Measurement and correlation of physical properties of aqueous solutions of tetrabutylammonium hydroxide, piperazine and their aqueous blends

doi:10.1016/j.cjche.2015.08.006

Abstract

Abstract: The density, viscosity and refractive index of aqueous solutions of tetrabutylammoniumhydroxide (TBAOH), piperazine (PZ) and their aqueous blends are determined at several temperatures (303.15 to 333.15 K). All these measured physicochemical properties decreases with an increase in temperature. The density data is used to calculate the coefficient of thermal expansion and excess molar volume of all aqueous binary and ternary solutions. The coefficient of thermal expansion increases with increase in temperatures and concentrations. The negativity of excess molar volume for all the aqueous solution decreasedwith increase in temperature. Each physical property is correlated with temperature by least square method and the corresponding coefficients for each property are presented. The prediction values fromcorrelations for the physical properties are in good agreement with the experimental values.

Key words: Density, ionic liquids, Density, Viscosity, Refractive index

摘要： The density, viscosity and refractive index of aqueous solutions of tetrabutylammoniumhydroxide (TBAOH), piperazine (PZ) and their aqueous blends are determined at several temperatures (303.15 to 333.15 K). All these measured physicochemical properties decreases with an increase in temperature. The density data is used to calculate the coefficient of thermal expansion and excess molar volume of all aqueous binary and ternary solutions. The coefficient of thermal expansion increases with increase in temperatures and concentrations. The negativity of excess molar volume for all the aqueous solution decreasedwith increase in temperature. Each physical property is correlated with temperature by least square method and the corresponding coefficients for each property are presented. The prediction values fromcorrelations for the physical properties are in good agreement with the experimental values.

关键词: Density, ionic liquids, Density, Viscosity, Refractive index

Rizwan Safdar, Abdul Aziz Omar, Lukman B. Ismail, Arhama Bari, Bhajan Lal. Measurement and correlation of physical properties of aqueous solutions of tetrabutylammonium hydroxide, piperazine and their aqueous blends[J]. Chin.J.Chem.Eng., 2015, 23(11): 1811-1818.

References

[1] V.D. Spasojevic, S.P. Serbanvic, B.D. Djordjevic, M.L. Kijevcanin, Densities, viscosities and refractive indices of aqueous alkanolamine solutions as potential carbon dioxide removal reagents, J. Chem. Eng. Data 58 (2013) 84-92.

[2] M.S. Shaikh, A.M. Shariff, M.A. Bustam, G. Murshid, Physical properties of aqueous blends of sodium glycinate (SG) and piperazine (PZ) as a solvent for CO₂ capture, J. Chem. Eng. Data 58 (2013) 634-638.

[3] A.B. Rao, E.S. Rubin, A technical, economic and environmental assessment of aminebased CO₂ capture technology for power plant greenhouse gas control, Environ. Sci. Technol. 36 (2002) 4467-4475.

[4] Y. Zhao, X. Zhang, S. Zeng, Q. Zhou, H. Dong, X. Tian, S. Zhang, Density, viscosity and performances of carbon dioxide capture in 16 absorbents of amine + ionic liquid + H₂O, ionic liquid + H₂O and amine + H₂O systems, J. Chem. Eng. Data 55 (2010) 3513-3519.

[5] K. Damen, W. Turkenburg, Pathways towards large-scale implementation of CO₂ capture and storage: a case study for the Netherlands, Int. J. Greenhouse Gas Control 3 (2009) 217-236.

[6] H. Yang, Z. Xu,M. Fan, R. Gupta, R.B. Slimane, A.E. Bland, I.Wright, Progress in carbon dioxide separation and capture: a review, J. Environ. Sci. 20 (2008) 14-27.

[7] K. Simsons, K. Nijmeijer, H. Mengers, W. Brilman, M. Wessling, Highly selective amino acid salt solutions as absorption liquid for CO₂ capture in gas-liquid membrane, Chem. Sustain. 3 (2010) 939-947.

[8] S. Park, B.O. Choi, J. Lee, Absorption of carbon dioxide into aqueous PAA solution containing diethanolamine, J. Chin. Inst. Chem. Eng. 38 (2007) 461-466.

[9] S. Bishnoi, G.T. Rochelle, Absorption of carbon dioxide in aqueous piperazine/ methyldiethanolamine, AICHE J. 48 (2002) 2788-2799.

[10] M. Wang, A. Lawal, P. Stephenson, J. Sidders, C. Ramshaw, Post-combustion CO₂ capture with chemical absorption: a state-of-art review, Chem. Eng. Res. Des. 89 (2011) 1609-1624.

[11] A. Aboudheir, W. ElMoudir, Performance of formulated solvent in handling of enriched CO₂ flue gas stream, Energy Procedia 1 (2009) 195-204.

[12] K. Simons, W. Brilman, H. Mengers, K. Nijmeijer, M. Wessling, Kinetics of CO₂ absorption in aqueous sarcosine salt solutions: influence of concentration, temperature, and CO₂ loading, Ind. Eng. Chem. Res. 49 (2010) 9693-9702.

[13] D.M. D'Alessandro, B. Smit, J.R. Long, Carbon dioxide capture: prospects for newmaterials, Angew. Chem. Int. Ed. 49 (2010) 6058-6082.

[14] M.K. Mondal, Absorption of carbon dioxide into a mixed aqueous solution of diethanolamine and piperazine, Indian J. Chem. Technol. 17 (2010) 431-435.

[15] D. Speyer, V. Ermatchkov, G. Maurer, Solubility of carbon dioxide in aqueous solutions of N-methyldiethanolamine and piperazine in the low gas loading region, J. Chem. Eng. Data 55 (2009) 238-290.

[16] S. Van Loo, E.P. Van Elk, G.F. Versteeg, The removal of carbon dioxide with activated solutions of methyl-diethanol-amine, J. Petrol. Sci. Eng. 55 (2007) 135-145.

[17] J. Baek, J. Yoon, Solubility of carbon dioxide in aqueous solutions of 2-amino-2-methyl-1, 3-propanediol, J. Chem. Eng. Data 43 (1998) 635-637.

[18] G. Murshid, A.M. Shariff, K.K. Lau, M.A. Bustam, F. Ahmad, Physical properties of piperazine (PZ) activated aqueous solutions of 2-amino-2-hydroxymethyl-1, 3-propanediol (AHPD + PZ), J. Chem. Eng. Data 57 (2012) 133-136.

[19] S. Xu, F.D. Otto, A.E. Mather, Physical properties of aqueous AMP solutions, J. Chem. Eng. Data 36 (1991) 71-75.

[20] M.H. Li, Y.C. Lie, Densities and viscosities of solutions of monoethanolamine + Nmethyldiethanolamine + water and monoethanolamine + 2-amino-2-methyl-1-propanol + water, J. Chem. Eng. Data 39 (1994) 444-447.

[21] A.V. Rayer, K.Z. Sumon, A. Henni, P. Tontiwachwuthikul, Physiochemical properties of {1-methyl piperazine (1) + water (2)} system at T = (298.15 to 343.15) K and atmospheric pressure, J. Chem. Thermodyn. 43 (2011) 1897-1905.

[22] A.M. Shariff, G. Murshid, K.K. Lau, M.A. Bustam, F. Ahmed, Solubility of CO₂ in aqueous solutions of 2-amino-2-methyl-1-propanol at high pressure, World Acad. Sci. Eng. Technol. 60 (2011) 1050-1053.

[23] A. Veawab, P. Tontiwachwuthikul, A. Chakma, Corrosion behavior of carbon steel in the CO₂ absorption process using aqueous amine solutions, Ind. Eng. Chem. Res. 38 (1999) 3917-3924.

[24] X. Chen, S.A. Freeman, G.T. Rochelle, Foaming of aqueous piperazine and monoethanolamine for CO₂ capture, Int. J. Greenhouse Gas Control 5 (2011) 381-386.

[25] L.M. Galan Sanchez, G.W. Meindersma, A.B. Haan, Solvent properties of functionalized ionic liquids for Co2 absorption, Chem. Eng. Res. Des. 85 (2007) 31-39.

[26] M.J.Muldoon, J.L. Anderson, J.K. Dixon, J.F. Brennecke, Improving carbon dioxide solubility in ionic liquids, J. Phys. Chem. 111 (2007) 9001-9009.

[27] H.C. Chang, J.C. Jiang, C.Y. Chang, J.C. Su, C.H. Hung, Y.C. Liou, S.H. Lin, Structural organization in aqueous solutions of 1-butyl-3-methylimidazolium halides: a highpressure infrared spectroscopic study on ionic liquids, J. Phys. Chem. 112 (2008) 4351-4356.

[28] K.R. Harris, M. Kanakubo, L.A. Woolf, Temperature and pressure dependence of the viscosity of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate: viscosity and density relationships in ionic liquids, J. Chem. Eng. Data 52 (2007) 2425-2430.

[29] M.M. Taib, T. Murugesan, Solubilities of CO₂ in aqueous solutions of ionic liquids (ILs) and monoethanolamine (MEA) at pressures from 100 to 1600 kPa, Chem. Eng. J. 181-182 (2012) 56-62.

[30] P.J. Carvalho, V.H. Alvarez, I.M. Marrucho, M. Aznar, J.A.P. Coutinho, High carbon dioxide solubilities in trihexyltetradecyl phosphonium-based ionic liquids, J. Supercrit. Fluids 52 (2010) 258-265.

[31] A. Blasig, J. Tang, X. Hu, Y. Shen, M. Radosz, Magnetic suspension balance study of carbon dioxide solubility in ammonium-based polymerized ionic liquids: poly (p-vinylbenzyltrimethyl ammonium tetrafluoroborate) and poly ([2-(methacryloyloxy) ethyl] trimethyl ammonium tetrafluoroborate), Fluid Phase Equilib. 256 (2007) 75-80.

[32] K.A. Kurnia, M.I.A. Mutalib, Densities and viscosities of binary mixture of ionic liquid bis (2-hydroxyethyl) ammonium propionate with methanol, ethanol, and 1-propanol at T = (293.15, 303.15, 313.15, 323.15) K and at P = 0.1 MPa, J. Chem. Eng. Data 56 (2011) 79-83.

[33] K.A. Kurnia, F. Harris, C.D. Wilfred, M.I.A. Mutalib, T. Murugesan, Thermodynamic properties of CO₂ absorption in hydroxyl ammonium ionic liquids at pressures of (100-1600) kPa, J. Chem. Thermodyn. 41 (2009) 1069-1073.

[34] B.P.Mandal, M. Kundu, S.S. Bandyopadhyay, Density and viscosity of aqueous solutions of (N-methyldiethanolamine + monoethanolamine), (N-methyldiethanolamine + diethanolamine), (2-amino-2-methyl-1-propanol + monoethanolamine), and (2-amino-2-methyl-1-propanol + diethanolamine), J. Chem. Eng. Data 48 (2003) 703-707.

[35] J. Park, S.J. Yoon, H. Lee, Density, viscosity, and solubility of CO₂ in aqueous solutions of 2-amino-2-hydroxymethyl-1, 3-propanediol, J. Chem. Eng. Data 47 (2002) 970-973.

[36] A.V. Rayer, K.Z. Sumon, A. Henni, P. Tontiwachwuthikul, Physicochemical properties of {1-methyl piperazine (1) + water (2)} system at T = (298.15 to 343.15) K and atmospheric pressure, J. Chem. Thermodyn. 43 (2011) 1897-1905.

[37] T. Kavitha, P. Attri, P. Venkatesu, R.S. Rama Devi, T. Hofman, Temperature dependence measurements and molecular interactions for ammonium ionic liquid with N-methyl-2-pyrrolidone, J. Chem. Thermodyn. 54 (2012) 223-237.

[38] K.A. Kurnia, C.D.Wilfred, T. Murugesan, Thermophysical properties of hydroxyl ammonium ionic liquids, J. Chem. Thermodyn. 41 (2009) 517-521.

[39] M.S. Shaikh, A.M. Shariff, M.A. Bustam, G. Murshid, Physicochemical properties of aqueous solutions of sodium L-prolinate as an absorbent for CO₂ removal, J. Chem. Eng. Data 59 (2014) 362-368.

[40] N.M. Yunus, M.I.A. Mutalib, Z. Man, M.A. Bustam, T. Murugesan, Thermophysical properties of 1-alkylpyridinum bis(trifluoromethylsulfonyl)imide ionic liquids, J. Chem. Thermodyn. 42 (2010) 491-495.

[41] A.Muhammad,M.I.A.Mutalib, T.Murugesan, A. Shafeeq, Density and excess properties of aqueous N-methyldiethanolamine solutions from (298.15 to 338.15) K, J. Chem. Eng. Data 53 (2008) 2217-2221.