride, Carbon 95 (2015) 58-64.
[5] M.L. Cantuaria, A.F. de Almeida Neto, E.S. Nascimento, M.G.A. Vieira, Adsorption of silver from aqueous solution onto pre-treated bentonite clay: Complete batch system evaluation, J. Clean. Prod. 112 (2016) 1112–1121.
[6] Y.Y. Huang, Y.Y. Wu, W. Ding, Q. Sun, C. Hu, B.Z. Liu, H.X. Liu, H.L. Zheng, Anion-synergistic adsorption enhances the selective removal of silver ions from complex wastewater by chitosan-coated magnetic silica core–shell nanoparticles, J. Clean. Prod. 339 (2022) 130777.
[7] L. Zhang, Y.C. Zhao, C.Q. Mu, X.M. Zhang, Selective adsorption for Ag(I) from wastewater by carbon-magnetic fly ash beads modified with polydopamine and thiourea, Sustain. Chem. Pharm.17 (2020) 100287.
[8] C. Jeon, Adsorption and recovery of immobilized coffee ground beads for silver ions from industrial wastewater, J. Ind. Eng. Chem. 53 (2017) 261–267.
[9] S.X. Guo, M.L. Gao, T. Shen, Y. Xiang, G.L. Cao, Effective adsorption of sulfamethoxazole by novel Organo-Vts and their mechanistic insights, Microporous Mesoporous Mater. 286 (2019) 36–44.
[10] F. di Natale, A. Erto, A. Lancia, D. Musmarra, A descriptive model for metallic ions adsorption from aqueous solutions onto activated carbons, J. Hazard. Mater. 169 (1-3) (2009) 360–369.
[11] S.G. Wang, K.K. Wang, C. Dai, H.Z. Shi, J.L. Li, Adsorption of Pb²⁺ on amino-functionalized core-shell magnetic mesoporous SBA-15 silica composite, Chem. Eng. J. 262 (2015) 897–903.
[12] H. Uslu, D. Datta, S. Azizian, Separation of chromium(VI) from its liquid solution using new montmorillonite supported with amine based solvent, J. Mol. Liq. 215 (2016) 449–453.
[13] S.S. Mao, M.L. Gao, Functional organoclays for removal of heavy metal ions from water: A review, J. Mol. Liq. 334 (2021) 116143.
[14] T. Shen, M.L. Gao, Gemini surfactant modified organo-clays for removal of organic pollutants from water: A review, Chem. Eng. J. 375 (2019) 121910.
[15] T. Shen, M.L. Gao, W.L. Zang, F. Ding, J. Wang, Architecting organo silica nanosheets for regenerable cost-effective organics adsorbents, Chem. Eng. J. 331 (2018) 211–220.
[16] F. Ding, M.L. Gao, T. Shen, H. Zeng, Y. Xiang, Comparative study of organo-vermiculite, organo-montmorillonite and organo-silica nanosheets functionalized by an ether-spacer-containing Gemini surfactant: Congo red adsorption and wettability, Chem. Eng. J. 349 (2018) 388–396.
[17] H. Zeng, M.L. Gao, T. Shen, F. Ding, Organo silica nanosheets with gemini surfactants for rapid adsorption of ibuprofen from aqueous solutions, J. Taiwan Inst. Chem. Eng. 93 (2018) 329–335.
[18] S.X. Guo, M.L. Gao, T. Shen, Dipyridyl-based organo-silica nanosheets for three emerging micropollutants efficient removal: Adsorption performance and mechanisms, J. Clean. Prod. 260 (2020) 121149.
[19] T. Shen, S.S. Mao, F. Ding, T. Han, M.L. Gao, Selective adsorption of cationic/anionic tritoluene dyes on functionalized amorphous silica: A mechanistic correlation between the precursor, modifier and adsorbate, Colloids Surf. A 618 (2021) 126435.
[20] D.V. Quang, J.E. Lee, J.K. Kim,Y.N. Kim, G.N. Shao, H.T. Kim, A gentle method to graft thiol-functional groups onto silica gel for adsorption of silver ions and immobilization of silver nanoparticles, Powder Technol. 235 (2013) 221–227.
[21] S.S. Mao, T. Shen, T. Han, F. Ding, Q. Zhao, M.L. Gao, Adsorption and co-adsorption of chlorophenols and Cr(VI) by functional organo-vermiculite: Experiment and theoretical calculation, Sep. Purif. Technol. 277 (2021) 119638.
[22] T. Kang, Y. Park, K. Choi, J.S. Lee, J. Yi, Ordered mesoporous silica (SBA-15) derivatized with imidazole-containing functionalities as a selective adsorbent of precious metal ions, J. Mater. Chem. 14 (6) (2004) 1043.
[23] Z.Y. Zhang, Y. Kuang, Y. Lin, D.Y. Wu, A closed-loop sustainable scheme for silver recovery from water by reusable thiol-grafted graphene oxide, J. Clean. Prod. 305 (2021) 127146.
[24] X. Lai, D. Sun, Y. Hou, Y. Zuo, Y.B. Li, L. Zhang, Amino-functionalized multilayer core–shell mesoporous organosilica nanospheres for Cr(VI) removal, Adv. Mater. Interfaces 5 (18) (2018) 1800630.
[25] M. Machida, B. Fotoohi, Y. Amamo, L. Mercier, Cadmium(II) and lead(II) adsorption onto hetero-atom functional mesoporous silica and activated carbon, Appl. Surf. Sci. 258 (19) (2012) 7389–7394.
[26] P. Li, X.Q. Zhang, Y.J. Chen, T.Y. Bai, H.Z. Lian, X. Hu, X. Hu, One-pot synthesis of thiol- and amine-bifunctionalized mesoporous silica and applications in uptake and speciation of arsenic, RSC Adv. 4 (90) (2014) 49421–49428.
[27] W.C. Zhao, Y.J. Huang, R. Chen, H. Peng, Y.G. Liao, Q. Wang, Facile preparation of thioether/hydroxyl functionalized polyhedral oligomeric silsesquioxanes hybrid polymer for ultrahigh selective adsorption of silver(I) ions, React. Funct. Polym. 163 (2021) 104899.
[28] Y.J. Huang, W.C. Zhao, X. Zhang, H. Peng, Y.F. Gong, Thiol-ene synthesis of thioether/carboxyl-functionalized polymers for selective adsorption of silver (I) ions, Chem. Eng. J. 375 (2019) 121935.
[29] D. Pérez-Quintanilla, I. del Hierro, M. Fajardo, I. Sierra, Preparation of 2-mercaptobenzothiazole-derivatized mesoporous silica and removal of Hg(II) from aqueous solution, J. Environ. Monit. 8 (1) (2006) 214–222.
[30] B.C. Zhong, Q.F. Shi, Z.X. Jia, Y.F. Luo, Y.J. Chen, D.M. Jia, Preparation of silica-supported 2-mercaptobenzimidazole and its antioxidative behavior in styrene-butadiene rubber, Polym. Degrad. Stab. 110 (2014) 260–267.
[31] P.N. Diagboya, B.I. Olu-Owolabi, K.O. Adebowale, Microscale scavenging of pentachlorophenol in water using amine and tripolyphosphate-grafted SBA-15 silica: Batch and modeling studies, J. Environ. Manage. 146 (2014) 42–49.
[32] Y. Snoussi, M. Abderrabba, A. Sayari, Removal of cadmium from aqueous solutions by adsorption onto polyethylenimine-functionalized mesocellular silica foam: Equilibrium properties, J. Taiwan Inst. Chem. Eng. 66 (2016) 372–378.
[33] K.C. Zhu, Y.Y. Duan, F. Wang, P. Gao, H.Z. Jia, C.Y. Ma, C.Y. Wang, Silane-modified halloysite/ Fe₃O₄ nanocomposites: Simultaneous removal of Cr(VI) and Sb(V) and positive effects of Cr(VI) on Sb(V) adsorption, Chem. Eng. J. 311 (2017) 236–246
[34] S. Radi, M. El Massaoudi, M. Bacquet, S. Degoutin, N.N. Adarsh, K. Robeyns, Y. Garcia, A novel environment-friendly hybrid material based on a modified silica gel with a bispyrazole derivative for the removal of ZnII, PbII, CdII and CuII traces from aqueous solutions, Inorg. Chem. Front. 4 (11) (2017) 1821–1831.
[35] S.L. Li, S.Q. Li, N. Wen, D. Wei, Y.F. Zhang, Highly effective removal of lead and cadmium ions from wastewater by bifunctional magnetic mesoporous silica, Sep. Purif. Technol. 265 (2021) 118341.
[36] F. di Natale, V. Gargiulo, M. Alfè, Adsorption of heavy metals on silica-supported hydrophilic carbonaceous nanoparticles (SHNPs), J. Hazard. Mater. 393 (2020) 122374.
[37] A. Shahbazi, H. Younesi, A. Badiei, Functionalized SBA-15 mesoporous silica by melamine-based dendrimer amines for adsorptive characteristics of Pb(II), Cu(II) and Cd(II) heavy metal ions in batch and fixed bed column, Chem. Eng. J. 168 (2) (2011) 505–518.
[38] Y. Liu, Z.M. Lou, Y. Sun, X.X. Zhou, S.A. Baig, X.H. Xu, Influence of complexing agent on the removal of Pb(II) from aqueous solutions by modified mesoporous SiO₂, Microporous Mesoporous Mater. 246 (2017) 1–13.
[39] F. Wu, T. Zhao, Y. Yao, T. Jiang, B. Wang, M.L. Wang, Recycling supercapacitor activated carbons for adsorption of silver(I) and chromium(VI) ions from aqueous solutions, Chemosphere 238 (2020) 124638.
[40] J. Chen, J.W. Zhu, N. Wang, J.T. Feng, W. Yan, Hydrophilic polythiophene/ SiO₂, composite for adsorption engineering: Green synthesis in aqueous medium and its synergistic and specific adsorption for heavy metals from wastewater, Chem. Eng. J. 360 (2019) 1486–1497.
[41] Y.M. Dai, L.L. Niu, J.Q. Zou, T.X. Chen, H. Liu, Y. Zhou, Preparation of core-shell magnetic Fe₃O₄@SiO₂-dithiocarbamate nanoparticle and its application for the Ni²⁺, Cu²⁺ removal, Chin. Chem. Lett. 29 (6) (2018) 887–891.
[42] H. Long, P.X. Wu, L. Yang, Z.J. Huang, N.W. Zhu, Z.X. Hu, Efficient removal of cesium from aqueous solution with vermiculite of enhanced adsorption property through surface modification by ethylamine, J. Colloid Interface Sci. 428 (2014) 295–301.
[43] T. A. Saleh, A. Sarı, M. Tuzen, Chitosan-modified vermiculite for As(III) adsorption from aqueous solution: Equilibrium, thermodynamic and kinetic studies, J. Mol. Liq. 219 (2016) 937–945.
[44] M. Santhamoorthy, K. Thirupathi, T. Periyasamy, D. Thirumalai, V. Ramkumar, S. Asrafali, S.C. Kim,Synthesis of bifunctional groups-integrated mesoporous silica hybrid adsorbent for simultaneous removal of Hg²⁺ and Cu²⁺ ions from aqueous solution, Surf. Interfaces 29 (2022) 101808.
[45] Y.Z. Zhou, L.P. Luan, B.T. Tang, Y.Z. Niu, R.J. Qu, Y. Liu, W.L. Xu, Fabrication of Schiff base decorated PAMAM dendrimer/magnetic Fe₃O₄ for selective removal of aqueous Hg(II), Chem. Eng. J. 398 (2020) 125651.
[46] Z.C. Chen, B.T. Tang, Y.Z. Niu, H. Chen, Y.F. Liu, A.L. Wang, L.J. Bai, Synthesis of silica supported thiosemicarbazide for Cu(II) and Zn(II) adsorption from ethanol: A comparison with aqueous solution, Fuel 286 (2021) 119287.
[47] L.P. Luan, B.T. Tang, Y.F. Liu, A.L. Wang, B.B. Zhang, W.L. Xu, Y.Z. Niu, Selective capture of Hg(II) and Ag(I) from water by sulfur-functionalized polyamidoamine dendrimer/magnetic Fe₃O₄ hybrid materials, Sep. Purif. Technol. 257 (2021) 117902.
[48] Z.J. Xu, K.J. Wang, Q. Liu, F.R. Guo, Z.D. Xiong, Y.G. Li, A bifunctional adsorbent of silica gel-immobilized Schiff base derivative for simultaneous and selective adsorption of Cu(II) and SO₄^2-, Sep. Purif. Technol. 191 (2018) 61–74.
[49] Q. Ge, H.Z. Liu, Tunable amine-functionalized silsesquioxane-based hybrid networks for efficient removal of heavy metal ions and selective adsorption of anionic dyes, Chem. Eng. J. 428 (2022) 131370.
[50] P. Liu, X.L. Wang, L. Tian, B.Q. He, X.L. Lv, X.D. Li, C. Wang, L.Z. Song, Adsorption of silver ion from the aqueous solution using a polyvinylidene fluoride functional membrane bearing thiourea groups, J. Water Process. Eng. 34 (2020) 101184.
[51] T. Shen, L. Wang, Q. Zhao, S.X. Guo, M.L. Gao, Single and simultaneous adsorption of basic dyes by novel organo-vermiculite: A combined experimental and theoretical study, Colloids Surf. A 601 (2020) 125059.

Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets

Selective capture of silver ions from aqueous solution by series of azole derivatives-functionalized silica nanosheets

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