A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al2O3

doi:10.1016/j.cjche.2017.06.017

Chin.J.Chem.Eng. ›› 2018, Vol. 26 ›› Issue (5): 1209-1212.DOI: 10.1016/j.cjche.2017.06.017

• Materials and Product Engineering • Previous Articles Next Articles

A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al₂O₃

Chidchon Sararuk^1,2, Dan Yang¹, Guoliang Zhang¹, Chunshan Li¹, Suojiang Zhang¹

1 Key Laboratory of Ionic Liquid Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 University of Chinese Academy of Sciences, Beijing 100190, China

Received:2017-04-07 Revised:2017-06-22 Online:2018-06-29 Published:2018-05-28
Contact: Chunshan Li,E-mail address:csli@ipe.ac.cn
Supported by:
Supported by the CAS/SAFEA International Partnership Program for Creative Research Teams, National Key R & D program (2016YFB0601303) and the National Science Fund for Excellent Young Scholars (21422607).

A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al₂O₃

Chidchon Sararuk^1,2, Dan Yang¹, Guoliang Zhang¹, Chunshan Li¹, Suojiang Zhang¹

1 Key Laboratory of Ionic Liquid Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2 University of Chinese Academy of Sciences, Beijing 100190, China

通讯作者: Chunshan Li,E-mail address:csli@ipe.ac.cn
基金资助:
Supported by the CAS/SAFEA International Partnership Program for Creative Research Teams, National Key R & D program (2016YFB0601303) and the National Science Fund for Excellent Young Scholars (21422607).

Abstract

Abstract: Crystalline phase is the key factor for catalyst activity. The zirconium modified PCs/γ-Al₂O₃ samples were prepared through a simple step incipient-wetness impregnation method. The raw materials and samples were characterized by thermogravimetric-differential analysis (TG-DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), temperature-programmed desorption of ammonia and carbon dioxide (NH₃-and CO₂-TPD). The effects of calcination temperature and zirconium content on structure, chemical transformation, and acidity-basicity were investigated. Calcination temperature exhibited the major effect on the crystalline phase of samples. The new phase of Al0_.1Zr_0.9O_1.95 was exhibited which was above 650℃. In addition, zirconium content was influenced by the acidic and basic properties of the surface. The acidity and basicity of the ZrPCs/γ-Al₂O₃ sample increased with the increasing of zirconium content.

Key words: TG-DTA, XRD, FTIR, Acid-base properties, Zirconia, Aluminium-Zirconium oxide

摘要： Crystalline phase is the key factor for catalyst activity. The zirconium modified PCs/γ-Al₂O₃ samples were prepared through a simple step incipient-wetness impregnation method. The raw materials and samples were characterized by thermogravimetric-differential analysis (TG-DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), temperature-programmed desorption of ammonia and carbon dioxide (NH₃-and CO₂-TPD). The effects of calcination temperature and zirconium content on structure, chemical transformation, and acidity-basicity were investigated. Calcination temperature exhibited the major effect on the crystalline phase of samples. The new phase of Al0_.1Zr_0.9O_1.95 was exhibited which was above 650℃. In addition, zirconium content was influenced by the acidic and basic properties of the surface. The acidity and basicity of the ZrPCs/γ-Al₂O₃ sample increased with the increasing of zirconium content.

关键词: TG-DTA, XRD, FTIR, Acid-base properties, Zirconia, Aluminium-Zirconium oxide

Chidchon Sararuk, Dan Yang, Guoliang Zhang, Chunshan Li, Suojiang Zhang. A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al₂O₃[J]. Chin.J.Chem.Eng., 2018, 26(5): 1209-1212.

Chidchon Sararuk, Dan Yang, Guoliang Zhang, Chunshan Li, Suojiang Zhang. A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al₂O₃[J]. Chinese Journal of Chemical Engineering, 2018, 26(5): 1209-1212.

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A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al₂O₃

A simple strategy to synthesize and characterization of zirconium modified PCs/γ-Al₂O₃

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