Heat of absorption of CO2 in aqueous N,N-diethylethanolamine+ N-methyl-1,3-propanediamine solutions at 313 K

doi:10.1016/j.cjche.2018.11.027

Abstract

Abstract: Differential heat of absorption of CO₂ in aqueous solutions of N,N-diethylethanolamine (DEEA) and activated DEEA solutions up to a total concentration of 2 mol·L^-1 was measured as a function of CO₂ loading at 313.15 K using a reaction calorimeter. In order to analyze the performance of N-methyl-1,3-propanediamine (MAPA) as an activator, DEEA blended solutions containing 0.05, 0.1 and 0.2 mol·L^-1 MAPA were studied. The heat of CO₂ absorption in single DEEA solutions was unaffected by changing the DEEA concentration in the range of (0.5-2) mol·L^-1. On the other hand, increasing the concentration of MAPA in aqueous amine mixtures of (DEEA + MAPA) raised the heat of absorption.

Key words: CO₂ capture, Differential heat of absorption, N,N-diethylethanolamine, N-methyl-1,3-propanediamine, Amine blends

摘要： Differential heat of absorption of CO₂ in aqueous solutions of N,N-diethylethanolamine (DEEA) and activated DEEA solutions up to a total concentration of 2 mol·L^-1 was measured as a function of CO₂ loading at 313.15 K using a reaction calorimeter. In order to analyze the performance of N-methyl-1,3-propanediamine (MAPA) as an activator, DEEA blended solutions containing 0.05, 0.1 and 0.2 mol·L^-1 MAPA were studied. The heat of CO₂ absorption in single DEEA solutions was unaffected by changing the DEEA concentration in the range of (0.5-2) mol·L^-1. On the other hand, increasing the concentration of MAPA in aqueous amine mixtures of (DEEA + MAPA) raised the heat of absorption.

关键词: CO₂ capture, Differential heat of absorption, N, N-diethylethanolamine, N-methyl-1, 3-propanediamine, Amine blends

Katarzyna Sobala, Hanna Kierzkowska-Pawlak. Heat of absorption of CO₂ in aqueous N,N-diethylethanolamine+ N-methyl-1,3-propanediamine solutions at 313 K[J]. Chin.J.Chem.Eng., 2019, 27(3): 628-633.

Katarzyna Sobala, Hanna Kierzkowska-Pawlak. Heat of absorption of CO₂ in aqueous N,N-diethylethanolamine+ N-methyl-1,3-propanediamine solutions at 313 K[J]. Chinese Journal of Chemical Engineering, 2019, 27(3): 628-633.

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Heat of absorption of CO₂ in aqueous N,N-diethylethanolamine+ N-methyl-1,3-propanediamine solutions at 313 K

Heat of absorption of CO₂ in aqueous N,N-diethylethanolamine+ N-methyl-1,3-propanediamine solutions at 313 K

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