Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation

›› 2011, Vol. 19 ›› Issue (4): 698-702.

Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation

宋华¹, 武显春², 汪怀远¹, 李峰¹

1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2 Chemical Engineering Dept., Texas A & M University, USA

收稿日期:2010-09-23 修回日期:2011-06-17 出版日期:2011-08-28 发布日期:2011-08-28
通讯作者: SONG Hua,E-mail:songhua@nepu.edu.cn
基金资助:
Supported by the Overseas Scholars of Heilongjiang Province of China (1151hq006)

Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation

SONG Hua¹, WU Xianchun², WANG Huaiyuan¹, LI Feng¹

1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;
2 Chemical Engineering Dept., Texas A & M University, USA

Received:2010-09-23 Revised:2011-06-17 Online:2011-08-28 Published:2011-08-28
Supported by:
Supported by the Overseas Scholars of Heilongjiang Province of China (1151hq006)

摘要/Abstract

摘要： A support(denoted AM) was prepared using pseudo-boehmite and mordenite.Ni-B and NiPtB amorphous catalysts were prepared on the support by the impregnation method followed by chemical reduction with a KBH4 solution.And the catalysts were characterized by X-ray diffraction(XRD), environment scanning electron microscope(ESEM), inductively coupled plasma(ICP), H₂-temperature programmed reduction(H₂-TPR), differential thermal analysis(DTA), and BET.Benzene hydrogenation was used as a probe reaction to evaluate the effect of addition of small quantities of Pt on the NiB/AM catalyst.The results show that Pt can promote the reduction of NiO and the formation of active sites, leading to smaller catalyst particles and better dispersion of active metal particles on the support.The catalytic activity, sulfur resistance and thermal stability were remarkably improved by Pt doping of the NiB/AM catalyst.

关键词: NiB amorphous alloy, benzene hydrogenation, Pt doping, sulfur resistance

Abstract: A support(denoted AM) was prepared using pseudo-boehmite and mordenite.Ni-B and NiPtB amorphous catalysts were prepared on the support by the impregnation method followed by chemical reduction with a KBH4 solution.And the catalysts were characterized by X-ray diffraction(XRD), environment scanning electron microscope(ESEM), inductively coupled plasma(ICP), H₂-temperature programmed reduction(H₂-TPR), differential thermal analysis(DTA), and BET.Benzene hydrogenation was used as a probe reaction to evaluate the effect of addition of small quantities of Pt on the NiB/AM catalyst.The results show that Pt can promote the reduction of NiO and the formation of active sites, leading to smaller catalyst particles and better dispersion of active metal particles on the support.The catalytic activity, sulfur resistance and thermal stability were remarkably improved by Pt doping of the NiB/AM catalyst.

Key words: NiB amorphous alloy, benzene hydrogenation, Pt doping, sulfur resistance

宋华, 武显春, 汪怀远, 李峰. Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation [J]. , 2011, 19(4): 698-702.

SONG Hua, WU Xianchun, WANG Huaiyuan, LI Feng. Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation [J]. , 2011, 19(4): 698-702.

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Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation

Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation

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