Calculation of Transport Properties of CF4+Noble Gas Mixtures

›› 2009, Vol. 17 ›› Issue (5): 814-821.

Calculation of Transport Properties of CF₄+Noble Gas Mixtures

Soodabeh Nikmanesh¹, Jalil Moghadasi¹, Mohammad Mehdi Papari²

1. Department of Chemistry, Shiraz University, Shiraz 71454, Iran;
2. Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran

收稿日期:2009-01-05 修回日期:2009-06-25 出版日期:2009-10-28 发布日期:2009-10-28
通讯作者: Soodabeh Nikmanesh,E-mail:soodabeh.nikmanesh@gmail.com
基金资助:
Research Committees of Shiraz University and Shiraz University of Technology for supporting this project and making computer facilities available

Calculation of Transport Properties of CF₄+Noble Gas Mixtures

Soodabeh Nikmanesh¹, Jalil Moghadasi¹, Mohammad Mehdi Papari²

1. Department of Chemistry, Shiraz University, Shiraz 71454, Iran;
2. Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran

Received:2009-01-05 Revised:2009-06-25 Online:2009-10-28 Published:2009-10-28
Supported by:
Research Committees of Shiraz University and Shiraz University of Technology for supporting this project and making computer facilities available

摘要/Abstract

摘要： The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF₄-He,CF₄-Ne,CF₄-Ar,CF4-Kr,CF₄-Xe from the principle of corresponding states of viscosity by the inversion technique.The Lennard-Jones (12-6) model potential is used as the initial model potential.The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities,diffusions,thermal diffusion factors,and thermal conductivities.The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%,respectively.

关键词: corresponding states principle, diffusion, inversion method, kinetic theory of gases, thermal conductivity, transport properties, viscosity

Abstract: The present work is concerned with determining the viscosity,diffusion,thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including:CF₄-He,CF₄-Ne,CF₄-Ar,CF4-Kr,CF₄-Xe from the principle of corresponding states of viscosity by the inversion technique.The Lennard-Jones (12-6) model potential is used as the initial model potential.The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities,diffusions,thermal diffusion factors,and thermal conductivities.The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%,respectively.

Key words: corresponding states principle, diffusion, inversion method, kinetic theory of gases, thermal conductivity, transport properties, viscosity

Soodabeh Nikmanesh, Jalil Moghadasi, Mohammad Mehdi Papari. Calculation of Transport Properties of CF₄+Noble Gas Mixtures[J]. , 2009, 17(5): 814-821.

参考文献

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Calculation of Transport Properties of CF₄+Noble Gas Mixtures

Calculation of Transport Properties of CF₄+Noble Gas Mixtures

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