Amethod to refine crude cottonseed oil using non-toxic polyamine-based cationic polymers

doi:10.1016/j.cjche.2014.11.002

›› 2015, Vol. 23 ›› Issue (2): 379-383.DOI: 10.1016/j.cjche.2014.11.002

• SEPARATION SCIENCE AND ENGINEERING • Previous Articles Next Articles

Amethod to refine crude cottonseed oil using non-toxic polyamine-based cationic polymers

Hailin Lin¹, Tom C. Wedegaertner², Xiaoyun Mao³, Xudong Jing¹, Aicardo Roa-Espinosa^4,5

1 Department of Chemistry & Chemical Engineering, Zhongkai University of Agriculture and Technology, Guangzhou 510225, China;
2 Cottonseed Research & Marketing Agricultural Research, NC 27513, USA;
3 College of Resources and Environment, South China Agricultural University, Guangzhou 510642, China;
4 Soil Net LLC, Belleville, WI, 53508, USA;
5 Biological Systems Engineering Department, University of Wisconsin-Madison, WI, 53706, USA

Received:2013-10-10 Revised:2014-04-28 Online:2015-03-01 Published:2015-02-28
Supported by:
Supported by the research foundation by the U.S. Cotton Research and Promotion Program, U.S. Department of Agriculture and the Project of Combination of Industry, Education and Research of Ministry of Education of Guangdong Province, China (2011B090400358).

Amethod to refine crude cottonseed oil using non-toxic polyamine-based cationic polymers

Hailin Lin¹, Tom C. Wedegaertner², Xiaoyun Mao³, Xudong Jing¹, Aicardo Roa-Espinosa^4,5

1 Department of Chemistry & Chemical Engineering, Zhongkai University of Agriculture and Technology, Guangzhou 510225, China;
2 Cottonseed Research & Marketing Agricultural Research, NC 27513, USA;
3 College of Resources and Environment, South China Agricultural University, Guangzhou 510642, China;
4 Soil Net LLC, Belleville, WI, 53508, USA;
5 Biological Systems Engineering Department, University of Wisconsin-Madison, WI, 53706, USA

通讯作者: Aicardo Roa-Espinosa
基金资助:
Supported by the research foundation by the U.S. Cotton Research and Promotion Program, U.S. Department of Agriculture and the Project of Combination of Industry, Education and Research of Ministry of Education of Guangdong Province, China (2011B090400358).

Abstract

Abstract: The traditional method to refine crude cottonseed oil is time-consuming and expensive. This study evaluates the effectiveness of coagulation-flocculation-sedimentation process using quaternary polyamine-based polymers in refining crude cottonseed oil. Flocculated by four commercial polyamine-based cationic polymers (SL2700, SL3000, SL4500 and SL5000) with varied molecular weight (MW) and charge density (CD) and followed by coagulation with sodiumhydroxide, crude cottonseed oil can be effectively purified. Free fatty acids, gossypol, pigments and trace elements are all effectively and sufficiently removed by the four polymers in a MW- and CDdependentmanner. Our results suggest that the use of polyamine-based cationic polymers may offer an effective and feasible alternative to the traditional method for crude cottonseed oil refining.

Key words: Granulation, Precipitation, Purification, Cotton seed oil, Polymer, Gossypol

摘要： The traditional method to refine crude cottonseed oil is time-consuming and expensive. This study evaluates the effectiveness of coagulation-flocculation-sedimentation process using quaternary polyamine-based polymers in refining crude cottonseed oil. Flocculated by four commercial polyamine-based cationic polymers (SL2700, SL3000, SL4500 and SL5000) with varied molecular weight (MW) and charge density (CD) and followed by coagulation with sodiumhydroxide, crude cottonseed oil can be effectively purified. Free fatty acids, gossypol, pigments and trace elements are all effectively and sufficiently removed by the four polymers in a MW- and CDdependentmanner. Our results suggest that the use of polyamine-based cationic polymers may offer an effective and feasible alternative to the traditional method for crude cottonseed oil refining.

关键词: Granulation, Precipitation, Purification, Cotton seed oil, Polymer, Gossypol

Hailin Lin, Tom C. Wedegaertner, Xiaoyun Mao, Xudong Jing, Aicardo Roa-Espinosa. Amethod to refine crude cottonseed oil using non-toxic polyamine-based cationic polymers[J]. , 2015, 23(2): 379-383.

References

[1] G. Kaynak, M. Ersoz, H. Kara, Investigation of the properties of oil at the bleaching unit of an oil refinery, J. Colloid Interface Sci. 280 (1) (2004) 131-138.
[2] P. Falaras, I. Kovanis, F. Lezou, G. Seiragakis, Cottonseed oil bleaching by acidactivated montmorillonite, Clay Miner. 34 (2) (1999) 221-232.
[3] O.A. Regina, D.O. Okechukwu, Adsorptive removal of colour pigment from palm oil using acid activated Nteje clay. Kinetics, equilibrium and thermodynamics, Physicochem. Probl. Miner. Process. 49 (1) (2013) 369.
[4] E. Gonzalez-Prdas, M. Villafranca-Sancshes, A. Gallego-Campo, Influence of the physical-chemistry properties of an acid-activated bentonite in the bleaching of olive oil, J. Chem. Technol. Biotechnol. 57 (3) (1993) 213-216.
[5] R.O. Ajemba, P.K. Igbokwe, O.D. Onukwuli, Kinetics, equilibrium, and thermodynamics studies of colour pigments, Arch. Appl. Sci. Res. 4 (5) (2012) 1958-1966.
[6] Y.Y. Liu, H.F. Lu, W. Jiang, D.S. Li, S.J. Liu, B. Liang, Biodiesel production from crude Jatropha curcas L. oil with trace acid catalyst, Chin. J. Chem. Eng. 20 (4) (2012) 740-746.
[7] H. Loewenschuss, P.J. Wakelyn, Occurrence of gossypol in dried bract of the cotton plant, J. Am. Oil Chem. Soc. 12 (1972) 678-680.
[8] R.J. Hron, P.J. Wan, M.S. Kuk, Ethanol vapor deactivation of gossypol in cottonseed meal, J. Am. Oil Chem. Soc. 73 (10) (1996) 1337-1339.
[9] T. Coyle, S. Levante, M. Shetler, J. Wintield, In-vitro and in-vivo cytotoxicity of gossypol against central nervous system tumor cell lines, J. Neuro-Oncol. 19 (1) (1994) 25-35.
[10] L. Besraa, D.K. Sengupta, S.K. Roy, P. Ay, Polymer adsorption: Its correlation with flocculation and dewatering of kaolin suspension in the presence and absence of surfactants, Int. J. Miner. Process. 66 (1-4) (2002) 183-202.
[11] D. Avci, N. Mol, L. Dagasan, New cationic polyelectrolytes for flocculation process of bakers, yeast waste water, Polym. Bull. 48 (4-5) (2002) 353-359.
[12] H.H. Li, J.P. O'shea, G.V. Franks, Effect of molecular weight of poly(N-isopropyl acrylamide) temperature-sensitive flocculants on dewatering, AIChE J. 55 (8) (2009) 2070-2080.
[13] Mohsen Abbasi, Aboozar Taheri, Effect of coagulant agents on oily wastewater treatment performance usingmullite ceramic MF membranes: Experimental andmodeling studies, Chin. J. Chem. Eng. 21 (11) (2013) 1251-1259.
[14] S.Y. Yoon, Y. Deng, Flocculation and reflocculation of clay suspension by different polymer systems under turbulent conditions, J. Colloid Interface Sci. 278 (1) (2004) 139-145.
[15] S.S. Wong, T.T. Teng, A.L. Ahmad, Treatment of pulp and paper mill wastewater by polyacrylamide (PAM) in polymer induced flocculation, J. Hazard. Mater. 135 (1-3) (2006) 378-388.
[16] B.Witold, H.L. Haley, P. Sagar, P.S. Ram, Polymeric flocculants for wastewater and industrial effluent treatment, J. Mater. Educ. 31 (3-4) (2009) 157-166.
[17] Y.K. Kang, J. Hamzik, M. Felo, B. Qi, J. Lee, S. Ng, G. Liebisch, B. Shanehsaz, N. Singh, K. Persaud, D.L. Ludwig, P. Balderes, Development of a novel and efficient cell culture flocculation process using a stimulus responsive polymer to streamline antibody purification processes, Biotechnol. Bioeng. 110 (11) (2013) 2928-2937.
[18] Y. Zhou, G.V. Franks, Flocculation mechanism induced by cationic polymers investigated by light scattering, Langmuir 22 (16) (2006) 6775-6786.
[19] D. Wu, S. Ji, Y. Wu, Y. Ju, Y. Zhao, Design, synthesis, and antitumor activity of bile acid-polyamine-nucleoside conjugates, Bioorg. Med. Chem. Lett. 17 (7) (2007) 2983-2986.
[20] Q.Y. Yue, B.Y. Gao, Y. Wang, H. Zhang, Synthesis of polyamine flocculants and their potential use in treating dye wastewater, J. Hazard. Mater. 152 (1) (2008) 221-227.
[21] S.K. Ali, R.P. Singh, An investigation of the flocculation characteristics of polyacrylamide-grafted chitosan, J. Appl. Polym. Sci. 114 (4) (2009) 2410-2414.
[22] P. Przybylski, G. Wojciechowski, B. Brzezinski, Spectroscopic and semiempirical studies of gossypol complexes with Fe²⁺ and Fe³⁺ cations, J. Mol. Struct. 569 (1- 3) (2001) 147-155.
[23] Gupta, Practical Guide to Vegetable Oil Processing, AOCS Press, Illinois, 2007.

Amethod to refine crude cottonseed oil using non-toxic polyamine-based cationic polymers

Amethod to refine crude cottonseed oil using non-toxic polyamine-based cationic polymers

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Bo Yu, Guang Fu, Xinpei Li, Libo Zhang, Jing Li, Hongtao Qu, Dongbin Wang, Qingfeng Dong, Mengmeng Zhang. Arsenic removal from acidic industrial wastewater by ultrasonic activated phosphorus pentasulfide [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 46-52.
[2]	Pan Wang, Mengdei Zhou, Zhuangxin Wei, Lu Liu, Tao Cheng, Xiaohua Tian, Jianming Pan. Preparation of bowl-shaped polydopamine surface imprinted polymer composite adsorbent for specific separation of 2′-deoxyadenosine [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 69-79.
[3]	Xia Miao, Xiaofan Pang, Shiyu Li, Haoguang Wei, Jianhao Yin, Xiangming Kong. Mechanical strength and the degradation mechanism of metakaolin based geopolymer mixed with ordinary Portland cement and cured at high temperature and high relative humidity [J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 118-130.
[4]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 9-15.
[5]	Yong Xu, Qingbai Chen, Yang Gao, Jianyou Wang, Huiqing Fan, Fei Zhao. Performance comparison of lithium fractionation from magnesium via continuous selective nanofiltration/electrodialysis [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 42-50.
[6]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application [J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 262-269.
[7]	Jiangshan Qu, Jianbo Zhang, Huiquan Li, Shaopeng Li, Da Shi, Ruiqi Chang, Wenfen Wu, Ganyu Zhu, Chennian Yang, Chenye Wang. Occurrence, leaching behavior, and detoxification of heavy metal Cr in coal gasification slag [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 11-19.
[8]	Xinyao Sun, Liu Zhao, Xu Hou, Hao Zhou, Huimin Qiao, Chenggong Song, Jing Huang, Enxian Yuan. Screening non-noble metal oxides to boost the low-temperature combustion of polyethylene waste in air [J]. Chinese Journal of Chemical Engineering, 2023, 58(6): 155-162.
[9]	Haike Li, Xindong Li, Guozai Ouyang, Lang Li, Zhaohuang Zhong, Meng Cai, Wenhao Li, Wanfu Huang. Tannic acid/Fe³⁺ interlayer for preparation of high-permeability polyetherimide organic solvent nanofiltration membranes for organic solvent separation [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 17-29.
[10]	Hui Yi Leong, Xiao-Qian Fu, Xiang-Yu Liu, Shan-Jing Yao, Dong-Qiang Lin. Characterisation and separation of infectious bursal disease virus-like particles using aqueous two-phase systems [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 72-78.
[11]	Yunchang Fan, Chunyan Zhu, Sheli Zhang, Lei Zhang, Qiang Wang, Feng Wang. Efficient and selective extraction of sinomenine by deep eutectic solvents [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 109-117.
[12]	Yongbo Liu, Zhihao Si, Cong Ren, Hanzhu Wu, Peng Zhan, Yuqing Peng, Peiyong Qin. Ultrathin polyamide nanofiltration membrane prepared by triazine-based porous organic polymer as interlayer for dye removal [J]. Chinese Journal of Chemical Engineering, 2023, 57(5): 193-201.
[13]	Jingran Liu, Yue Wu, Jie Tang, Tao Wang, Feng Ni, Qiumin Wu, Xijiao Yang, Ayyaz Ahmad, Naveed Ramzan, Yisheng Xu. Polymeric assembled nanoparticles through kinetic stabilization by confined impingement jets dilution mixer for fluorescence switching imaging [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 89-96.
[14]	Xiaoping Li, Jiaxin Pan, Jinwen Shi, Yanlin Chai, Songwei Hu, Qiaorong Han, Yanming Zhang, Xianwen Li, Dengwei Jing. Nanoparticle-induced drag reduction for polyacrylamide in turbulent flow with high Reynolds numbers [J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 290-298.
[15]	Taoyan Mao, Runhui Xiao, Peng Liu, Jiale Chen, Junqiang Luo, Su Luo, Fengwei Xie, Cheng Zheng. Facile fabrication of durable superhydrophobic fabrics by silicon polyurethane membrane for oil/water separation [J]. Chinese Journal of Chemical Engineering, 2023, 55(3): 73-83.