Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons

›› 2009, Vol. 17 ›› Issue (6): 955-959.

Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons

罗建洪¹, 李军¹, 黄平¹, 黄美英²

1. Department of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2. Chongqing Three Gorges University, Chongqing 404000, China

收稿日期:2008-11-27 修回日期:2009-07-07 出版日期:2009-12-28 发布日期:2009-12-28
通讯作者: LI Jun,E-mail:lijun@email.scu.edu.cn
基金资助:
Supported by the Eleventh Five Year National Key Technology R&D Program (2008BAE58B01);New Century Excellent Talents of Ministry of Education (NCET-07-0577),the People's Republic of China

Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons

LUO Jianhong¹, LI Jun¹, HUANG Ping¹, HUANG Meiying²

1. Department of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2. Chongqing Three Gorges University, Chongqing 404000, China

Received:2008-11-27 Revised:2009-07-07 Online:2009-12-28 Published:2009-12-28
Supported by:
Supported by the Eleventh Five Year National Key Technology R&D Program (2008BAE58B01);New Century Excellent Talents of Ministry of Education (NCET-07-0577),the People's Republic of China

摘要/Abstract

摘要： A kinetic model fitted by the empirical equation has been proposed to describe the liquid drainage behavior.Rate constants(k_d) of liquid drainage equation could be obtained from the above empirical equation.In this paper,the stability of the colloidal gas aphrons(CGAs),the effect of concentrations of sodium dodecyl benzene sulphate(SDBS),dodecyl trimethylammonium bromide(HTAB) and polyoxyethylene sorbitol anhydride monolaurate(Tween-20),temperature,stirring speed,stirring time,and various kinds of salts on the k_d of liquid drainage are further investigated.The results show that the Arrhenius equation can be successfully used to describe the relation between k_d and absolute temperature(T),and concentrations of surfactants,stirring speed,stirring time and salinities also have great effect on the k_d.At last,the CGAs drainage mechanism is explained from analysis of the rate of liquid drainage as a function of time.

关键词: colloidal gas aphrons, liquid drainage, stability, rate constants

Abstract: A kinetic model fitted by the empirical equation has been proposed to describe the liquid drainage behavior.Rate constants(k_d) of liquid drainage equation could be obtained from the above empirical equation.In this paper,the stability of the colloidal gas aphrons(CGAs),the effect of concentrations of sodium dodecyl benzene sulphate(SDBS),dodecyl trimethylammonium bromide(HTAB) and polyoxyethylene sorbitol anhydride monolaurate(Tween-20),temperature,stirring speed,stirring time,and various kinds of salts on the k_d of liquid drainage are further investigated.The results show that the Arrhenius equation can be successfully used to describe the relation between k_d and absolute temperature(T),and concentrations of surfactants,stirring speed,stirring time and salinities also have great effect on the k_d.At last,the CGAs drainage mechanism is explained from analysis of the rate of liquid drainage as a function of time.

Key words: colloidal gas aphrons, liquid drainage, stability, rate constants

罗建洪, 李军, 黄平, 黄美英. Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons[J]. , 2009, 17(6): 955-959.

LUO Jianhong, LI Jun, HUANG Ping, HUANG Meiying. Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons[J]. , 2009, 17(6): 955-959.

参考文献

1 Sebba, F., Foams and Biliquid Foams:Aphrons, Wiley, New York(1987).
2 Save, S.V., Pangarkar, V.G., “Characterization of colloidal gas aphrons”, Chem. Eng. Commun., 127, 35-53(1994).
3 Jauregi, P., Gilmour, S., Varley, J., “Characterization of colloidal gas aphrons for subsequent use for protein recovery”, Chem. Eng. J., 65, 1-11(1997).
4 Jauregi, P., Varley, J., “Colloidal gas aphrons:potential applications in biotechnology”, Reviews, 17, 390-395(1999).
5 Amiri, M.C., “Sulphur removal from NTA dispersion by aphron flotation”, Ph.D. Thesis, Manchester University of Science and Technology, Manchester(1989).
6 Amiri, M.C., “Separation of ultra-fine sulphur particles from NTA dispersion by aphron flotation”, Int. J. Eng. Iran, 3, 148-153(1990).
7 Matsushita, K., Mollah, A.H., Stuckey, D.C., del Cerro, C., Bailey, A.I., “Predispersed solvent extraction of dilute products using CGA and CLA:Aphron preparation, stability and size”, Colloids Surf., 69, 65-72(1992).
8 Save, S.V., Pangarkar, V.G., Kumar, S.V., “Intensification of mass transfer in aqueous two-phase systems”, Biotechnol. Bioeng., 41, 72-78(1993).
9 Huang, Y.Y., Wang, Y.D., Dai, Y.Y., “Separation of organic dyes from water by colloidal gas aphrons”, Tsinghua Science and Technology, 7(1), 46-51(2002).
10 Jacobi, W.M., Woodcock, K. E., Grove, C.S., “Theoretical investigation of foam drainage”, Ind. Eng. Chem., 48, 2046(1956).
11 Yan, Y.L., Qu, C.T., Zhang, N.S., Yang, Z.G., Li, L., “A study on the kinetics of liquid drainage from colloidal gas aphrons(CGAs)”, Colloid. Surf. A:Physicochem. Eng. Aspects, 259, 167-172(2005).
12 Sebba, F., “An improved generator for micron-sized bubbles”, Chemistry and Industry,(9), 91(1985).
13 Zhang, C., Valsaraj, K.T., Constant, W.D., Roy, D., “Studies in solvent extraction using polyaphrons(I) size distribution, stability, and flotation of polyaphrons”, Sep. Sci. Technol., 31, 1059(1996).
14 Jarudilokkul, S., Rungphetcharat, K., Boonamnuayvitaya, V., “Protein separation by colloidal gas aphrons using nonionic surfactant”, Sep. Purif. Technol., 35, 23-29(2004).
15 Chaphalkar, P.G., Valsaraj, K.T., Roy, D., “A study of the size distribution and stability of colloidal gas aphrons using a particle size analyzer”, Sep. Sci. Technol., 28(6), 1287-1302(1993).
16 Dai,Y.J., Deng, T., “Stabilization and characterization of colloidal gas aphron dispersions”, J. Colloid and Interf. Sci., 261, 360-365(2003).
17 Rosen, M.J., Surfactants and Interfacial Phenomena, Wiley, 123-141, 200-220(1978).

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Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons

Kinetic Rate Constant of Liquid Drainage from Colloidal Gas Aphrons

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