The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH2

doi:10.1016/j.cjche.2021.10.016

Chinese Journal of Chemical Engineering ›› 2022, Vol. 43 ›› Issue (3): 343-352.DOI: 10.1016/j.cjche.2021.10.016

Previous Articles Next Articles

The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂

Liuting Zhang¹, Haijie Yu¹, Zhiyu Lu¹, Changhao Zhao¹, Jiaguang Zheng¹, Tao Wei¹, Fuying Wu², Beibei Xiao¹

1. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. Analysis and Testing Center, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Received:2021-08-06 Revised:2021-10-12 Online:2022-04-28 Published:2022-03-28
Contact: Jiaguang Zheng,E-mail:jgzheng@just.edu.cn;Tao Wei,E-mail:wt863@126.com;Beibei Xiao,E-mail:xiaobb11@mails.jlu.edu.cn
Supported by:
The authors would like to express gratitude for support from the National Natural Science Foundation of China (Grant No. 51801078 and 21701083) and the Natural Science Foundation of Jiangsu Province (Grant No. BK20180986 and BK20210884).

The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂

Liuting Zhang¹, Haijie Yu¹, Zhiyu Lu¹, Changhao Zhao¹, Jiaguang Zheng¹, Tao Wei¹, Fuying Wu², Beibei Xiao¹

1. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. Analysis and Testing Center, Jiangsu University of Science and Technology, Zhenjiang 212003, China

通讯作者: Jiaguang Zheng,E-mail:jgzheng@just.edu.cn;Tao Wei,E-mail:wt863@126.com;Beibei Xiao,E-mail:xiaobb11@mails.jlu.edu.cn
基金资助:
The authors would like to express gratitude for support from the National Natural Science Foundation of China (Grant No. 51801078 and 21701083) and the Natural Science Foundation of Jiangsu Province (Grant No. BK20180986 and BK20210884).

Abstract

Abstract: High hydrogen desorption temperature and sluggish reaction kinetics are the major limitations for the practical application of MgH₂. In this study, Co particles with a face centered cubic (FCC) structure and a hexagonal close packed (HCP) structure were prepared facilely and proved to be good catalysts for magnesium hydride. Co particles with FCC structure presented better catalytic effect on MgH₂ than that with HCP structure. Both 7% (mass) Co FCC and HCP particle modified MgH₂ decreased the initial dehydrogenation temperature from 301.3 ℃ to approximately 195.0 ℃, but 7% (mass) Co with FCC structure modified MgH₂ has a faster desorption rate, and around 6.5% (mass) H₂ was desorbed in 10 min at 325 ℃. Hydrogen uptake was detected at 70 ℃ under 3.25 MPa hydrogen pressure and 6.0% (mass) H₂ was recharged in 40 min at 150 ℃. The hydrogen desorption and absorption activation energy for 7% (mass) FCC Co modified MgH₂ was significantly decreased to (76.6±8.3) kJ·mol^-1 and (68.3±6.0) kJ·mol^-1, respectively. Thermodynamic property was also studied, the plateau pressures of MgH₂ + 7% (mass) FCC Co were determined to be 0.14, 0.28, 0.53 and 0.98 MPa for 300 ℃, 325 ℃, 350 ℃ and 375℃. The decomposition enthalpy of hydrogen (ΔH) for MgH₂ + 7% (mass) FCC Co was (80.6±0.1) kJ·mol^-1, 5.8 kJ·mol^-1 lower than that of as-prepared MgH₂. Moreover, cycling performance for the first 20 cycles revealed that the reaction kinetics and capacity of MgH₂-FCC Co composite remained almost unchanged. The result of density functional theory calculation demonstrated that cobalt could extract the Mg—H bond and reduced the decompose energy of magnesium hydride. Our paper can be presented as a reference for searching highly effective catalysts for hydrogen storage and other energy-related research fields.

Key words: Hydrogen storage, MgH₂, FCC/HCP Co particles, Catalysis, Density functional theory

摘要： High hydrogen desorption temperature and sluggish reaction kinetics are the major limitations for the practical application of MgH₂. In this study, Co particles with a face centered cubic (FCC) structure and a hexagonal close packed (HCP) structure were prepared facilely and proved to be good catalysts for magnesium hydride. Co particles with FCC structure presented better catalytic effect on MgH₂ than that with HCP structure. Both 7% (mass) Co FCC and HCP particle modified MgH₂ decreased the initial dehydrogenation temperature from 301.3 ℃ to approximately 195.0 ℃, but 7% (mass) Co with FCC structure modified MgH₂ has a faster desorption rate, and around 6.5% (mass) H₂ was desorbed in 10 min at 325 ℃. Hydrogen uptake was detected at 70 ℃ under 3.25 MPa hydrogen pressure and 6.0% (mass) H₂ was recharged in 40 min at 150 ℃. The hydrogen desorption and absorption activation energy for 7% (mass) FCC Co modified MgH₂ was significantly decreased to (76.6±8.3) kJ·mol^-1 and (68.3±6.0) kJ·mol^-1, respectively. Thermodynamic property was also studied, the plateau pressures of MgH₂ + 7% (mass) FCC Co were determined to be 0.14, 0.28, 0.53 and 0.98 MPa for 300 ℃, 325 ℃, 350 ℃ and 375℃. The decomposition enthalpy of hydrogen (ΔH) for MgH₂ + 7% (mass) FCC Co was (80.6±0.1) kJ·mol^-1, 5.8 kJ·mol^-1 lower than that of as-prepared MgH₂. Moreover, cycling performance for the first 20 cycles revealed that the reaction kinetics and capacity of MgH₂-FCC Co composite remained almost unchanged. The result of density functional theory calculation demonstrated that cobalt could extract the Mg—H bond and reduced the decompose energy of magnesium hydride. Our paper can be presented as a reference for searching highly effective catalysts for hydrogen storage and other energy-related research fields.

关键词: Hydrogen storage, MgH₂, FCC/HCP Co particles, Catalysis, Density functional theory

Liuting Zhang, Haijie Yu, Zhiyu Lu, Changhao Zhao, Jiaguang Zheng, Tao Wei, Fuying Wu, Beibei Xiao. The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂[J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 343-352.

References

[1] R. Bardhan, A.M. Ruminski, A. Brand, J.J. Urban, Magnesium nanocrystal-polymer composites:A new platform for designer hydrogen storage materials, Energy Environ. Sci. 4 (12) (2011) 4882.https://doi.org/10.1039/c1ee02258j
[2] L. Schlapbach, A. Züttel, Hydrogen-storage materials for mobile applications, Nature 414 (6861) (2001) 353-358.https://www.ncbi.nlm.nih.gov/pubmed/11713542/
[3] M. Pudukudy, Z. Yaakob, M. Mohammad, B. Narayanan, K. Sopian, Renewable hydrogen economy in Asia-Opportunities and challenges:An overview, Renew. Sustain. Energy Rev. 30 (2014) 743-757.http://dx.doi.org/10.1016/j.rser.2013.11.015
[4] S.Y. Liu, P. Kundu, T.W. Huang, Y.J. Chuang, F.G. Tseng, Y. Lu, M.L. Sui, F.R. Chen, Quasi-2D liquid cell for high density hydrogen storage, Nano Energy 31 (2017) 218-224.http://dx.doi.org/10.1016/j.nanoen.2016.11.017
[5] Y.H. Sun, C.Q. Shen, Q.W. Lai, W. Liu, D.W. Wang, K.F. Aguey-Zinsou, Tailoring magnesium based materials for hydrogen storage through synthesis:Current state of the art, Energy Storage Mater. 10 (2018) 168-198.http://dx.doi.org/10.1016/j.ensm.2017.01.010
[6] H. Zhou, H. Wang, A.D. Sadow, I.I. Slowing, Toward hydrogen economy:Selective guaiacol hydrogenolysis under ambient hydrogen pressure, Appl. Catal. B:Environ. 270 (2020) 118890.http://dx.doi.org/10.1016/j.apcatb.2020.118890
[7] K.J. Jeon, H.R. Moon, A.M. Ruminski, B. Jiang, C. Kisielowski, R. Bardhan, J.J. Urban, Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts, Nat Mater 10 (4) (2011) 286-290.https://www.ncbi.nlm.nih.gov/pubmed/21399630/
[8] N. Juahir, N.S. Mustafa, A.M. Sinin, M. Ismail, Improved hydrogen storage properties of MgH₂ by addition of Co₂NiO nanoparticles, RSC Adv. 5 (75) (2015) 60983-60989.https://doi.org/10.1039/c5ra07094e
[9] M. Konarova, A. Tanksale, J. Norberto Beltramini, Q.L. Gao, Effects of nano-confinement on the hydrogen desorption properties of MgH₂, Nano Energy 2(1) (2013) 98-104. http://dx.doi.org/10.1016/j.nanoen.2012.07.024.
[10] L.S. Xie, J.S. Li, T.B. Zhang, L. Song, H.C. Kou, Microstructure and hydrogen storage properties of Mg-Ni-Ce alloys with a long-period stacking ordered phase, J. Power Sources 338 (2017) 91-102.http://dx.doi.org/10.1016/j.jpowsour.2016.11.025
[11] Y.Q. Lei, Y.M. Wu, Q.M. Yang, J. Wu, Q.D. Wang, Electrochemical behaviour of some mechanically alloyed Mg-Ni-based amorphous hydrogen storage alloys, Zeitschrift Für Physikalische Chemie 183 (1-2) (1994) 379-384.https://doi.org/10.1524/zpch.1994.183.part_1_2.379
[12] Q. Li, Q. Luo, Q.F. Gu, Insights into the composition exploration of novel hydrogen storage alloys:Evaluation of the Mg-Ni-Nd-H phase diagram, J. Mater. Chem. A 5 (8) (2017) 3848-3864.https://doi.org/10.1039/c6ta10090b
[13] M.G. Verón, H. Troiani, F.C. Gennari, Synergetic effect of Co and carbon nanotubes on MgH₂ sorption properties, Carbon 49 (7) (2011) 2413-2423. http://dx.doi.org/10.1016/j.carbon.2011.02.008
[14] Y.J. Chai, Z.Y. Liu, H.N. Gao, Z.Y. Zhao, N. Wang, D.L. Hou, Microstructure and hydrogen storage properties of porous Ni@Mg, Int. J. Hydrog. Energy 36 (22) (2011) 14484-14487.h ttp://dx.doi.org/10.1016/j.ijhydene.2011.08.024
[15] X.L. Ding, H.F. Ding, Y. Song, C.L. Xiang, Y.T. Li, Q.G. Zhang, Activity-tuning of supported Co-Ni nanocatalysts via composition and morphology for hydrogen storage in MgH₂, Front Chem 7 (2019) 937.https://www.ncbi.nlm.nih.gov/pubmed/32047735/
[16] Q. Li, Y. Li, B. Liu, X.G. Lu, T.F. Zhang, Q.F. Gu, The cycling stability of the in situ formed Mg-based nanocomposite catalyzed by YH₂, J. Mater. Chem. A 5 (33) (2017) 17532-17543. https://doi.org/10.1039/c7ta04551d.
[17] Y. Wang, Z.M. Ding, X.J. Li, S.Q. Ren, S.H. Zhou, H.M. Zhang, Y. Li, S.M. Han, Improved hydrogen storage properties of MgH₂ by nickel@nitrogen-doped carbon spheres, Dalton Trans. 49 (11) (2020) 3495-3502.https://doi.org/10.1039/d0dt00025f
[18] Z.L. Ma, J.C. Liu, Y.F. Zhu, Y.Y. Zhao, H.J. Lin, Y. Zhang, H.W. Li, J.G. Zhang, Y.N. Liu, W.T. Gao, S.S. Li, L.Q. Li, Crystal-facet-dependent catalysis of anatase TiO₂ on hydrogen storage of MgH₂, J. Alloy. Compd. 822 (2020) 153553.http://dx.doi.org/10.1016/j.jallcom.2019.153553
[19] Q. Li, K.C. Chou, Q. Lin, L.J. Jiang, F. Zhan, Hydrogen absorption and desorption kinetics of Ag-Mg-Ni alloys, Int. J. Hydrog. Energy 29 (8) (2004) 843-849.http://dx.doi.org/10.1016/j.ijhydene.2003.10.002
[20] J.L. Bobet, E. Akiba, B. Darriet, Study of Mg-M (M=Co, Ni and Fe) mixture elaborated by reactive mechanical alloying:Hydrogen sorption properties, Int. J. Hydrog. Energy 26 (5) (2001) 493-501.http://dx.doi.org/10.1016/S0360-3199(00)00082-3
[21] D. Korablov, F. Besenbacher, T.R. Jensen, Kinetics and thermodynamics of hydrogenation-dehydrogenation for Mg-25%TM (TM=Ti, Nb or V) composites synthesized by reactive ball milling in hydrogen, Int. J. Hydrog. Energy 43 (34) (2018) 16804-16814. http://dx.doi.org/10.1016/j.ijhydene.2018.05.091.
[22] R.A. Varin, S. Li, C. Chiu, L. Guo, O. Morozova, T. Khomenko, Z. Wronski, Nanocrystalline and non-crystalline hydrides synthesized by controlled reactive mechanical alloying/milling of Mg and Mg-X (X = Fe, Co, Mn, B) systems, J. Alloy. Compd. 404-406 (2005) 494-498.http://dx.doi.org/10.1016/j.jallcom.2004.12.176
[23] W. Su, Y.F. Zhu, J.G. Zhang, Y.N. Liu, Y. Yang, Q.F. Mao, L.Q. Li, Effect of multi-wall carbon nanotubes supported nano-nickel and TiF₃ addition on hydrogen storage properties of magnesium hydride, J. Alloy. Compd. 669 (2016) 8-18.http://dx.doi.org/10.1016/j.jallcom.2016.01.253
[24] X. Zhang, Z.H. Leng, M.X. Gao, J.J. Hu, F. Du, J.H. Yao, H.G. Pan, Y.F. Liu, Enhanced hydrogen storage properties of MgH₂ catalyzed with carbon-supported nanocrystalline TiO₂, J. Power Sources 398 (2018) 183-192.http://dx.doi.org/10.1016/j.jpowsour.2018.07.072
[25] T.Z. Si, X.Y. Zhang, J.J. Feng, X.L. Ding, Y.T. Li, Enhancing hydrogen sorption in MgH₂ by controlling particle size and contact of Ni catalysts, Rare Met. 40 (4) (2021) 995-1002. http://dx.doi.org/10.1007/s12598-018-1087-x.
[26] M.S. Yahya, M. Ismail, Improvement of hydrogen storage properties of MgH₂ catalyzed by K₂NbF₇ and multiwall carbon nanotube, J. Phys. Chem. C 122 (21) (2018) 11222-11233. https://doi.org/10.1021/acs.jpcc.8b02162.
[27] L.T. Zhang, Z.L. Cai, Z.D. Yao, L. Ji, Z. Sun, N.H. Yan, B.Y. Zhang, B.B. Xiao, J. Du, X.Q. Zhu, L.X. Chen, A striking catalytic effect of facile synthesized ZrMn₂ nanoparticles on the de/rehydrogenation properties of MgH₂, J. Mater. Chem. A 7 (10) (2019) 5626-5634. https://doi.org/10.1039/c9ta00120d.
[28] M. Ismail, N.S. Mustafa, N.A. Ali, N.A. Sazelee, M.S. Yahya, The hydrogen storage properties and catalytic mechanism of the CuFe₂O₄-doped MgH₂ composite system, Int. J. Hydrog. Energy 44 (1) (2019) 318-324. http://dx.doi.org/10.1016/j.ijhydene.2018.04.191.
[29] M.S. Yahya, M. Ismail, Catalytic effect of SrTiO₃ on the hydrogen storage behaviour of MgH₂, J. Energy Chem. 28 (2019) 46-53.http://dx.doi.org/10.1016/j.jechem.2017.10.020
[30] J. Cui, J.W. Liu, H. Wang, L.Z. Ouyang, D.L. Sun, M. Zhu, X.D. Yao, Mg-TM (TM:Ti, Nb, V, Co, Mo or Ni) core-shell like nanostructures:Synthesis, hydrogen storage performance and catalytic mechanism, J. Mater. Chem. A 2 (25) (2014) 9645-9655. https://doi.org/10.1039/c4ta00221k.
[31] L.Z. Ouyang, X.S. Yang, M. Zhu, J.W. Liu, H.W. Dong, D.L. Sun, J. Zou, X.D. Yao, Enhanced hydrogen storage kinetics and stability by synergistic effects of in situ formed CeH_2.73 and Ni in CeH_2.73-MgH₂-Ni nanocomposites, J. Phys. Chem. C 118 (15) (2014) 7808-7820. http://dx.doi.org/10.1021/jp500439n.
[32] D. Pukazhselvan, N. Nasani, T. Yang, I. Bdikin, A.V. Kovalevsky, D.P. Fagg, Dehydrogenation properties of magnesium hydride loaded with Fe, Fe-C, and Fe-Mg additives, ChemPhysChem 18 (3) (2017) 287-291. https://doi.org/10.1002/cphc.201601078.
[33] N. Hanada, T. Ichikawa, H. Fujii, Catalytic effect of nanoparticle 3d-transition metals on hydrogen storage properties in magnesium hydride MgH₂ prepared by mechanical milling, J. Phys. Chem. B 109 (15) (2005) 7188-7194. https://www.ncbi.nlm.nih.gov/pubmed/16851820/.
[34] S.C. Gao, H.Z. Liu, L. Xu, S.Q. Li, X.H. Wang, M. Yan, Hydrogen storage properties of nano-CoB/CNTs catalyzed MgH₂, J. Alloy. Compd. 735 (2018) 635-642.http://dx.doi.org/10.1016/j.jallcom.2017.11.047
[35] M.J. Liu, X.Z. Xiao, S.C. Zhao, M. Chen, J.F. Mao, B.S. Luo, L.X. Chen, Facile synthesis of Co/Pd supported by few-walled carbon nanotubes as an efficient bidirectional catalyst for improving the low temperature hydrogen storage properties of magnesium hydride, J. Mater. Chem. A 7 (10) (2019) 5277-5287. https://doi.org/10.1039/c8ta12431k.
[36] C. Xu, H.J. Lin, J.C. Liu, P. Zhang, Y.Y. Meng, Y.N. Liu, J.G. Zhang, L.Q. Li, Y.F. Zhu, Improved hydrogen absorption/desorption properties of MgH₂ by Co-catalyzing of YH₂ and Co@C, ChemistrySelect 4 (26) (2019) 7709-7714. https://doi.org/10.1002/slct.201901475.
[37] He Y, Wang L, Chen Z, Shen B, Wei J, Zeng P, Wen X, Catalytic ozonation for metoprolol and ibuprofen removal over different MnO₂ nanocrystals:Efficiency, transformation and mechanism, Sci Total Environ 785 (2021) 147328.https://www.ncbi.nlm.nih.gov/pubmed/33940402/
[38] M. Zhang, X.Z. Xiao, X.W. Wang, M. Chen, Y.H. Lu, M.J. Liu, L.X. Chen, Excellent catalysis of TiO₂ nanosheets with high-surface-energy {001} facets on the hydrogen storage properties of MgH₂, Nanoscale 11 (15) (2019) 7465-7473. https://www.ncbi.nlm.nih.gov/pubmed/30942207/.
[39] X.W. Wang, G.T. Fei, P. Tong, X.J. Xu, L.D. Zhang, Structural control and magnetic properties of electrodeposited Co nanowires, J. Cryst. Growth 300(2) (2007) 421-425. http://dx.doi.org/10.1016/j.jcrysgro.2006.12.039.
[40] L.T. Zhang, L. Ji, Z.D. Yao, N.H. Yan, Z. Sun, X.L. Yang, X.Q. Zhu, S.L. Hu, L.X. Chen, Facile synthesized Fe nanosheets as superior active catalyst for hydrogen storage in MgH₂, Int. J. Hydrog. Energy 44 (39) (2019) 21955-21964. http://dx.doi.org/10.1016/j.ijhydene.2019.06.065.
[41] X. Lu, L.T. Zhang, H.J. Yu, Z.Y. Lu, J.H. He, J.G. Zheng, F.Y. Wu, L.X. Chen, Achieving superior hydrogen storage properties of MgH₂ by the effect of TiFe and carbon nanotubes, Chem. Eng. J. 422 (2021) 130101.http://dx.doi.org/10.1016/j.cej.2021.130101
[42] B. Delley, From molecules to solids with the DMol3 approach, J. Chem. Phys. 113 (18) (2000) 7756-7764. https://doi.org/10.1063/1.1316015.
[43] B. Delley, DMol3 DFT studies:From molecules and molecular environments to surfaces and solids, Comput. Mater. Sci. 17 (2-4) (2000) 122-126. http://dx.doi.org/10.1016/S0927-0256(00)00008-2.
[44] J.P. Perdew, K. Burke, M. Ernzerhof, Generalized gradient approximation made simple, Phys. Rev. Lett. 77 (18) (1996) 3865.https://doi.org/10.1103/physrevlett.77.3865
[45] D.A. McKnight, J.P. Simmer, P.S. Hart, T.C. Hart, L.W. Fisher, Overlapping DSPP mutations cause dentin dysplasia and dentinogenesis imperfecta, J. Dent. Res. 87 (12) (2008) 1108-1111. https://doi.org/10.1177/154405910808701217.
[46] P. Marfey, M. Ottesen, Determination ofd-amino acids. I. Hydrolysis of DNP-l-amino acid methyl esters with carboxypeptidase-Y, Carlsberg Res. Commun. 49 (6) (1984) 585-590. http://dx.doi.org/10.1007/BF02908687.
[47] H.E. Kissinger, Reaction kinetics in differential thermal analysis, Anal. Chem. 29 (11) (1957) 1702-1706. https://doi.org/10.1021/ac60131a045.
[48] N.A. Sazelee, N.H. Idris, M.F. Md Din, M. S Yahya, N.A. Ali, M. Ismail, LaFeO₃ synthesised by solid-state method for enhanced sorption properties of MgH₂, Results Phys. 16 (2020) 102844.http://dx.doi.org/10.1016/j.rinp.2019.102844
[49] Y. Cheng, J. Bi, W. Zhang, The hydrogen storage properties of MgH₂-Fe₇S₈ composites, Mater. Adv. 2 (2) (2021) 736-742.https://doi.org/10.1039/d0ma00818d
[50] M. Ismail, M.S. Yahya, N.A. Sazelee, N.A. Ali, F.A.H. Yap, N.S. Mustafa, The effect of K₂SiF₆ on the MgH₂ hydrogen storage properties, J. Magnes. Alloy. 8 (3) (2020) 832-840. http://dx.doi.org/10.1016/j.jma.2020.04.002.
[51] M. Zhang, X.Z. Xiao, Z.M. Hang, M. Chen, X.C. Wang, N. Zhang, L.X. Chen, Superior catalysis of NbN nanoparticles with intrinsic multiple valence on reversible hydrogen storage properties of magnesium hydride, Int. J. Hydrog. Energy 46 (1) (2021) 814-822. http://dx.doi.org/10.1016/j.ijhydene.2020.09.173.
[52] T. Huang, X. Huang, C. Hu, J. Wang, H. Liu, Z. Ma, J. Zou, W. Ding, Enhancing hydrogen storage properties of MgH₂ through addition of Ni/CoMoO₄ nanorods, Mater. Today Energy 19 (2021) 100613.http://dx.doi.org/10.1016/j.mtener.2020.100613
[53] M.C. Weinberg, D.P. BirnieIII, V.A. ShneidmanIII, Crystallization kinetics and the JMAK equation, J. Non-Cryst. Solids 219 (1997) 89-99.http://dx.doi.org/10.1016/S0022-3093(97)00261-5
[54] M. Castro, F. Domınguez-Adame, A. Sánchez, T. Rodrıguez, Model for crystallization kinetics:Deviations from Kolmogorov-Johnson-Mehl-Avrami kinetics, Appl. Phys. Lett. 75 (15) (1999) 2205-2207. https://doi.org/10.1063/1.124965.
[55] F. Jensen, Activation energies and the Arrhenius equation, Qual. Reliab. Engng. Int. 1 (1) (1985) 13-17.https://doi.org/10.1002/qre.4680010104
[56] M.J. Liu, X.Z. Xiao, S.C. Zhao, S. Saremi-Yarahmadi, M. Chen, J.G. Zheng, S.Q. Li, L.X. Chen, ZIF-67 derived Co@CNTs nanoparticles:Remarkably improved hydrogen storage properties of MgH₂ and synergetic catalysis mechanism, Int. J. Hydrog. Energy 44 (2) (2019) 1059-1069. http://dx.doi.org/10.1016/j.ijhydene.2018.11.078.
[57] J. Huot, G. Liang, S. Boily, A. van Neste, R. Schulz, Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride, J. Alloy. Compd. 293-295 (1999) 495-500.http://dx.doi.org/10.1016/S0925-8388(99)00474-0
[58] X.S. Liu, H.Z. Liu, N. Qiu, Y.B. Zhang, G.Y. Zhao, L. Xu, Z.Q. Lan, J. Guo, Cycling hydrogen desorption properties and microstructures of MgH₂-AlH₃-NbF₅ hydrogen storage materials, Rare Met. 40 (4) (2021) 1003-1007. http://dx.doi.org/10.1007/s12598-020-01425-1.

The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂

The effect of different Co phase structure (FCC/HCP) on the catalytic action towards the hydrogen storage performance of MgH₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Shuo Li, Jianlin Cao, Xiang Feng, Yupeng Du, De Chen, Chaohe Yang, Wenhua Wang, Wanzhong Ren. Insights into the confinement effect on isobutane alkylation with C₄ olefin catalyzed by zeolite catalyst: A combined theoretical and experimental study [J]. Chinese Journal of Chemical Engineering, 2022, 47(7): 174-184.
[2]	Zhouxin Chang, Feng Yu, Zhisong Liu, Zijun Wang, Jiangbing Li, Bin Dai, Jinli Zhang. Ni-Al mixed metal oxide with rich oxygen vacancies: CO methanation performance and density functional theory study [J]. Chinese Journal of Chemical Engineering, 2022, 46(6): 73-83.
[3]	Weizhou Jiao, Xingyue Wei, Shengjuan Shao, Youzhi Liu. Catalytic decomposition and mass transfer of aqueous ozone promoted by Fe-Mn-Cu/γ-Al₂O₃ in a rotating packed bed [J]. Chinese Journal of Chemical Engineering, 2022, 45(5): 133-142.
[4]	Feng Guo, Zhihao Chen, Xiliu Huang, Longwen Cao, Xiaofang Cheng, Weilong Shi, Lizhuang Chen. Ternary Ni₂P/Bi₂MoO₆/g-C₃N₄ composite with Z-scheme electron transfer path for enhanced removal broad-spectrum antibiotics by the synergistic effect of adsorption and photocatalysis [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 157-168.
[5]	Qi Liu, Gao Cheng, Ming Sun, Weixiong Yu, Xiaohong, Zeng, Shichang Tang, Yongfeng li, Lin Yu. A facile preparation of hausmannite as a high-performance catalyst for toluene combustion [J]. Chinese Journal of Chemical Engineering, 2022, 44(4): 392-401.
[6]	Zhen Lu, Jie He, Bogeng Guo, Yulai Zhao, Jingyu Cai, Longqiang Xiao, Linxi Hou. Efficient homogenous catalysis of CO₂ to generate cyclic carbonates by heterogenous and recyclable polypyrazoles [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 110-115.
[7]	Di Gao, Yibo Zhi, Liyuan Cao, Liang Zhao, Jinsen Gao, Chunming Xu, Mingzhi Ma, Pengfei Hao. Influence of zinc state on the catalyst properties of Zn/HZSM-5 zeolite in 1-hexene aromatization and cyclohexane dehydrogenation [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 124-134.
[8]	Xin Li, Song Hong, Leiduan Hao, Zhenyu Sun. Cadmium-based metal-organic frameworks for high-performance electrochemical CO₂ reduction to CO over wide potential range [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 143-151.
[9]	Yanliang Zhou, Qianjin Sai, Zhenni Tan, Congying Wang, Xiuyun Wang, Bingyu Lin, Jun Ni, Jianxin Lin, Lilong Jiang. Highly efficient subnanometer Ru-based catalyst for ammonia synthesis via an associative mechanism [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 177-184.
[10]	Xuanyi Jia, Xiaomin Hu, Qiao Wang, Baiquan Chen, Xingyue Xie, Lihong Huang. Auto-thermal reforming of acetic acid for hydrogen production by Zn_xNi_yCrO_m±δ catalysts: Effect of Cr promoted Ni-Zn intermetallic compound [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 216-221.
[11]	Yichao Wu, Zhiwei Xie, Xiaofeng Gao, Xian Zhou, Yangzhi Xu, Shurui Fan, Siyu Yao, Xiaonian Li, Lili Lin. The highly selective catalytic hydrogenation of CO₂ to CO over transition metal nitrides [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 248-254.
[12]	Feng Guo, Haoran Sun, Yuxing Shi, Fengyu Zhou, Weilong Shi. CdS nanoparticles decorated hexagonal Fe₂O₃ nanosheets with a Z-scheme photogenerated electron transfer path for improved visible-light photocatalytic hydrogen production [J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 266-274.
[13]	Cuiting Yang, Bowen Wu, Zewei Liu, Guang Miao, Qibin Xia, Zhong Li, Michael J. Janik, Guoqing Li, Jing Xiao. Catalytic adsorptive desulfurization of mercaptan, sulfide and disulfide using bifunctional Ti-based adsorbent for ultra-clean oil [J]. Chinese Journal of Chemical Engineering, 2022, 42(2): 25-34.
[14]	Jiankang Wang, Yajing Wang, Zhongping Yao, Zhaohua Jiang. Metal-organic framework-derived Ni doped Co₃S₄ hierarchical nanosheets as a monolithic electrocatalyst for highly efficient hydrogen evolution reaction in alkaline solution [J]. Chinese Journal of Chemical Engineering, 2022, 42(2): 380-388.
[15]	Wei-Qi Yan, Yi-An Zhu, Xing-Gui Zhou, Wei-Kang Yuan. Rational design of heterogeneous catalysts by breaking and rebuilding scaling relations [J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 22-28.