Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment

doi:10.1016/j.cjche.2023.12.025

中国化学工程学报 ›› 2024, Vol. 71 ›› Issue (7): 102-109.DOI: 10.1016/j.cjche.2023.12.025

Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment

Yuke Li^1,2, Yuxin Liu¹, Jizhen Huang¹, Yi Mei^1,2

1. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China;
2. Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials, Kunming University of Science and Technology, Kunming 650500, China

收稿日期:2023-10-26 修回日期:2023-12-12 出版日期:2024-07-28 发布日期:2024-08-30
通讯作者: Yuxin Liu,E-mail:yuxinliukm@kmust.edu.cn;Yi Mei,E-mail:meiyi_412@sina.com
基金资助:
This work was supported by the Degradable Plastics Engineering Research Center of Yunnan Provincial Education Department (KKPU202205001).

Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment

Yuke Li^1,2, Yuxin Liu¹, Jizhen Huang¹, Yi Mei^1,2

1. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China;
2. Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials, Kunming University of Science and Technology, Kunming 650500, China

Received:2023-10-26 Revised:2023-12-12 Online:2024-07-28 Published:2024-08-30
Contact: Yuxin Liu,E-mail:yuxinliukm@kmust.edu.cn;Yi Mei,E-mail:meiyi_412@sina.com
Supported by:
This work was supported by the Degradable Plastics Engineering Research Center of Yunnan Provincial Education Department (KKPU202205001).

摘要/Abstract

摘要： Elucidating the effect of growth periods on the quality of calcium sulfate whiskers (CSWs) prepared from calcium sulfate dihydrate (DH) is imperative. Herein, crystal seeds and whiskers were prepared from DH in a water–glycerol system. Longer whiskers were obtained from crystal seeds prepared via hydration of DH for 30 s than via ball milling for 5 min followed by hydration for 20 s. The attachment of cetyltrimethyl ammonium bromide and glycerol additives to the whisker tops promoted whisker growth. The whisker sponges exhibited good thermal barrier properties and compression cycle stability.

关键词: Hemihydrate gypsum whisker, Hydration, Ball milling/hydration, Crystal seed, Growth process

Abstract: Elucidating the effect of growth periods on the quality of calcium sulfate whiskers (CSWs) prepared from calcium sulfate dihydrate (DH) is imperative. Herein, crystal seeds and whiskers were prepared from DH in a water–glycerol system. Longer whiskers were obtained from crystal seeds prepared via hydration of DH for 30 s than via ball milling for 5 min followed by hydration for 20 s. The attachment of cetyltrimethyl ammonium bromide and glycerol additives to the whisker tops promoted whisker growth. The whisker sponges exhibited good thermal barrier properties and compression cycle stability.

Key words: Hemihydrate gypsum whisker, Hydration, Ball milling/hydration, Crystal seed, Growth process

Yuke Li, Yuxin Liu, Jizhen Huang, Yi Mei. Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment[J]. 中国化学工程学报, 2024, 71(7): 102-109.

Yuke Li, Yuxin Liu, Jizhen Huang, Yi Mei. Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment[J]. Chinese Journal of Chemical Engineering, 2024, 71(7): 102-109.

参考文献

[1] W. Du, L.P. Ma, J. Yang, W. Zhang, R. Ao, Experimental and numerical simulation of lignite chemical looping gasification with phosphogypsum as oxygen carrier in a fluidized bed, Chin. J. Chem. Eng. 37 (2021) 197-207.
[2] M.X. Du, J.M. Wang, F.Q. Dong, Z.J. Wang, F.H. Yang, H.B. Tan, K.B. Fu, W.Q. Wang, The study on the effect of flotation purification on the performance of α-hemihydrate gypsum prepared from phosphogypsum, Sci. Rep. 12 (1) (2022) 95.
[3] J.W. Jiao, X.P. Shen, H. Ding, D.Y. Lu, D.X. Li, Study on the hydration and properties of multiphase phosphogypsum synergistically activated by sodium sulfate and calcium sulfate whisker, Constr. Build. Mater. 355 (2022) 129225.
[4] F.H. Wu, C.Y. Zhao, G.F. Qu, S. Liu, Y.C. Ren, B.J. Chen, J.Y. Li, L.L. Liu, A critical review of the typical by-product clean ecology links in the Chinese phosphorus chemical industry in China: production technologies, fates and future directions, J. Environ. Chem. Eng. 10 (2) (2022) 106685.
[5] L. Sun, Z.J. Zhao, X.S. Yang, Y. Sun, Q.D. Li, C.H. Luo, Q. Zhao, Thermochemical decomposition of phosphogypsum with Fe-P slag via a solid-state reaction, Chin. J. Chem. Eng. 47 (2022) 113-119.
[6] B.X. Li, L. Li, X. Chen, Y. Ma, M.K. Zhou, Modification of phosphogypsum using circulating fluidized bed fly ash and carbide slag for use as cement retarder, Constr. Build. Mater. 338 (2022) 127630.
[7] J. Yang, B. Zhu, L.P. Ma, H.P. Liu, Investigation of Al₂O₃ and Fe₂O₃ transmission and transformation during the decomposition of phosphogypsum, Chin. J. Chem. Eng. 27 (5) (2019) 1125-1131.
[8] J.Y. Hao, G.J. Cheng, T. Hu, B. Guo, X.J. Li, Preparation of high-performance building gypsum by calcining FGD gypsum adding CaO as crystal modifier, Constr. Build. Mater. 306 (2021) 124910.
[9] J. Zhou, X.Q. Li, Y. Zhao, Z. Shu, Y.X. Wang, Y. Zhang, X. Shen, Preparation of paper-free and fiber-free plasterboard with high strength using phosphogypsum, Constr. Build. Mater. 243 (2020) 118091.
[10] J.W. Bossolani, C.A.C. Crusciol, M.F.A. Leite, L.F. Merloti, L.G. Moretti, I.M. Pascoaloto, E.E. Kuramae, Modulation of the soil microbiome by long-term Ca-based soil amendments boosts soil organic carbon and physicochemical quality in a tropical no-till crop rotation system, Soil Biol. Biochem. 156 (2021) 108188.
[11] M. Danouche, A. Bounaga, R. Boulif, Y. Zeroual, R. Benhida, K. Lyamlouli, Optimization of sulfate leaching from Phosphogypsum for efficient bioreduction in a batch bioreactor using a sulfate-reducing microbial consortium, Chem. Eng. J. 475 (2023) 146072.
[12] J.L. Guerrero, S.M. Perez-Moreno, I. Gutierrez-Alvarez, M.J. Gazquez, J.P. Bolivar, Behaviour of heavy metals and natural radionuclides in the mixing of phosphogypsum leachates with seawater, Environ. Pollut. 268 (Pt A) (2021) 115843.
[13] A.M. Rashad, Phosphogypsum as a construction material, J. Clean. Prod. 166 (2017) 732-743.
[14] S.W. Jian, X. Yang, W.B. Gao, B.D. Li, X. Gao, W.C. Huang, H.B. Tan, Y.T. Lei, Study on performance and function mechanisms of whisker modified flue gas desulfurization (FGD) gypsum, Constr. Build. Mater. 301 (2021) 124341.
[15] F.T. Ma, C. Chen, Y.B. Wang, Mechanical behavior of calcium sulfate whisker-reinforced paraffin/gypsum composites, Constr. Build. Mater. 305 (2021) 124795.
[16] S. Shao, B.Z. Ma, Y.Q. Chen, W.J. Zhang, B. Liu, P. Xing, C.Y. Wang, Direct synthesis of single-phase α-CaSO₄·0.5H₂O whiskers from waste nitrate solution, Chin. J. Chem. Eng. 28 (6) (2020) 1752-1754.
[17] T.T. Fan, X.S. Wang, Y. Gao, X.Y. Zhang, Investigating the interaction mechanism and effect of different calcium sulfate whiskers on performance of asphalt binder, Constr. Build. Mater. 224 (2019) 515-533.
[18] M. Miao, X. Feng, G.L. Wang, S.M. Cao, W. Shi, L.Y. Shi, Direct transformation of FGD gypsum to calcium sulfate hemihydrate whiskers: preparation, simulations, and process analysis, Particuology 19 (2015) 53-59.
[19] L. Liu, N. Yin, M.Q. Kang, X.K. Wang, Study on CaSO₄ whisker reinforcing and toughening mechanisms for polyurethane elastomer, Acta Polym. Sin. (2) (2001) 245-249.
[20] Q.J. Guan, W. Sun, Y.H. Hu, C.P. Guan, Z.G. Yin, C.H. Zhang, Removal and utilization of calcite existed in scheelite by preparation of calcium sulfate whiskers, Int. J. Min. Sci. Technol. 27 (6) (2017) 1005-1010.
[21] J.Y. Cui, Y.B. Cai, W.J. Yuan, Z.F. Lv, S.A. Xu, Preparation of a crosslinked chitosan coated calcium sulfate whisker and its reinforcement in polyvinyl chloride, J. Mater. Sci. Technol. 32 (8) (2016) 745-752.
[22] Z.M. Sheng, J. Zhou, Z. Shu, Y. Yakubu, Y. Chen, W.B. Wang, Y.X. Wang, Calcium sulfate whisker reinforced non-fired ceramic tiles prepared from phosphogypsum, Boletin De La Soc. Espanola De Ceramica Y Vidrio 57 (2) (2018) 73-78.
[23] M.G. Li, K. Ye, K.B. Luo, H.P. Li, Y. Su, G.B. Li, Y. Mei, Research progress on modification and applications in the material fields of calcium sulfate whisker, Bull. Chin. Ceram. Soc. 36 (5) (2017) 1590-1593, 1598.
[24] P. Bakshi, A. Pappu, D. Kumar Bharti, Transformation of flue gas desulfurization (FGD) gypsum to β-CaSO₄·0.5H₂O whiskers using facile water treatment, Mater. Lett. 308 (2022) 131177.
[25] X. Wang, B. Jin, Z. Xu, X. Zhang, X. Liu, L. Yang, Effects of AlCl₃ on the crystal morphology of calcium sulfate whisker prepared from FGD gypsum, In: 6th Annual International Conference on Material Science and Environmental Engineering (MSEE), Chongqing, China, 2018.
[26] H.L. Fu, J.S. Huang, L.M. Shen, Z.Y. Yu, L.H. Xu, J.Y. Li, S. Cao, M. Zhang, G.M. Jiang, Role and fate of the lead during the conversion of calcium sulfate dihydrate to α-hemihydrate whiskers in ethylene glycol-water solutions, Chem. Eng. J. 372 (2019) 74-81.
[27] F. Li, J.L. Liu, G.Y. Yang, Z.Y. Pan, X. Ni, H.Z. Xu, Q. Huang, Effect of pH and succinic acid on the morphology of α-calcium sulfate hemihydrate synthesized by a salt solution method, J. Cryst. Growth 374 (2013) 31-36.
[28] X.T. Zhang, X. Wang, B. Jin, X.P. Liu, L.S. Yang, Crystal structure formation of hemihydrate calcium sulfate whiskers (HH-CSWs) prepared using FGD gypsum, Polyhedron 173 (2019) 114140.
[29] M.L. Vo, J. Plank, Dispersing effectiveness of a phosphated polycarboxylate in α- and β-calcium sulfate hemihydrate systems, Constr. Build. Mater. 237 (2020) 117731.
[30] X. Wang, L.S. Yang, X.F. Zhu, J.K. Yang, Preparation of calcium sulfate whiskers from FGD gypsum via hydrothermal crystallization in the H₂SO₄-NaCl-H₂O system, Particuology 17 (2014) 42-48.
[31] Q.J. Guan, W. Sun, Y.H. Hu, Z.G. Yin, C.P. Guan, A facile method of transforming FGD gypsum to α-CaSO₄·0.5H₂O whiskers with cetyltrimethylammonium bromide (CTAB) and KCl in glycerol-water solution, Sci. Rep. 7 (1) (2017) 7085.
[32] Z.S. Tian, Preparation of gypsum whiskers and their application in paper making, Master Thesis, Kunming University of Science and Technology, China, 2022. (in Chinses).
[33] R.M. Ding, L.C. Yang, Y. Huang, J.F. Zhang, Morphology control and growth mechanism of calcium sulfate whisker from recrystallization induced by temperature elevation, J. Synth. Cryst. 44 (7) (2015) 1922-1928.
[34] X.L. Mao, X.F. Song, G.M. Lu, Y.Z. Sun, Y.X. Xu, J.G. Yu, Control of crystal morphology and size of calcium sulfate whiskers in aqueous HCl solutions by additives: experimental and molecular dynamics simulation studies, Ind. Eng. Chem. Res. 54 (17) (2015) 4781-4787.
[35] D.X. Li, Preparation of hemihydrate calcium sulfate whiskers from phosphogypsum under atmospheric pressure microwave irradiation in glycerol water system, Mater Thesis, Kunming University of Science and Technology, China, 2023. (in Chinese).
[36] N. Yang, H.N. Xiao, W.M. Guo, Additives-assisted hydrothermal synthesis of calcium sulfate whisker and its growth mechanism, J. Chin. Ceram. Soc. 42 (4) (2014) 539-544.
[37] C.J. Liu, Q. Zhao, Y.G. Wang, P.Y. Shi, M.F. Jiang, Hydrothermal synthesis of calcium sulfate whisker from flue gas desulfurization gypsum, Chin. J. Chem. Eng. 24 (11) (2016) 1552-1560.
[38] Z.Q. Zhang, Z.M. Zhao, S.C. Quan, Z. Liu, C. Wang, S. Liao, J. Cheng, Study on the formation of clean phosphogypsum whiskers with different particle size ranges, Non-metallic Mines. 43(6) (2020) 90-93. (in Chinese).
[39] Q. Li, C. Shi, F. Liu, C. Shang, P. Yan, L. Wang, Preparation of calcium sulfate whiskers from FGD gypsum via hydrothermal crystallization in the sulfuric acid-inorganic salt, Non-metallic Mines. 40(2) (2017) 42-45. (in Chinese).
[40] J. Wu, S. Qin, X. Niu, Y. Qi, Z. Liu, Y. Hu, F. Feng, J. Li, Preparation of calcium sulfate whiskers from rare earth gypsum and formation mechanism of whiskers, Non-metallic Mines. 45(6) (2022) 1-5. (in Chinese).
[41] J. Gao, Q. Li, F.L. Liu, Calcium sulfate whisker prepared by flue gas desulfurization gypsum: a physical-chemical coupling production process, Chin. J. Chem. Eng. 28 (8) (2020) 2221-2226.
[42] S.Z. Wang, D.Y. Chen, K.K. Zhang, Preparation, characterization, and formation mechanism of calcium sulfate hemihydrate whiskers, J. Wuhan Univ. Technol.-Mat. Sci. Edit. 33 (6) (2018) 1407-1415.
[43] L.G. Wang, Y. Huang, A. Waleed, K. Wu, C. Lin, Z.X. Wang, G. Zheng, Z.Y. Fan, J.L. Sun, H.P. Zhou, L.D. Sun, C.H. Yan, A-site cation effect on growth thermodynamics and photoconductive properties in ultrapure lead iodine perovskite monocrystalline wires, ACS Appl. Mater. Interfaces 9 (31) (2017) 25985-25994.
[44] D. Li, R. Guo, Z. Lin, S. Zhang, Study on Preparation of alpha-Calcium Sulfate Hemihydrate Whiskers by Atmospheric Microwave Glycerol Water Method, Non-metallic Mines. 45(1) (2022) 46. (in Chinese).
[45] S.Z. Wang, D.Y. Chen, Y.L. He, C.L. Wu, The experimental research on preparation of calcium sulfate whiskers with hydrothermal synthesis from phosphogypsum residue, Non Met. Mines 39 (1) (2016) 4-7.
[46] Z. Su, X.C. Sun, X.Z. Liu, J. Zhang, L. Sun, X. Zhang, Z.X. Liu, F.P. Yu, Y.L. Li, X.F. Cheng, Y. Ding, X. Zhao, A strategy to prepare high-quality monocrystalline graphene: inducing graphene growth with seeding chemical vapor deposition and its mechanism, ACS Appl. Mater. Interfaces 12 (1) (2020) 1306-1314.
[47] W. Shuzhou, Study on Preparation of Calcium Sulfate Whiskers Using Phosphogypsum via the liquid phase growth method, Master Thesis, Southwest University of Science and Technology, 2017. (in Chinese).
[48] M.M.C. Canut, V.M.F. Jacomino, K. Bratveit, A.M. Gomes, M.I. Yoshida, Microstructural analyses of phosphogypsum generated by Brazilian fertilizer industries, Mater. Charact. 59 (4) (2008) 365-373.
[49] H. He, F.Q. Dong, P. He, Regulation preparation of large aspect ratio calcium sulfate whisker in the presence of mixed crystallization promoting agents, J. Synth. Cryst. 41 (6) (2012) 1679-1685.
[50] S. Zhang, Research Status of Preparation of Calcium Sulfate Hemihydrate Whisker from Industrial By-Product Gypsum, B Chin Cream Soc. 39(11) (2020) 3528-3534. (in Chinese).
[51] Z.T. Yuan, X.L. Wang, Y.X. Han, W.Z. Yin, Preparation of ultrafine calcium sulfate whiskers by hydrothermal synthesis, J. Northeast. Univ. Nat. Sci. 29 (4) (2008) 573-576.
[52] B.C. Wang, T.J. Peng, Y.X. Hao, D.H. Wang, Crystallization behavior of preparing calcium sulfate whisker from phosphogypsum, Acta Petrol. Mineral. 34 (6) (2015) 835-843.
[53] K.B. Luo, H.P. Li, C.M. Li, P. Ning, Influence of the process parameters on the formation of CaSO₄·0.5H₂O whiskers, J. Nanomater. 2013 (2013) 906267.
[54] D. Zhou, R.F. Wei, Y.L. Zhu, H.M. Long, B.F. Huang, Y.F. Wang, S.C. Wu, Calcium sulfate whisker one-step preparation using semi-dry flue gas desulfurization ash and directional growth control, J. Clean. Prod. 290 (2021) 125754.
[55] F.Q. Dong, H. He, P. He, W. Yang, L.H. Xu, The optimal conditions of preparation of phosphogypsum-based calcium sulfate hemihydrate whiskers by hydrothermal method using phosphogypsum. Dong F, Proceedings of the 11th International Congress for Applied Mineralogy (ICAM). Cham: Springer, 2015: 81-89.
[56] F.C. Wang, J.J. Li, C.S. Shi, E.Z. Liu, C.N. He, N.Q. Zhao, In-situ synthesis of MgAlB₄ whiskers as a promising reinforcement for aluminum matrix composites, Mater. Sci. Eng. A 764 (2019) 138229.

Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment

Improved length of calcium sulfate crystal seeds and whiskers via ball milling and hydration treatment

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Zhihao Zhang, Danyang Song, Hengxing Bao, Xiang Ling, Xiaogang Jin. Experimental and numerical studies of Ca(OH)₂/CaO dehydration process in a fixed-bed reactor for thermochemical energy storage[J]. 中国化学工程学报, 2023, 62(10): 11-20.
[2]	Tianyu Zhang, Qian Wang, Wei Luan, Xue Li, Xianfu Chen, Dong Ding, Zhichao Shen, Minghui Qiu, Zhaoliang Cui, Yiqun Fan. Zwitterionic monolayer grafted ceramic membrane with an antifouling performance for the efficient oil-water separation[J]. 中国化学工程学报, 2022, 42(2): 227-235.
[3]	Xiaodong Liu, Zhengwei Jin, Yunhuan Jing, Panpan Fan, Zhili Qi, Weiren Bao, Jiancheng Wang, Xiaohui Yan, Peng Lv, Lianping Dong. Review of the characteristics and graded utilisation of coal gasification slag[J]. 中国化学工程学报, 2021, 35(7): 92-106.
[4]	Mingyuan Hu, Hui Tian. Design of process and control scheme for cyclohexanol production from cyclohexene using reactive distillation[J]. 中国化学工程学报, 2021, 40(12): 96-105.
[5]	Shupanxiang Chen, Guangying Chen, Xiaolan Zhao, Xiao Luo, Hongxia Gao, Wensheng Li, Zhiwu Liang. Feasibility analysis and process simulation of CO₂ dehydration using triethylene glycol for CO₂ pipeline transportation[J]. 中国化学工程学报, 2021, 40(12): 179-186.
[6]	Xiaopan Chen, Meihua Zhu, Sitong Xiang, Tian Gui, Ting Wu, Yuqin Li, Na Hu, Izumi Kumakiri, Xiangshu Chen, Hidetoshi Kita. Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane[J]. 中国化学工程学报, 2021, 29(1): 154-159.
[7]	Muhammad Salman, Liangliang Zhang, Jianfeng Chen. A computational simulation study for techno-economic comparison of conventional and stripping gas methods for natural gas dehydration[J]. 中国化学工程学报, 2020, 28(9): 2285-2293.
[8]	Hongxi Li, Chenggong Xu, Qishan Yang. Preparation and characterization of neodymium hydroxide powder via the hydration method[J]. 中国化学工程学报, 2020, 28(7): 1973-1980.
[9]	Hongyin Pang, Ruifang Lu, Tao Zhang, Li Lü, Yanxiao Chen, Shengwei Tang. Chemical dehydration coupling multi-effect evaporation to treat waste sulfuric acid in titanium dioxide production process[J]. 中国化学工程学报, 2020, 28(4): 1162-1170.
[10]	Yuan Wang, Yang Xiao, Guomin Xiao. Sustainable value-added C₃ chemicals from glycerol transformations: A mini review for heterogeneous catalytic processes[J]. 中国化学工程学报, 2019, 27(7): 1536-1542.
[11]	Yiwei Luo, Waseem Raza, Jianhua Yang, Liangqing Li, Ying Lu. Recent advances in acid-resistant zeolite T membranes for dehydration of organics[J]. 中国化学工程学报, 2019, 27(6): 1449-1457.
[12]	Junqiang Zhang, Shu Zhang, Mei Zhong, Zhi Wang, Guoyu Qian, Junhao Liu, Xuzhong Gong. Relationship between pore structure and hydration activity of CaO from carbide slag[J]. 中国化学工程学报, 2019, 27(11): 2771-2782.
[13]	Xiuhui Huang, Zeqiu Li, Ying Tian. Process optimization of an industrial acetic acid dehydration progress via heterogeneous azeotropic distillation[J]. Chinese Journal of Chemical Engineering, 2018, 26(8): 1631-1643.
[14]	Chongwen Jiang, Jundong Zhu, Bing Wang, Lu Li, Hong Zhong. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chinese Journal of Chemical Engineering, 2018, 26(6): 1270-1277.
[15]	Xin Zhang, Hui Liu, Amar Samb, Guofeng Wang. CFD simulation of homogeneous reaction characteristics of dehydration of fructose to HMF in micro-channel reactors[J]. Chinese Journal of Chemical Engineering, 2018, 26(6): 1340-1349.