Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

doi:10.1016/j.cjche.2017.05.021

Chin.J.Chem.Eng. ›› 2018, Vol. 26 ›› Issue (3): 601-607.DOI: 10.1016/j.cjche.2017.05.021

• Energy, Resources and Environmental Technology • Previous Articles Next Articles

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

Moses Arowo^1,2, Zemeng Zhao^1,3, Guangjun Li^1,4, Guangwen Chu^1,3, Baochang Sun^1,3, Lei Shao^1,3

1 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
2 Department of Chemical & Process Engineering, Moi University, 3900-3100 Eldoret, Kenya;
3 Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China;
4 Beijing Yanjing Beer Co. Ltd., Beijing 101300, China

Received:2017-02-27 Revised:2017-05-10 Online:2018-04-18 Published:2018-03-28
Contact: Baochang Sun, Lei Shao
Supported by:
Supported by the National Natural Science Foundation of China (21276013, 21676008) and Specialized Research Fund for the Doctoral Program of Higher Education of China (20130010110001).

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

Moses Arowo^1,2, Zemeng Zhao^1,3, Guangjun Li^1,4, Guangwen Chu^1,3, Baochang Sun^1,3, Lei Shao^1,3

1 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
2 Department of Chemical & Process Engineering, Moi University, 3900-3100 Eldoret, Kenya;
3 Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China;
4 Beijing Yanjing Beer Co. Ltd., Beijing 101300, China

通讯作者: Baochang Sun, Lei Shao
基金资助:
Supported by the National Natural Science Foundation of China (21276013, 21676008) and Specialized Research Fund for the Doctoral Program of Higher Education of China (20130010110001).

Abstract

Abstract: The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide (O₃/H₂O₂ process) to degrade o-phenylenediamine (o-PDA) in a simulated wastewater. A rotor-stator reactor (RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA (η) as well as the overall gas-phase volumetric mass transfer coefficient (K_Ga) were determined under different operating conditions of H₂O₂ concentration, initial o-PDA concentration, temperature of reaction, initial pH and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate (r_COD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer (GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone (O₃ process), and it was noted that η, K_Ga and r_COD achieved by O₃/H₂O₂ process was 24.4%, 31.6% and 25.2% respectively higher than those of O₃ process, indicating that H₂O₂ can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.

Key words: Degradation, Environment, Organic compounds, Oxidation, Ozone, Rotor-stator reactor

摘要： The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide (O₃/H₂O₂ process) to degrade o-phenylenediamine (o-PDA) in a simulated wastewater. A rotor-stator reactor (RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA (η) as well as the overall gas-phase volumetric mass transfer coefficient (K_Ga) were determined under different operating conditions of H₂O₂ concentration, initial o-PDA concentration, temperature of reaction, initial pH and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate (r_COD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer (GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone (O₃ process), and it was noted that η, K_Ga and r_COD achieved by O₃/H₂O₂ process was 24.4%, 31.6% and 25.2% respectively higher than those of O₃ process, indicating that H₂O₂ can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.

关键词: Degradation, Environment, Organic compounds, Oxidation, Ozone, Rotor-stator reactor

Moses Arowo, Zemeng Zhao, Guangjun Li, Guangwen Chu, Baochang Sun, Lei Shao. Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology[J]. Chin.J.Chem.Eng., 2018, 26(3): 601-607.

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Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

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