Thermal Decomposition Kinetics of Abietic Acid in Static Air

doi:10.1016/S1004-9541(13)60493-3

Chin.J.Chem.Eng. ›› 2013, Vol. 21 ›› Issue (7): 724-729.DOI: 10.1016/S1004-9541(13)60493-3

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Thermal Decomposition Kinetics of Abietic Acid in Static Air

NONG Weijian¹, CHEN Xiaopeng^1,2, WANG Linlin^1,2, LIANG Jiezhen^1,2, ZHONG Lingping¹, TONG Zhangfa ^1,2

1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2 Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China

Received:2011-09-08 Revised:2012-02-18 Online:2013-08-24 Published:2013-07-28
Supported by:
Supported by the National Natural Science Foundation of China (20976031, 31060102), the Natural Science Foundation of Guangxi Autonomous Region (2011GXNSFD018011, 0991030, 2010GXNSFA013042), the Science and Technology Program Foundation of Wuzhou City (200901011), the Scientific and Technological Project of Guangxi (1099060-2), the Scientific Research Innovative Foundation of Doctor Candidate (105930901008).

Thermal Decomposition Kinetics of Abietic Acid in Static Air

农韦健¹, 陈小鹏^1,2, 王琳琳^1,2, 梁杰珍^1,2, 钟玲萍¹, 童张法^1,2

1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2 Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China

通讯作者: TONG Zhangfa
基金资助:
Supported by the National Natural Science Foundation of China (20976031, 31060102), the Natural Science Foundation of Guangxi Autonomous Region (2011GXNSFD018011, 0991030, 2010GXNSFA013042), the Science and Technology Program Foundation of Wuzhou City (200901011), the Scientific and Technological Project of Guangxi (1099060-2), the Scientific Research Innovative Foundation of Doctor Candidate (105930901008).

Abstract

Abstract: The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis (TGA-DTA) technique with heating rates of 5, 10, 15 and 25 K·min^-1. The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric (TG-DTG) curves by using Flynn-Wall-Ozawa method and Kissinger method. The thermal decomposition mechanism of abietic acid was studied with four integral methods (Šatava-Šesták, MacCallum-Tanner, ordinary integral and Agrawal). The results show that the thermal decomposition mechanism is nucleation and growth, and the mechanism function is Avrami-Erofeev equation with n equates 1/2. The activation energy and the pre-exponential factor are 64.04 kJ·mol^-1 and 5.89×10⁵ s^-1, respectively.

Key words: abietic acid, activation energy, thermal decomposition, kinetics, integral method

摘要： The thermal decomposition of abietic acid in air was investigated under non-isothermal condition using thermogravimetric analysis-differential thermal analysis (TGA-DTA) technique with heating rates of 5, 10, 15 and 25 K·min^-1. The non-isothermal kinetic parameters were obtained via the analysis of the thermogravimetric and differential thermogravimetric (TG-DTG) curves by using Flynn-Wall-Ozawa method and Kissinger method. The thermal decomposition mechanism of abietic acid was studied with four integral methods (Šatava-Šesták, MacCallum-Tanner, ordinary integral and Agrawal). The results show that the thermal decomposition mechanism is nucleation and growth, and the mechanism function is Avrami-Erofeev equation with n equates 1/2. The activation energy and the pre-exponential factor are 64.04 kJ·mol^-1 and 5.89×10⁵ s^-1, respectively.

关键词: abietic acid, activation energy, thermal decomposition, kinetics, integral method

NONG Weijian, CHEN Xiaopeng, WANG Linlin, LIANG Jiezhen, ZHONG Lingping, TONG Zhangfa . Thermal Decomposition Kinetics of Abietic Acid in Static Air[J]. Chin.J.Chem.Eng., 2013, 21(7): 724-729.

农韦健, 陈小鹏, 王琳琳, 梁杰珍, 钟玲萍, 童张法. Thermal Decomposition Kinetics of Abietic Acid in Static Air[J]. Chinese Journal of Chemical Engineering, 2013, 21(7): 724-729.

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Thermal Decomposition Kinetics of Abietic Acid in Static Air

Thermal Decomposition Kinetics of Abietic Acid in Static Air

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