SCI和EI收录∣中国化工学会会刊

Chin.J.Chem.Eng. ›› 2016, Vol. 24 ›› Issue (3): 415-420.DOI: 10.1016/j.cjche.2015.11.007

• MATERIALS AND PRODUCT ENGINEERING • Previous Articles     Next Articles

The structure, tensile properties and water resistance of hydrolyzed feather keratin-based bioplastics

Yao Dou1, Buning Zhang2, Ming He1, Guoqiang Yin2, Yingde Cui1,3   

  1. 1 School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China;
    2 Green Chemical Engineering Institute, Zhongkai University of Agriculture and Engineering, Guangzhou 510225, China;
    3 Guangzhou Vocational College of Science and Technology, Guangzhou 510550, China
  • Received:2015-01-30 Revised:2015-05-05 Online:2016-04-08 Published:2016-03-28
  • Supported by:

    Supported by the National Natural Science Foundation of China(21176269, 31371880, 31401526), Higher School Science and Technology Innovation Project of Guangdong Province(2013KJCX0102), and Science and Technology Plan Project of Guangdong Province(2013B010403029).

Abstract: Feather, as a by-product of the poultry industry, has long been treated as a solid waste, which causes environmental and economic problems.In this work, the hydrolyzed feather keratin(HFK) was extracted fromthe chicken feather using a cost-effectivemethod of alkali-extraction and acid-precipitation by applying urea and sodium sulfide.The aim was development and characterization of the eco-friendly films based on the HFK with variable glycerol contents by a thermoplastic process.The thermal analysis showed that high temperature and high pressure improved the compatibility between the glycerol and the HFK molecules.Also it was shown that the addition of water is necessary in the hot-pressing process of films.The FT-IR analysis indicated that the formation of the new hydrogen bonds between HFK and glycerol.By increasing the glycerol content, the film tensile strength(σb) decreases from10.5 MPa to 5.7 MPa and the solubility increases from15.3% to 20.9%, while the elongation at break(εb) achieves themaximumvalue of 63.8% for the film with 35% glycerol.The swellingwas just below 16.9% at 25℃ for 24 h, suggesting a good stability of the films in water.The water vapor permeability(WVP) varied between 3.02×10-10 g·m-2·s-1·Pa-1 and 4.11×10-10 g·m-2·s-1·Pa-1 for the films with 20% and 40% glycerol, respectively.The HFK film was uniform, translucent and tough, which could be used in packaging and agricultural field.

Key words: Feather keratin, Biodegradable films, Glycerol, Hot-pressing, Eco-friendly material