Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study

doi:10.1016/j.cjche.2023.03.017

中国化学工程学报 ›› 2023, Vol. 61 ›› Issue (9): 248-259.DOI: 10.1016/j.cjche.2023.03.017

• Full Length Article • 上一篇下一篇

Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study

Wenming Hao^1,2, Basma I. Waisi^2,3, Timothy M. Vadas⁴, Jeffrey R. McCutcheon²

1. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
2. Department of Chemical & Biomolecular Engineering, University of Connecticut, Storrs, CT 06269, United States;
3. Department of Chemical Engineering, University of Baghdad, Baghdad 10071, Iraq;
4. Department of Civil and Environmental Engineering, University of Connecticut, Storrs, CT 06269, United States

收稿日期:2022-07-18 修回日期:2023-03-13 出版日期:2023-09-28 发布日期:2023-12-14
通讯作者: Wenming Hao,E-mail:haowenming@tyut.edu.cn
基金资助:
Dr. Jian Ren is thanked for the help with the mechanical strength measurements. This work was financially supported by the National Science Foundation (1438518).

Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study

Wenming Hao^1,2, Basma I. Waisi^2,3, Timothy M. Vadas⁴, Jeffrey R. McCutcheon²

1. College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, China;
2. Department of Chemical & Biomolecular Engineering, University of Connecticut, Storrs, CT 06269, United States;
3. Department of Chemical Engineering, University of Baghdad, Baghdad 10071, Iraq;
4. Department of Civil and Environmental Engineering, University of Connecticut, Storrs, CT 06269, United States

Received:2022-07-18 Revised:2023-03-13 Online:2023-09-28 Published:2023-12-14
Contact: Wenming Hao,E-mail:haowenming@tyut.edu.cn
Supported by:
Dr. Jian Ren is thanked for the help with the mechanical strength measurements. This work was financially supported by the National Science Foundation (1438518).

摘要/Abstract

摘要： Activated carbon nanofibers (ACNFs) with small diameter can significantly increase the accessibility of intra pores and accelerate adsorption of molecules from water. In this study, ACNFs were made by blending K₂CO₃ or ZnCl₂ as the activating agent into the polyacrylonitrile (PAN) in dimethylformamide solution for electrospinning prior to pyrolysis. Bisphenol-A (BPA), an endocrine disruption pollutant, is widely applied in the production of polycarbonate plastics and epoxy resins. Accordingly, BPA is often used as a model contaminant commonly removed via adsorption. Batch adsorption studies were used to evaluate the kinetics and adsorption capacity of the ACNFs. Redlich–Peterson (R–P) and Langmuir models were found to fit the isotherm of BPA adsorption better than Freundlich model, showing the homogeneous nature of the PAN originated ACNFs. The adsorption kinetics was better described by the pseudo second-order model than that by the pseudo first-order model. The fitting by intraparticle diffusion model indicates the adsorption of BPA onto ACNFs is mainly controlled by pore diffusion. High pH value and ionic strength reduced BPA adsorption from aqueous solution. The breakthrough curves studied in two different fixed bed systems (cross flow bed system and packed flow bed system) confirmed the scalability of BPA removal by ACNFs in dynamic adsorption processes. The modified dose–response model predicted well the fixed-bed outlet concentration profiles.

关键词: Activated carbon nanofibers (ACNFs), Chemical activation, Bisphenol-A (BPA), Fixed bed, Adsorption

Abstract: Activated carbon nanofibers (ACNFs) with small diameter can significantly increase the accessibility of intra pores and accelerate adsorption of molecules from water. In this study, ACNFs were made by blending K₂CO₃ or ZnCl₂ as the activating agent into the polyacrylonitrile (PAN) in dimethylformamide solution for electrospinning prior to pyrolysis. Bisphenol-A (BPA), an endocrine disruption pollutant, is widely applied in the production of polycarbonate plastics and epoxy resins. Accordingly, BPA is often used as a model contaminant commonly removed via adsorption. Batch adsorption studies were used to evaluate the kinetics and adsorption capacity of the ACNFs. Redlich–Peterson (R–P) and Langmuir models were found to fit the isotherm of BPA adsorption better than Freundlich model, showing the homogeneous nature of the PAN originated ACNFs. The adsorption kinetics was better described by the pseudo second-order model than that by the pseudo first-order model. The fitting by intraparticle diffusion model indicates the adsorption of BPA onto ACNFs is mainly controlled by pore diffusion. High pH value and ionic strength reduced BPA adsorption from aqueous solution. The breakthrough curves studied in two different fixed bed systems (cross flow bed system and packed flow bed system) confirmed the scalability of BPA removal by ACNFs in dynamic adsorption processes. The modified dose–response model predicted well the fixed-bed outlet concentration profiles.

Key words: Activated carbon nanofibers (ACNFs), Chemical activation, Bisphenol-A (BPA), Fixed bed, Adsorption

Wenming Hao, Basma I. Waisi, Timothy M. Vadas, Jeffrey R. McCutcheon. Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study[J]. 中国化学工程学报, 2023, 61(9): 248-259.

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Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study

Chemically activated carbon nanofibers for adsorptive removal of bisphenol-A: Batch adsorption and breakthrough curve study

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