Research progress in the SO2 resistance of the catalysts for selective catalytic reduction of NOx

doi:10.1016/j.cjche.2017.03.030

Abstract

Abstract: The selective catalytic reduction (SCR) of NO_x with NH₃ has been proven to be an efficient technology for NO_x conversion to N₂. However, the catalysts used for SCR usually suffer from the problem of sulfur poisoning which seriously limits their practical application. This review summarized sulfur poisoning mechanisms of various SCR deNO_x catalysts and strategies to reduce deactivation caused by SO₂ such as doping metals, controlling the structures and morphologies of the catalysts, and selecting appropriate supports. The methods and procedures of catalysts preparation and the reaction conditions also have effect on SO₂-resistance of the catalysts. Several novel catalyst systems that exhibited good SO₂ resistance are also introduced. This paper could provide guidance for the development of highly efficient sulfur-tolerant deNO_x catalysts.

Key words: Words Selective catalytic reduction (SCR), SO₂ resistance, catalyst, No_x

摘要： The selective catalytic reduction (SCR) of NO_x with NH₃ has been proven to be an efficient technology for NO_x conversion to N₂. However, the catalysts used for SCR usually suffer from the problem of sulfur poisoning which seriously limits their practical application. This review summarized sulfur poisoning mechanisms of various SCR deNO_x catalysts and strategies to reduce deactivation caused by SO₂ such as doping metals, controlling the structures and morphologies of the catalysts, and selecting appropriate supports. The methods and procedures of catalysts preparation and the reaction conditions also have effect on SO₂-resistance of the catalysts. Several novel catalyst systems that exhibited good SO₂ resistance are also introduced. This paper could provide guidance for the development of highly efficient sulfur-tolerant deNO_x catalysts.

关键词: Words Selective catalytic reduction (SCR), SO₂ resistance, catalyst, No_x

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen. Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x[J]. Chin.J.Chem.Eng., 2017, 25(12): 1695-1705.

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen. Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x[J]. Chinese Journal of Chemical Engineering, 2017, 25(12): 1695-1705.

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Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x

Research progress in the SO₂ resistance of the catalysts for selective catalytic reduction of NO_x

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